Skip to main content
SpringerLink
Log in

Application of mesoporous ZSM-5 as a support for Fischer–Tropsch cobalt catalysts

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

The effect of mesoporous structure of ZSM-5 on the properties of cobalt-based catalysts for Fischer–Tropsch synthesis was studied in this work. ZSM-5 and amorphous SiO2 supports have also been applied for comparison. It was shown that post treatment of ZSM-5 catalyst by NaOH solution improved the catalytic performance to produce higher amount of liquid hydrocarbons. The hierarchical structure combining with the acidity of meso-ZSM-5 had great effect on increasing the selectivity to C5–18 hydrocarbons and preventing the formation of CH4. The more acid sites of the support promoted catalytic cracking reaction of olefinic hydrocarbons to light hydrocarbons, the lower olefin to paraffin ratio was observed over Co/meso-ZSM-5 catalyst compared with that of Co/SiO2 catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M. E. Dry, G. Ertl, H. Knözinger, F. Schth, J. Weitkamp, Handbook of Heterogeneous Catalysis, vol. 6, (Wiley-VCH, Weinheim, 2008), p. 2965

  2. R.J. Madon, E. Iglesia, J. Catal. 139, 576 (1993)

    Article  CAS  Google Scholar 

  3. Q. Zhang, J. Kang, Y. Wang, Chem. Cat. Chem. 2, 1030 (2010)

    CAS  Google Scholar 

  4. A.Y. Khodakov, W. Chu, P. Fongarland, Chem. Rev. 107, 1692 (2007)

    Article  CAS  Google Scholar 

  5. B.H. Davis, Fuel Process Technol. 71, 157 (2001)

    Article  CAS  Google Scholar 

  6. R. Snel, Catal. Rev. Sci. Eng. 29, 361 (1984)

    Article  Google Scholar 

  7. R.C. Reuel, C.H. Bartholomew, J. Catal. 85, 78 (1984)

    Article  CAS  Google Scholar 

  8. L. Gora, B. Sulikowski, E.M. Serwicka, App. Catal. A Gen. 325, 316 (2007)

    Article  CAS  Google Scholar 

  9. J. Arandes, I. Torre, M.J. Azkoiti, J. Erena, M. Olazar, J. Bilbao, Energy Fuels 23, 4215 (2009)

    Article  CAS  Google Scholar 

  10. A. Corma, J. Martinez-Triguero, C. Martinez, J. Catal. 197, 151 (2001)

    Article  CAS  Google Scholar 

  11. G.G. Juttu, R.F. Lobo, Micro. Meso. Mater. 40(1–3), 9 (2000)

    Article  CAS  Google Scholar 

  12. P. Arendt, K.H. Van Heek, Fuel 60, 779 (1981)

    Article  CAS  Google Scholar 

  13. A. Arenillas, F. Rubiera, J.J. Pis, J. Anal. Appl. Pyrolysis 58, 685 (2001)

    Article  Google Scholar 

  14. G.H. Yang, J.J. He, Y. Yoneyama, Y.S. Tan, Y.Z. Han, N. Tsubaki, Appl. Catal. A Gen. 329, 99 (2007)

    Article  CAS  Google Scholar 

  15. S. Kang, J. Ryu, J. Kim, I. Jang, A.R. Kim, G. Han, J. Bae, K. Ha, Energy Fuels 26, 6061 (2012)

    Article  CAS  Google Scholar 

  16. J. Kang, K. Cheng, L. Zhang, Q. Zhang, J. Ding, W. Hua, Y. Lou, Q. Zhai, Y. Wang, Angew. Chem. 123, 5306 (2011)

    Article  Google Scholar 

  17. S. Sartipi, K. Parashar, M. Valero Romero, V.P. Santos, B. Linden, M. Makkee, F. Kapteijn, J. Gascon, J. Catal. 305, 179 (2013)

    Article  CAS  Google Scholar 

  18. D. Verboekend, S. Mitchell, M. Milina, J.C. Groen, J. Pérez-Ramírez, J. Phys. Chem. C 115, 14193 (2011)

    Article  CAS  Google Scholar 

  19. X. Wang, W. Li, G. Zhu, S. Qiu, D. Zhao, B. Zhong, Micro. Meso. Mater. 71, 87 (2004)

    Article  CAS  Google Scholar 

  20. A.Y. Khodakov, A. Griboval-Constant, R. Bechara, V.L. Zholobenko, J. Catal. 206, 230 (2002)

    Article  CAS  Google Scholar 

  21. R.B. Anderson, W.K. Hall, A. Krieg, B. Seligman, J. Am. Chem. Soc. 71, 183 (1949)

    Article  CAS  Google Scholar 

  22. L. Fu, C.H. Bartholomew, J. Catal. 92, 376 (1985)

    Article  CAS  Google Scholar 

  23. N.O. Elbashir, P. Dutta, A. Manivannan, M.S. Seehra, C.B. Roberts, Appl. Catal. A Gen. 285, 169 (2005)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The work was supported by the National Natural Science Foundation of China (21106177, 21203232), the Open funds of Key Laboratory of Biofuel (CASKLB201306) and The Basic Research Funds for Central University (2010QNA17), A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Author information

Authors and Affiliations

  1. Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, Xuzhou, 221116, Jiangsu, China

    Yuelun Wang, Weiming Zhao, Min Li, Zhiping Hu, Yongshen Wang, Jun Huang & Yunpeng Zhao

  2. Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, Qingdao, 266101, China

    Zhuo Li, Hui Wang & Jinhu Wu

  3. School of Chemical Engineering, China University of Mining and Technology, Xuzhou, 221116, Jiangsu, China

    Yuelun Wang

Authors
  1. Yuelun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Weiming Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhuo Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hui Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jinhu Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Min Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Zhiping Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Yongshen Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Jun Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. Yunpeng Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yuelun Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, Y., Zhao, W., Li, Z. et al. Application of mesoporous ZSM-5 as a support for Fischer–Tropsch cobalt catalysts. J Porous Mater 22, 339–345 (2015). https://doi.org/10.1007/s10934-014-9901-9

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-014-9901-9

Keywords

Search

Navigation