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Ordered mesoporous silica polymer nanocomposites for the adsorption of bovine serum albumin (BSA)

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Abstract

Silica polymer nanocomposites were synthesized via in situ free radical polymerization of vinyl monomers inside mesoporous silica frame work for their potential use in adsorption of bovine serum albumin (BSA). Powder X-ray diffraction studies and adsorption isotherm studies confirmed the mesoporous nature of the nanocomposites. Very high adsorption (6.5–14.2 mg/g) of BSA was observed for functionalized ordered silica nanocomposites (SBA/x). Various adsorption parameters such as adsorbent weight, adsorption time and pH etc. were optimized and possible synergism of hydrophilic/hydrophobic interactions was also discussed.

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References

  1. S. Inagaki, S. Guan, Y. Fukushima, T. Ohsuna, O. Terasaki, J. Am. Chem. Soc. 121, 9611 (1999)

    Article  CAS  Google Scholar 

  2. M. Kruk, M. Jaroniec, C.H. Ko, R. Ryoo, Chem. Mater. 12, 1961 (2000)

    Article  CAS  Google Scholar 

  3. M.J. MacLachlan, T. Asefa, G.A. Ozin, Chem. Eur. J. 6, 2507 (2000)

    Article  CAS  Google Scholar 

  4. W.C. Molenkamp, M. Watanabe, H. Miyata, S.H. Tolbert, J. Am. Chem. Soc. 126, 4476 (2004)

    Article  CAS  Google Scholar 

  5. A.P. Wight, M.E. Davis, Chem. Rev. 102, 3589 (2002)

    Article  CAS  Google Scholar 

  6. N. Al-Haq, R. Ramnauth, S. Kleinebiekel, D.L. Ou, A.C. Sullivan, J. Wilson, Green Chem. 4, 239 (2002)

    Article  CAS  Google Scholar 

  7. S. Cheng, X. Wang, S.-Y. Chen, Top. Catal. 52, 681 (2009)

    Article  CAS  Google Scholar 

  8. B.M. Choudary, M.L. Kantam, P. Sreekanth, T. Bandopadhyay, F. Figueras, A. Tuel, J. Mol. Catal. A Chem. 142, 361 (1999)

    Article  CAS  Google Scholar 

  9. S. Saravanamurugan, Sujandi, D.-S. Han, J.-B. Koo, S.-E. Park, Catal. Commun. 9, 158 (2008)

    Article  CAS  Google Scholar 

  10. A. Dubey, M. Choi, R. Ryoo, Green Chem. 8, 144 (2006)

    Article  CAS  Google Scholar 

  11. D. Sachdev, A. Dubey, Catal. Lett. 141, 1548 (2011)

    Article  CAS  Google Scholar 

  12. D. Sachdev, A. Dubey, Catal. Commun. 39, 39 (2013)

    Article  CAS  Google Scholar 

  13. A. Corma, Chem. Rev. 9, 2373 (1997)

    Article  Google Scholar 

  14. B. Krajewska, Enzyme Microb. Technol. 35, 126 (2004)

    Article  CAS  Google Scholar 

  15. M. Sardar, R. Agarwal, A. Kumar, M.N. Gupta, Enzyme Microb. Technol. 20, 361 (1997)

    Article  CAS  Google Scholar 

  16. T. Kopac, K. Bozgeyik, J. Yener, Colloids Surf. A 322, 19 (2008)

    Article  CAS  Google Scholar 

  17. S.J. McClellan, E.I. Franses, Colloids Surf. B 28, 63 (2003)

    Article  CAS  Google Scholar 

  18. M. Choi, F. Kleitz, D. Liu, H.Y. Lee, W.-S. Ahn, R. Ryoo, J. Am. Chem. Soc. 127, 1924 (2005)

    Article  CAS  Google Scholar 

  19. A. Tavolaro, P. Tavolaro, E. Drioli, Colloids Surf. B 55, 67 (2007)

    Article  CAS  Google Scholar 

  20. D.-H. Zhang, Y.-F. Zhang, G.-Y. Zhi, Y.-L. Xie, Colloids Surf. B 82, 302 (2011)

    Article  CAS  Google Scholar 

  21. Y. Ding, G. Yin, X. Liao, Z. Huang, X. Chen, Y. Yao, J. Li, Microporous Mesoporous Mater. 170, 45 (2013)

    Article  CAS  Google Scholar 

  22. Q. Tao, Z. Xu, J. Wang, F. Liu, H. Wan, S. Zheng, Microporous Mesoporous Mater. 131, 177 (2010)

    Article  CAS  Google Scholar 

  23. D. Tanyolaç, H. Sönmezışık, A.R. Özdural, Biochem. Eng. 22, 221 (2005)

    Article  Google Scholar 

  24. Y.L. Jeyachandran, E. Mielczarski, B. Rai, J.A. Mielczarski, Langmuir 25, 11614 (2009)

    Article  CAS  Google Scholar 

  25. Y.L. Jeyachandran, J.A. Mielczarski, E. Mielczarski, B. Rai, J. Colloid Interface Sci. 341, 136 (2010)

    Article  CAS  Google Scholar 

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Acknowledgments

AD thanks MPCST-Bhopal 6054/CST/R&D/2011 and CSIR, (01 (2696)12/EMR-II), New Delhi for research funding.

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Authors and Affiliations

  1. Department of Chemistry, Maulana Azad National Institute of Technology (MANIT), Bhopal, M.P., India

    G. Robin Wilson, Ankita Sharma, Neel Mani Srivastava & Amit Dubey

  2. National Institute of Food Technology Entrepreneurship and Management, Kundli, Haryana, India

    Divya Sachdev

Authors
  1. G. Robin Wilson
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  2. Ankita Sharma
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  3. Neel Mani Srivastava
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  4. Divya Sachdev
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  5. Amit Dubey
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Correspondence to Amit Dubey.

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Wilson, G.R., Sharma, A., Srivastava, N.M. et al. Ordered mesoporous silica polymer nanocomposites for the adsorption of bovine serum albumin (BSA). J Porous Mater 22, 333–337 (2015). https://doi.org/10.1007/s10934-014-9900-x

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