Skip to main content
SpringerLink
Log in

Infrared investigations of arenesulfonic modified mesoporous materials by the use of complementary probes

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Arenesulfonic mesoporous materials [SBA(R), 0.05 ≤ R (incorporation ratio) ≤0.15] have been prepared by the co-condensation of tetraethoxysilane (TEOS) and 2-(4-chlorosulfonylphenyl) ethyltrimethoxysilane (CSPTMS) in acidic solutions of Pluronic P123. The extent of the surface functionalisation and the nature of the interactions between sulfonic groups and the surface in SBA(0.05) and SBA(0.15) samples were investigated by FT-IR spectroscopy using two probes of different basic strengths. It was shown that carbon monoxide (CO, at 77 K) can be used as a good probe to study the surface functionalisation through the νC=O vibration at 2,158 cm−1 corresponding to its interaction with free silanol groups. Ammonia (NH3, at 423 K) is able to disturb the strong interactions of Si–OH–H3OS by forming the δNH–NH4 + which allowed to emphasise that SO3H groups of the less functionalised material SBA(0.05) are less acidic since the number of the acid groups is less important than in SBA(0.15).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 1
Fig. 5
Fig. 6
Scheme 2
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. A.P. Wight, M.E. Davis, Chem. Rev. 102, 3589 (2002)

    Article  CAS  Google Scholar 

  2. D.E. De Vos, M. Dams, B.F. Sels, P.A. Jacobs, Chem. Rev. 102, 3615 (2002)

    Article  Google Scholar 

  3. A. Taguchi, F. Schüth, Micropor. Mesopor. Mater. 77, 1 (2005)

    Article  CAS  Google Scholar 

  4. H.H.P. Yiu, P.A. Wright, Ser. Chem. Eng. 4, 849 (2004)

    Article  CAS  Google Scholar 

  5. F. Hoffmann, M. Cornelius, M.J. Maximilian, M. Froeba, Angew. Chem. Int. Ed. 45, 3216 (2006)

    Article  CAS  Google Scholar 

  6. J.H. Clark, Acc. Chem. Res. 35, 791 (2002)

    Article  CAS  Google Scholar 

  7. M. Boveri, J. Agúndez, I. Díaz, J. Pérez-Pariente, E. Sastre, Collect. Czech. Chem. Commun. 68, 1914 (2003)

    Article  CAS  Google Scholar 

  8. V. Dufaud, M.E. Davis, J. Am. Chem. Soc. 125, 9403 (2003)

    Article  CAS  Google Scholar 

  9. D. Das, J.F. Lee, S. Cheng, Chem. Commun. 21, 2178 (2001)

    Article  Google Scholar 

  10. D. Das, J.-F. Lee, S. Cheng, J. Catal. 223, 152 (2004)

    Article  CAS  Google Scholar 

  11. M. Alvaro, A. Corma, D. Das, V. Fornés, H. Garcia, Chem. Commun. 8, 956 (2004)

    Article  Google Scholar 

  12. B. Rác, Á. Molnár, P. Forgo, M. Mohai, I. Bertóti, J. Mol. Catal. A: Chem. 244, 46 (2006)

    Article  Google Scholar 

  13. I.K. Mbaraka, B.H. Shanks, J. Catal. 244, 78 (2006)

    Article  CAS  Google Scholar 

  14. X. Wang, C.-C. Chen, S.-Y. Chen, Y. Mou, S. Cheng, Appl. Catal. A: Gen. 281, 47 (2005)

    Article  CAS  Google Scholar 

  15. Q. Yang, M.P. Kapoor, N. Shirokura, M. Ohashi, S. Inagaki, J.N. Kondo, K. Domen, J. Mater. Chem. 15, 666 (2005)

    Article  CAS  Google Scholar 

  16. J. Liu, Q. Yang, M.P. Kapoor, N. Setoyama, S. Inagaki, J. Yang, L. Zhang, J. Phys. Chem. B 109, 12250 (2005)

    Article  CAS  Google Scholar 

  17. R. Van Grieken, J.A. Melero, G. Morales, Appl. Catal. A: Gen. 289, 143 (2005)

    Article  Google Scholar 

  18. S. Hamoudi, S. Royer, S. Kaliaguine, Micropor. Mesopor. Mater. 71, 17 (2004)

    Article  CAS  Google Scholar 

  19. I.K. Mbaraka, D.R. Radu, V.S.Y. Lin, B.H. Shanks, J. Catal. 219, 329 (2003)

    Article  CAS  Google Scholar 

  20. J.A. Melero, G.D. Stucky, R. van Grieken, G. Morales, J. Mater. Chem. 12, 1664 (2002)

    Article  CAS  Google Scholar 

  21. K. Wilson, A.F. Lee, D.J. Macquarrie, J.H. Clark, Appl. Catal. A: Gen. 228, 127 (2002)

    Article  CAS  Google Scholar 

  22. D. Margolese, J.A. Melero, S.C. Christiansen, B.F. Chmelka, G.D. Stucky, Chem. Mater. 12, 2448 (2000)

    Article  CAS  Google Scholar 

  23. W.M. van Rhijn, D.E. De Vos, B.F. Sels, W.D. Bossaert, P.A. Jacobs, Chem. Commun. 3, 317 (1998)

    Article  Google Scholar 

  24. J. Pérez-Pariente, I. Diaz, F. Mohino, E. Sastre, Appl. Catal. A: Gen. 254, 173 (2003)

    Article  Google Scholar 

  25. J.G.C. Shen, R.G. Herman, K. Klier, J. Phys. Chem. B 106, 9975 (2002)

    Article  CAS  Google Scholar 

  26. M.H. Lim, C.F. Blanford, A. Stein, Chem. Mater. 10, 467 (1998)

    Article  CAS  Google Scholar 

  27. I. Díaz, C. Marquez-Alvarez, F. Mohino, J. Pérez-Pariente, E. Sastre, J. Catal. 193, 283 (2000)

    Article  Google Scholar 

  28. X. Wang, S. Cheng, J.C.C. Chan, J. Phys. Chem. C 111, 2156 (2007)

    Article  CAS  Google Scholar 

  29. I. Díaz, F. Mohino, T. Blasco, E. Sastre, J. Pérez-Pariente, Micropor. Mesopor. Mater. 80, 33 (2005)

    Article  Google Scholar 

  30. I. Díaz, F. Mohino, J. Pérez-Pariente, E. Sastre, Appl. Catal. A: Gen. 205, 19 (2001)

    Article  Google Scholar 

  31. I. Díaz, C. Márquez-Alvarez, F. Mohino, J. Pérez-Pariente, E. Sastre, J. Catal. 193, 295 (2000)

    Article  Google Scholar 

  32. J.M. Yang, J. Lü, Chin. J. Chem. 23, 349 (2005)

    Article  CAS  Google Scholar 

  33. R. van Grieken, J.A. Melero, G. Morales, J. Mol. Catal. A: Chem. 256, 29 (2006)

    Article  Google Scholar 

  34. W. Zhao, P. Salamé, V. Herlédan, F. Launay, A. Gédéon (2004) Proceedings of the Fourth International Mesostructured Materials Symposium, Cape Town, May 1st to 4th

  35. S. Habib, P. Salamé, F. Launay, V. Semmer-Herledan, O. Marie, W. Zhao, N. Novak Tusar, A. Gédéon, J. Mol. Catal. A: Chem. 271, 117 (2007)

    Article  CAS  Google Scholar 

  36. J.A. Melero, R. van Grieken, G. Morales, V. Nuño, Catal. Commun. 5, 131 (2004)

    Article  CAS  Google Scholar 

  37. S. Fiorilli, B. Onida, B. Bonelli, E. Garrone, J. Phys. Chem. B. 109, 16725 (2005)

    Article  CAS  Google Scholar 

  38. X.G. Wang, S.F. Cheng, J.C.C. Chan, J.C.H. Chao, Micropor. Mesopor. Mater. 96, 321 (2006)

    Article  CAS  Google Scholar 

  39. L.M. Yang, Y.J. Wang, G.S. Luo, Y.Y. Dai, Micropor. Mesopor. Mater. 84, 275 (2005)

    Article  CAS  Google Scholar 

  40. R. Marschall, I. Bannat, J. Caro, M. Wark, Micropor. Mesopor. Mater. 99, 190 (2007)

    Article  CAS  Google Scholar 

  41. P.F. Siril, A.D. Davison, J.K. Randhawava, D.R. Brown, J. Mol. Catal. A: Chem. 267, 72 (2007)

    Article  CAS  Google Scholar 

  42. S. Coluccia, L. Marchese, G. Martra, Micropor. Mesopor. Mater. 30, 43 (1999)

    Article  CAS  Google Scholar 

  43. G. Busca, Catal. Today 41, 191 (1998)

    Article  CAS  Google Scholar 

  44. L.M. Kustov, Top. Catal. 4, 131 (1997)

    Article  CAS  Google Scholar 

  45. H. Knözinger, S. Huber, J. Chem. Soc., Faraday Trans. 94, 2047 (1998)

    Article  Google Scholar 

  46. H. Pfeifer, Colloids Surfaces 36, 169 (1989)

    Article  CAS  Google Scholar 

  47. H.E. Bergna (ed.), The Colloid Chemistry of Silica (Adv. Chem. Ser. 234) (American Chemical Society, Washington, DC, 1984)

    Google Scholar 

  48. G. Ghiotti, E. Garrone, C. Morterra, F. Boccuzi, J. Phys. Chem. 83, 2863 (1979)

    Article  CAS  Google Scholar 

  49. J.P. Gallas, J.C. Lavalley, A. Burneau, O. Barrès, Langmuir 7, 1235 (1991)

    Article  CAS  Google Scholar 

  50. F. Guenneau, M. Nader, P. Salamé, F. Launay, V. Semmer-Herlédan, A. Gédéon, Catal. Today 103, 126 (2006)

    Article  Google Scholar 

  51. M.H. Nader, F. Guenneau, P. Salamé, F. Launay, V. Semmer-Herledan, A. Gédéon, J. Phys. Chem. C 111, 13564 (2007)

    Article  CAS  Google Scholar 

  52. V. Herlédan-Semmer, S. Dakhlaoui, F. Guenneau, E. Haddad, A. Gédéon, Stud. Surface Sci. Catal. 154, 1519 (2004)

    Article  Google Scholar 

  53. W. Zhao, P. Salamé, F. Launay, A. Gédéon, Z. Hao, J. Porous. Mater. 15, 139 (2008)

    Article  CAS  Google Scholar 

  54. I. Kinski, H. Gies, F. Marlow, Zeolite 19, 1375 (1997)

    Article  Google Scholar 

  55. J. Sauer, P. Ugliengo, E. Garrone, V.R. Saunders, Chem. Rev. 94, 2095 (1994)

    Article  CAS  Google Scholar 

  56. A. Nossov, E. Haddad, F. Guenneau, A. Galarneau, F. Di Renzo, F. Fajula, A. Gédéon, J. Phys. Chem. B 107, 12456 (2003)

    Article  CAS  Google Scholar 

  57. A. Galarneau, M. Nader, F. Guenneau, F. Di Renzo, A. Gédéon, J. Phys. Chem. C 111, 8268 (2007)

    Article  CAS  Google Scholar 

  58. S. Bordiga, C. Lamberti, F. Geobaldo, A. Zecchina, G. Turnes Palomino, C. Otero Arean, Langmuir 11, 527 (1995)

    Article  CAS  Google Scholar 

  59. E.H. Teunissen, R.A. Van Santen, A.P.J. Jansen, F.B. Van Duijneveldt, J. Phys. Chem. 97, 203 (1993)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, CNRS UMR 7142, Université Pierre et Marie Curie, Paris VI, 4, place Jussieu, 75252, Paris, France

    Pétra Salamé, Virginie Semmer-Herlédan, Franck Launay & Antoine Gédéon

  2. Laboratoire Catalyse et Spectrochimie, CNRS-UMR 6506, ENSICAEN, 6 Bd du maréchal Juin, 14050, Caen Cedex, France

    Olivier Marie

  3. Institute of Process Engineering, Chinese Academy of Sciences, 100190, Beijing, People’s Republic of China

    Wei Zhao

Authors
  1. Pétra Salamé
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Olivier Marie
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wei Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Virginie Semmer-Herlédan
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Franck Launay
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Antoine Gédéon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Pétra Salamé or Antoine Gédéon.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Salamé, P., Marie, O., Zhao, W. et al. Infrared investigations of arenesulfonic modified mesoporous materials by the use of complementary probes. J Porous Mater 19, 465–472 (2012). https://doi.org/10.1007/s10934-011-9495-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-011-9495-4

Keywords

Search

Navigation