Abstract
The surface thermodynamics of poly(3-hydroxybutyric acid) (PHBA) as a biodegradable polymer, was characterized using the inverse gas chromatography method. Gel permeation chromatography and differential scanning calorimetry method was also used to measure the molar mass, polydispersity, glass and melting temperatures. Twenty-seven solutes (solvents) with different families having a variety of chemical natures were used to measure the strength of the interaction forces of these solutes with PHBA. All these solutes showed an endothermic interactions which varied from one family to another. All families showed a chemical dependence on the interaction coefficients, a successful correction was used to eliminate the chemical dependence which resulted in exothermic interactions. Retention diagrams of all solvents showed no crystallinity occurred at the temperature range used. The molar heat of sorption of all solutes was measured from the retention diagrams ranged from − 19.41 for acetone to − 90.38 kJ/mol for cyclohexane. The dispersive component of the surface energy of PHBA was measured using alkanes which ranged from 24.42 mJ/m2 at 80 °C to 13.94 mJ/m2 at 120 °C. The decrease in surface energy attributed to the weakening of the surface at a higher temperature due to the melt and expansion of the surface.
Similar content being viewed by others
References
Al-Ghamdi A, Melibari M, Al-Saigh ZY (2005) J Polym Environ 13:319
Batz H-G, Sluka P, Jendrossek D, Steinbuechel A (1995) Eur Pat Appl EP 679412(A1):1102
Jacquel N, Lo CW, Wu HS, Wang SS (2007) AlChE J 53:2704
Senior PJ, Dawes EA (1973) Biochem J 134:225
Dunlop WF, Robards AW (1973) J Bacteriol 114:1271
Ellar D, Lundgren DG, Okamma K, Marchessault RH (1968) J Mol Biol 35:489
Lundgren DG, Pfister RM, Merrick JM (1964) J Gen Microbiol 34:441
Steinbüchel A, Debzi EM, Marchessault RH, Timm A (1993) Appl Microbiol Biotechnol 39:443
Kawaguchi Y, Doi Y (1990) FEMS Microbiol Lett 79:151
Fukui T, Kato M, Matsusaki H, Iwata T, Doi Y (1998) FEMS Microbiol Lett 164:219
Stockdale H, Ribbons DW, Dawes EA (1968) J Bacteriol 95:1798
Soma P, Amal KP (2002) Curr Sci 83:25
Meyers R (ed) (2000) Inverse gas chromatography in analysis of polymers and rubbers. In: Encyclopedia of analytical chemistry: instrumentation and applications, vol 9. Wiley, Chichester, pp 7759–7792
Al-Saigh ZY (1996) Polym Int 40: 25
Al-Saigh ZY (1999) Polymer 40:3479
Chehimi MM, Pigois-Landureau E, Delamar MM (1992) J Chim Phys 89:1173
Landureau E, Chehimi MM (1993) J Appl Polym Sci 49:183
Chehimi MM, Abel ML, Perruchot C, Delamar M, Lascelles SF, Armes SP (1999) Synth Metals 104:51
Papirer E, Eckhardt A, Muller F, Yvon J (1990) J Mater Sci 25:5109
Papirer E, Ligner G, Vidal A, Balard H, Mauss F (1990) In: Leyden E, Collins WT (eds) Chemically modified oxide surfaces. Gordon and Breach, New York, p 361
Papirer E, Balard H, Vidal A (1988) Eur Polym J 24:783
Papirer E, Roland P, Nardin M, Balard H (1986) J Colloid Interface Sci 113:62
Al-Saigh ZY, Chen P (1991) Macromolecules 24:3788
Al-Gahmdi A, Al-Saigh ZY (2000) J Polym Sci B B38:1155
Al-Saigh ZY, Munk P (1984) Macromolecules 17:803
Al-Saigh ZY (1997) Int J Polym Charact Anal 3:249
Papirer E, Brendle E, Ballard H, Vergelati C (2000) J Adhesion Sci Technol 14:321
Tshabalala MA, Denes AR, Williams RS, (1999) J Appl Polym Sci 73:399
Tshabalala MA (1997) J Appl Polym Sci 65:1013
Boutboul A, Lenfant F, Giampaoli P, Feigenbaum A, Ducruet V (2002) J Chromatogr A 969:9
Munk P (1991) Modern methods of polymer characterization. In: Barth H, Mays JW (eds) Chemical analysis: a series of monographs on analytical chemistry and its applications, Winefordner, J. D. series, 113. Wiley, Hoboken, pp 151–200
Fowkes FM (1964) Ind Eng Chem 561:40
Fowkes FM (1967) Ind Eng Chem Prod Res Dev 56:40
Card TW, Al-Saigh ZY, Munk P (1984) J Chromatogr 301:261
Munk P, Hattam P, Abdual-Azim A, Du Q (1990) Makromol Chem Macromol Symp 38:205
Prolongo MG, Masegosa RM, Horta A (1989) Macromolecules 22:4346
Shi ZH, Schreiber HP (1991) Macromolecules 24:3522
Vanlautem N, Gilain J (1982) US Patent 4310684
Terada M, Marchessault RH (1999) Int J Biol Macromol 25:207
Hildebrand J, Scott R (1949) Solubility of non-electrolytes, 3rd edn. Reinhold, New York
Hansen CM (1967) J Paint Technol 39:511
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mosher, H., Al-Saigh, Z.Y. Characterization of Environmentally Friendly Polymers by Inverse Gas Chromatography: II, Poly(3-hydroxybutyric acid). J Polym Environ 27, 74–83 (2019). https://doi.org/10.1007/s10924-018-1317-1
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10924-018-1317-1