Skip to main content
Log in

Novel Fabrication of PAA/PVA/Yeast Superabsorbent with Interpenetrating Polymer Network for pH-Dependent Selective Adsorption of Dyes

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

Traditional superabsorbent polymers have wide application potential as an adsorbent, but the poor physical and mechanical properties limit their further applications. To tentatively overcome this dilemma, a novel poly(acrylic acid)/poly(vinyl alcohol)/yeast superabsorbent polymers (PAA/PVA/yeast SAPs) with interpenetrating polymer networks (IPNs) were fabricated herein via solution polymerization. The mechanical stability tests showed that the resulting products could desirably resist the destruction of shear flow (<5000 rpm) and load pressure (<3 kg). The effects of yeast content, pH, contact time, initial dye concentration and temperature were systematically studied to evaluate their adsorption properties. Consecutive five cycles of adsorption–desorption indicated that their easy regeneration and reusability. More importantly, the PVA/PAA/yeast SAPs displayed brilliant pH-dependent selective adsorption for dyes in dye mixtures. It is believed hereby that the PAA/PVA/yeast SAPs can be expected to be economically and technically feasible for the scalable treatment of dyes wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Bao Y, Ma JZ, Li N (2011) Synthesis and swelling behaviors of sodium carboxymethyl cellulose-g-poly(AA-co-AM-co-AMPS)/MMT superabsorbent hydrogel. Carbohyd Polym 84:76–82.

    Article  CAS  Google Scholar 

  2. Sen G, Ghosh S, Jha U, Pal S (2011) Hydrolyzed polyacrylamide grafted carboxymethylstarch (Hyd. CMS-g-PAM): an efficient flocculant for the treatment of textile industry wastewater. Chem Eng J 171:495–501

    Article  CAS  Google Scholar 

  3. Zheng YA, Zhu YF, Wang AQ (2014) Highly efficient and selective adsorption of malachite green onto granular composite hydrogel. Chem Eng J 257:66–73

    Article  CAS  Google Scholar 

  4. Ferfera-Harrar H, Aiouaz N, Dairi N, Hadj-Hamou AS (2014) Preparation of chitosan-g-poly(acrylamide)/montmorillonite superabsorbent polymer composites: studies on swelling, thermal, and antibacterial properties. J Appl Polym Sci 131:1–15

    Article  Google Scholar 

  5. Cheng ZQ, Li JF, Yan JT, Kang LJ, Ru X, Liu MZ (2013) Synthesis and properties of a novel superabsorbent polymer composite from microwave irradiated waste material cultured Auricularia auricula, and poly(acrylic acid-co-acrylamide). J Appl Polym Sci 130:3674–3681

    Article  CAS  Google Scholar 

  6. Saber-Samandari Samaneh, Saber-Samandari Saeed, Mustafa G (2013) Cellulose-graft-polyacrylamide/hydroxyapatite composite hydrogel with possible application in removal of Cu (II) ions. React Funct Polym 73:1523–1530

    Article  Google Scholar 

  7. Fu ZY, He CL, Li HB, Yan C, Chen LM, Huang JH, Liu YN (2015) A novel hydrophilic–hydrophobic magnetic interpenetrating polymer networks (IPNs) and its adsorption towards salicylic acid from aqueous solution. Chem Eng J 279:250–257

    Article  CAS  Google Scholar 

  8. Mandal BM, Ray SK, Bhattacharyya RB (2012) Synthesis of full and semi Interpenetrating hydrogel from polyvinyl alcohol and poly(acrylic acid-co-hydroxyethylmethacrylate) copolymer: study of swelling behavior, network parameters, and dye uptake properties. J Appl Polym Sci 124:2250–2268

    Article  CAS  Google Scholar 

  9. Li Q, Liu J, Su Y, Yue QY, Gao BY (2012) Synthesis and swelling behaviors of semi-IPNs superabsorbent resin based on chicken feather protein. J Appl Polym Sci 18:4505–4509

    Google Scholar 

  10. Wang L, Zhang JP, Wang AQ (2011) Fast removal of methylene blue from aqueous solution by adsorption onto chitosan-g-poly(acrylic acid)/attapulgite composite. Desalination 266:33–39

    Article  CAS  Google Scholar 

  11. Mahdavinia GR, Asgari A (2013) Synthesis of kappa-carrageenan-g-poly(acrylamide)/sepiolite nanocomposite hydrogels and adsorption of cationic dye. Polym Bull 70:2451–2470.

    Article  CAS  Google Scholar 

  12. Shirsath SR, Patil AP, Patil R, Naik JB, Gogate PR, Sonawane SH (2012) Removal of Brilliant Green from wastewater using conventional and ultrasonically prepared poly(acrylic acid) hydrogel loaded with kaolin clay: A comparative study. Ultrason Sonochem 20:914–923

    Article  Google Scholar 

  13. Zheng Y, Wang AQ (2009) Evaluation of ammonium removal using a chitosan-g-poly(acrylic acid)/rectorite hydrogel composite. J Hazard Mater 171:671–677

    Article  CAS  Google Scholar 

  14. Feng DJ, Bo B, Ding CX, Wang HL, Suo YR (2014) Synthesis and swelling behaviors of yeast-g-poly(acrylic acid) superabsorbent co-polymer. Ind Eng Chem Res 53:12760–12769

    Article  CAS  Google Scholar 

  15. Nguyen TH, Fleet GH, Rogers PL (1998) Composition of the cell walls of several yeast species. Appl Microbiol Biot 50:206–212

    Article  CAS  Google Scholar 

  16. Magnelli P, Cipollo JF, Abeijon C (2002) A refined method for the determination of saccharomyces cerevisiae, cell wall composition and β-1,6-glucan fine structure. Anal Biochem 301:136–150

    Article  CAS  Google Scholar 

  17. Aguilar-Uscanga B, François JM (2003) A study of the yeast cell wall composition and structure in response to growth conditions and mode of cultivation. Lett Appl Microbiol 37:268–274

    Article  CAS  Google Scholar 

  18. Chen L, Bai B (2013) Equilibrium, kinetic, thermodynamic, and in situ regeneration studies about methylene blue adsorption by the raspberry-like TiO2 @ yeast microspheres. Ind Eng Chem Res 52:15568–15577

    Article  CAS  Google Scholar 

  19. Bo B, Quici N, Li ZY, Puma GL (2011) Novel one step fabrication of raspberry-like TiO2@yeast hybrid microspheres via electrostatic-interaction-driven self-assembled hetero coagulation for environmental applications. Chem Eng J 170:451–456

    Article  Google Scholar 

  20. Bhattacharyya R, Ray SK (2015) Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol. Chem Eng J 260:269–283

    Article  CAS  Google Scholar 

  21. Feng DJ, Bai B, Wang HL, Suo YR (2016) Enhanced mechanical stability and sensitive swelling performance of chitosan/yeast hybrid hydrogel beads. New J Chem 40:3350–3362

    Article  CAS  Google Scholar 

  22. Liu P, Jiang LP, Zhu LX, Wang AQ (2014) Novel covalently cross-linked attapulgite/poly(acrylic acid-co-acrylamide) hybrid hydrogels by inverse suspension polymerization: Synthesis optimization and evaluation as adsorbents for toxic heavy metals. Ind Eng Chem Res 53:4277–4285

    Article  CAS  Google Scholar 

  23. Dragan ES, Apopei DF (2011) Synthesis and swelling behavior of pH-sensitive semi-interpenetrating polymer network composite hydrogels based on native and modified potatoes starch as potential sorbent for cationic dyes. Chem Eng J 178:252–263

    Article  CAS  Google Scholar 

  24. Wang YZ, Wang WB, Wang AQ (2013) Efficient adsorption of methylene blue on an alginate-based nanocomposite hydrogel enhanced by organo-illite/smectite clay. Chem Eng J 228:132–139

    Article  CAS  Google Scholar 

  25. Zhu HY, Fu Y, Jiang R, Yao J, Xiao L, Zeng GM (2011) Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: Preparation, characterization and application for adsorption of dye from aqueous solution. Bioresource Technol 105:24–30

    Article  Google Scholar 

  26. Habiba U, Islam MS, Siddique TA, Afifi AM, Ang BC (2016) Adsorption and photocatalytic degradation of anionic dyes on chitosan/PVA/Na–Titanate/TiO2, composites synthesized by solution casting method. Carbohydr Polym 149:317–331.

    Article  CAS  Google Scholar 

  27. Moscoso-Londoño O, Gonzalez JS, Muraca D, Hoppe CE, Alvarez VA, Quintela AL, Socolovsky LM, Pirota KR (2013) Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles. Eur Polym J 49:279–289

    Article  Google Scholar 

  28. Feng DJ, Bai B, Wang HL, Suo YR (2015) Thermo-chemical modification to produce citric acid–yeast superabsorbent composites for ketoprofen delivery. RSC Adv 5:104756–104768.

    Article  CAS  Google Scholar 

  29. Liu J, Li Q, Su Y, Yue QY, Gao BY, Wang R (2013) Synthesis of wheat straw cellulose-g-poly (potassium acrylate)/PVA semi-IPNs superabsorbent resin. Carbohydr Polym 94:539–546.

    Article  CAS  Google Scholar 

  30. Maiolo AS, Amado MN, Gonzalez JS, Alvarez VA (2012) Development and characterization of poly(vinyl alcohol) based hydrogels for potential use as an articular cartilage replacement. Mat Sci Eng C 32:1490–1495.

    Article  CAS  Google Scholar 

  31. Cong HP, Wang P, Yu SH (2014) Highly elastic and super stretchable graphene oxide/polyacrylamide hydrogels. Small 10:448–453

    Article  CAS  Google Scholar 

  32. Saquib M, Tariq MA, Haque MM, Muneer M (2008) Photocatalytic degradation of disperse blue 1 using UV/TiO2/H2O2 process. J Environ Manage 88:300–306

    Article  CAS  Google Scholar 

  33. Vimonses V, Lei SM, Jin B, Chow CWK, Saint C (2009) Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials. Chem Eng J 148:354–364

    Article  CAS  Google Scholar 

  34. Liu JS, Ma S, Zang LJ (2013) Preparation and characterization of ammonium-functionalized silica nanoparticle as a new adsorbent to remove methyl orange from aqueous solution. Appl Surf Sci 265:393–398

    Article  CAS  Google Scholar 

  35. Bayramoglu G, Altintas B, Arica MY (2009) Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin. Chem Eng J 152:339–346

    Article  CAS  Google Scholar 

  36. Mahmoodi NM (2014) Binary catalyst system dye degradation using photocatalysis. Fiber Polym 15:273–280.

    Article  CAS  Google Scholar 

  37. Farah JY, El-Gendy NS, Farahat LA (2007) Biosorption of astrazone blue basic dye from an aqueous solution using dried biomass of Baker’s yeast. J Hazard Mater 148:402–408

    Article  CAS  Google Scholar 

  38. Qada ENE, Allen SJ, Walker GM (2006) Adsorption of Methylene blue onto activated carbon produced from steam activated bituminous coal: a study of equilibrium adsorption isotherm. Chem Eng J 124:103–110

    Article  Google Scholar 

  39. Maurya NS, Mittal AK, Cornel P, Rother E (2006) Biosorption of dyes using dead macro fungi: Effect of dye structure, ionic strength and pH. Bioresource Technol 97:512–521

    Article  CAS  Google Scholar 

  40. Hackley VA (1997) Colloidal processing of silicon nitride with poly(acrylic acid): I, Adsorption and electrostatic interactions. J Am Ceram Soc 80:2315–2325

    Article  CAS  Google Scholar 

  41. Tang YJ, Wang X, Zhu LH (2013) Removal of methyl orange from aqueous solutions with poly(acrylic acid-co-acrylamide) superabsorbent resin. Polym Bull 70:905–918.

    Article  CAS  Google Scholar 

  42. Jing ZX, Zhang GC, Sun XF, Shi XT, Sun WM (2014) Preparation and adsorption properties of a novel superabsorbent based on multiwalled carbon nanotubes–xylan composite and poly(methacrylic acid) for methylene blue from aqueous solution. Polym Compos 35:1516–1528.

    Article  CAS  Google Scholar 

  43. Anirudhan TS, Tharun AR (2012) Preparation and adsorption properties of a novel interpenetrating polymer network (IPN) containing carboxyl groups for basic dye from aqueous media. Chem Eng J 181–182:761–769.

    Article  Google Scholar 

  44. Bhattacharyya R, Ray SK (2013) Kinetic and equilibrium modeling for adsorption of textile dyes in aqueous solutions by carboxymethyl cellulose/poly(acrylamide-co-hydroxyethy methacrylate) semi-interpenetrating network hydrogel. Polym Eng Sci 53:2439–2453

    Article  CAS  Google Scholar 

  45. Lagergren S, Svenska BK (1898) Zur theorie der sogenannten adsorption geloester stoffe, Vetenskapsakad Handlingar 24:1–39.

  46. Ho YS, Mckay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–124

    Article  CAS  Google Scholar 

  47. Ai LH, Li M, Li L (2011) Adsorption of methylene bue from aqueous solution with activated carbon/cobalt ferrite/alginate composite beads: kinetics, isotherms, and thermodynamics. J Chem Eng Data 56:3475–3483

    Article  CAS  Google Scholar 

  48. Wu FC, Tseng RL, Juang RS (2009) Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chem Eng J 150:366–373

    Article  CAS  Google Scholar 

  49. Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM (2006) Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloid Surfaces A 272:89–104

    Article  CAS  Google Scholar 

  50. Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. ASCE Sanit Engng Div J 1:1–2.

    CAS  Google Scholar 

  51. Kannan N, Sundaram MM (2001) Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study. Dyes Pigments 51:25–40.

    Article  CAS  Google Scholar 

  52. Lorenc-Grabowska E, Gryglewicz G (2007) Adsorption characteristics of congo red on coal-based mesoporous activated carbon. Dyes Pigments 74:34–40.

    Article  CAS  Google Scholar 

  53. Özcan AS, Özcan A (2004) Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite. J Colloid Interface Sci 276:39–46

    Article  Google Scholar 

  54. Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403

    Article  CAS  Google Scholar 

  55. Hall KR, Eagleton LC, Acrivos A, Vermeulen T (1966) Pore- and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Ind Eng Chem Fundam 5:587–594

    Article  Google Scholar 

  56. Freundlich HMF (1906) Uber die adsorption in losungen. J Phys Chem 57A:385–470

    Google Scholar 

  57. Haghseresht F, Lu GQ (1998) Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents. Energ Fuel 12:1100–1107

    Article  CAS  Google Scholar 

  58. Fytianos K, Voudrias E, Kokkalis E (2000) Sorption–desorption behaviour of 2,4-dichlorophenol by marine sediments. Chemosphere 40:3–6

    Article  CAS  Google Scholar 

  59. Rubín E, Rodríguez P, Herrero R, Vicente MESD (2010) Adsorption of methylene blue on chemically modified algal biomass: equilibrium, dynamic, and surface data. J Chem Eng Data 55:727–734

    Article  Google Scholar 

  60. Deng H, Lu JJ, Li GX, Zhang GL, Wang XG (2011) Adsorption of methylene blue on adsorbent materials produced from cotton stalk. Chem Eng J 172:326–334

    Article  CAS  Google Scholar 

  61. Pang XL, Peng HL, Yang HS, Gao KW, Wu XL, Volinsky AA (2013) Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chem Eng Res Des 91:361–368

    Article  Google Scholar 

  62. Liu FF, Teng SX, Song RH, Wang SG (2010) Adsorption of methylene blue on anaerobic granular sludge: effect of functional groups. Desalination 263:11–17

    Article  CAS  Google Scholar 

  63. Li J, Huang Y, Liu ZY, Zhang J, Liu XX, Luo H, Ma YH, Xu XW, Lu Y, Lin J, Zou J, Tang CC (2015) Chemical activation of boron nitride fibers for improved cationic dye removal performance. J Mater Chem A 3:8185–8193

    Article  CAS  Google Scholar 

  64. Shukla NB, Rattan S, Madras G (2012) Swelling and dye-adsorption characteristics of an amphoteric superabsorbent polymer. Ind Eng Chem Res 51:14941–14948

    Article  CAS  Google Scholar 

  65. Singh T, Singhal R (2012) Poly(acrylic acid/acrylamide/sodium humate) superabsorbent hydrogels for metal ion/dye adsorption: effect of sodium humate concentration. J Appl Polym Sci 125:1267–1283

    Article  CAS  Google Scholar 

  66. Pourjavadi A, Nazari M, Kabiri B, Hosseini SH, Bennett C (2016) Preparation of porous graphene oxide/hydrogel nano composites and their ability for efficient adsorption of methylene blue. RSC Adv 6:10430–10437.

    Article  CAS  Google Scholar 

  67. Dubinin MM, Zaverina ED, Radushkevich LV (1947) Sorption and structure of active carbons. I. Adsorption of organic vapors. Zh Fiz Khim 21:1351–1362.

    CAS  Google Scholar 

  68. Caliskan N, Kul AR, Alkan S, Sogut EG, Alacabey I (2011) Adsorption of Zinc(II) on diatomite and manganese-oxide-modified diatomite: a kinetic and equilibrium study. J Hazard Mater 193:27–36

    Article  CAS  Google Scholar 

  69. Ahmad A, Rafatullah M, Sulaiman O, Ibrahim MH, Hashim R (2009) Scavenging behaviour of meranti sawdust in the removal of methylene blue from aqueous solution. J Hazard Mater 170:357–365

    Article  CAS  Google Scholar 

  70. Hasan M, Ahmad AL, Hameed BH (2008) Adsorption of reactive dye onto cross-linked chitosan/oil palm ash composite beads. Chem Eng J 136:164–172

    Article  CAS  Google Scholar 

  71. Ma J, Yu F, Zhou L, Yang MX, Luan JS, Tang YH, Fan HB, Yuan ZW, Chen JH. (2012) Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes. ACS Appl Mater Interfaces 4:5749–5760.

    Article  CAS  Google Scholar 

  72. Ghaedi M, Karimi F, Barazesh B, Sahraei R, Daneshfar A (2013) Removal of reactive orange 12 from aqueous solutions by adsorption on tin sulfide nanoparticle loaded on activated carbon. J Ind Eng Chem 19:756–763

    Article  CAS  Google Scholar 

  73. Horsfall M, Spiff AI (2005) Effects of temperature on the sorption of Pb2 + and Cd2 + from aqueous solution by caladium bicolor (wild cocoyam) biomass. Electron J Biotechn 8:43–50.

    Google Scholar 

  74. Abasi CY, Abia AA, Igwe JC (2012) Adsorption of iron (III), lead (II) and cadmium (II) ions by unmodified raphia palm (Raphia hookeri) fruit endocarp. Environ Res J 5:104–113

    Google Scholar 

  75. Mall ID, Srivastava VC, Kumar GVA, Mishra IM (2006) Characterization and utilization of mesoporous fertilizer plant waste carbon for adsorptive removal of dyes from aqueous solution. Colloid Surfaces A 278:175–187

    Article  CAS  Google Scholar 

  76. Chatterjee S, Lee DS, Lee MW, Woo SH (2009) Congo red adsorption from aqueous solutions by using chitosan hydrogel beads impregnated with nonionic or anionic surfactant. Bioresource Technol 100:3862–3868

    Article  CAS  Google Scholar 

  77. Wang ZX, Guo J, Ma J, Shao L (2015) Highly regenerable alkali-resistant magnetic nanoparticles inspired by mussels for rapid selective dye removal offer high-efficiency environmental remediation. J Mater Chem A 3:19960–19968

    Article  CAS  Google Scholar 

  78. Okesola BO, Smith DK (2013) Versatile supramolecular pH-tolerant hydrogels which demonstrate pH-dependent selective adsorption of dyes from aqueous solution. Chem Commun 49:11164–11166

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by Shaanxi Provincial Natural Science Foundation of China (No. 2015JM2071), Fundamental Research Funds for the Central Universities (No. 310829162014, No. 310829161015, and No. 310829165007).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bo Bai.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 340 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Feng, D., Bai, B., Wang, H. et al. Novel Fabrication of PAA/PVA/Yeast Superabsorbent with Interpenetrating Polymer Network for pH-Dependent Selective Adsorption of Dyes. J Polym Environ 26, 567–588 (2018). https://doi.org/10.1007/s10924-017-0972-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-017-0972-y

Keywords

Navigation