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Properties of Glauconite/Polyaniline Composite Prepared in Aqueous Solution of Citric Acid

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Abstract

Hybrid composite made of glauconite and polyaniline was prepared in aqueous solution of citric acid. Scanning electron microscopy combined with energy dispersive X-ray analysis shows uniform aggregates made of glauconite microparticles and polyaniline matrix. The results of X-ray powder diffraction suggest that: (1) citric acid used for the polymerisation of aniline causes formation of emeraldine salt where macromolecular ordering in the amorphous polymer takes place; (2) no chemical interaction between glauconite and emeraldine takes place in the prepared composite. FT-IR spectra of the prepared polymer and composite show features indicating all the functional groups that are present in the diiminoquinone–diaminobenzene state of polyaniline. Thermal stability of the composite was higher than the prepared polymer suggesting the occurrence of an interphase interaction between glauconite and emeraldine. After pyrolysis in purified nitrogen the composite still remained glauconite, and ε-Fe3N together with amorphous and graphitic carbon were found as reaction products. The values of electrical conductivity and magnetization of the composite suggest that optimization of these values might be achieved based upon the relationship between glauconite and polyaniline.

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Acknowledgments

The research work was financially supported by Cariplo2013-0592 project received by Cariplo Italian Foundation and XФ-149Ф project of the Ministry of Education and Science of Ukraine. All authors affiliated to Department of Chemistry and CSGI acknowledge financial support from CSGI (Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase).

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Authors and Affiliations

  1. Department of Physical and Colloid Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodia 6, Lviv, 79005, Ukraine

    Mykhaylo Yatsyshyn, Ivan Saldan, Viktoriia Makogon & Oleksandr Reshetnyak

  2. Department of Chemistry, CSGI, University of Pavia, Viale Taramelli 12-16, 27100, Pavia, Italy

    Ivan Saldan, Chiara Milanese, Alberto Zeffiro, Rosadele Di Lorenzo, Pacifico Cofrancesco, Alessandro Girella & Daniele Dondi

  3. Department of Physics, University of Pavia, Via Bassi 6, 27100, Pavia, Italy

    Vittorio Bellani

  4. Karpenko Physical-Mechanical Institute of the NASU, Naukova 5, Lviv, 79060, Ukraine

    Sergiy Korniy

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  1. Mykhaylo Yatsyshyn
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  2. Ivan Saldan
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Correspondence to Ivan Saldan.

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Yatsyshyn, M., Saldan, I., Milanese, C. et al. Properties of Glauconite/Polyaniline Composite Prepared in Aqueous Solution of Citric Acid. J Polym Environ 24, 196–205 (2016). https://doi.org/10.1007/s10924-016-0763-x

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