Abstract
A study on chemical, morphology, and thermal analysis of cultivated pineapple leaf fibres (PALF) were carried out. The chemical compositions were determined by using Technical Association Pulp and Paper Industries standards. Fourier Transform-Infrared Spectroscopy analysis of PALF detect sharp band at 1,733 cm−1, due to the absorption of carbonyl stretching of ester and carboxyl groups which is most abundant in pineapple leaf hemicelluloses. Cell wall ultra structure of PALF was studied by using Transmission electron microscopy. Transmission electron micrograph confirmed that cell wall structure of PALF consists of middle lamella, primary wall and secondary wall including S1, S2 and S3 layers. X-Ray Diffraction indicated that PALF have crystalline nature. Thermal analysis of PALF shows that T10% and T50% weight loss occurred at temperature of 212 and 306 °C respectively. Differential Scanning Calorimetry of PALF showed the broad endothermic peak at a temperature of 80 °C. The relationships between these properties were discussed and relate it with industrial application of pineapple leaf fibers.
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References
Reddy N, Yang Y (2005) Trends Biotechnol 23:22
Tran AV (2006) Ind Crop Prod 24:66
FAO (Food and Agriculture Organization of the United Nations) Statistical Database (FAOSTAT) (2008) [Online]. http://www.fao.org. Accessed 6 July 2011
Munirah M, Rahmat AR, Hassan A (2007) Characterization and treatments of pineapple leaf fibre. Department of Polymer Engineering, Faculty of Chemical and Natural Resources Engineering, Malaysia Technology University, Johor Bharu
Bartholomew DP, Paull RE, Rohrbach KG (2003) The pineapple: botany, production and use. CABI Publishing, Wellingford, UK
Py C, Lacoeuilhe JJ, Teisson C (1987) The pineapple: cultivation and uses. Maisonneuve & Larose, Quae
Cherian BM, Leao AL, de Souza SF, Thomas S, Pothan LA, Kottaisamy M (2010) Carbohydr. Polym 81:720
Uma Devi L, Bhagawan SS, Thomas S (1997) J Appl Polym Sci 64:1739
Chollakup R, Tantatherdtam R, Ujjin S, Sriroth K (2010) J Appl Polym Sci 119:1952
Mishra S, Mohanty AK, Drzal LT, Misra M, Hinrichsen G (2004) J Macromol Mater Eng 289:955
Mukherjee PS, Satyanarayana KG (1986) J Mater Sci 21:51
Nieschlag HJ, Nelson GH, Wolff JA, Perdue RE (1960) Tappi 433:193
Panshin A, Dezeeuw C (1980) Textbook of wood technology, 4th edn. McGraw-Hill, New York
Abdul Khalil HPS, Siti Alwani M, Ridzuan R, Kamarudin H, Khairul A (2008) Polym Plast Technol 47:273
Abdul Khalil HPS, Siti Alwani M, Mohd Omar AK (2006) Cell wall of tropical fibers. BioResources 12:220
Wirawan R, Zainudin ES, Sapuan SM (2009) Sains Malays 38:531
Abdul Khalil HPS, Ireana Yusra AF, Bhat AH, Jawaid M (2010) Ind Crop Prod 31:113
Ververis C, Georghiou K, Christodoulakis N, Santas P, Santas R (2004) J Ind Crops Prod 19:245–254
Herbert Morrison W III, Akin DE, Archilbald DD, Dodd RB, Paul LR (1999) Ind Crops Prod 10:21–34
Mui ELK, Cheung WH, Lee VKC, McKay G (2008) Ind Eng Chem Res 47:5710–5722
Harada H, Cote WA Jr (1985) In: Higuchi T (ed) Biosynthesis and biodegradation of wood components. Academic Press, Orlando
Booker RE, Sell J (1998) Holz Roh Werstoff 56:1–8
Law KN, Jiang XF (2001) Tappi J 841:95
Ramiah MV (1970) J Appl Polym Sci 14:1323
Stout HP, Jenkins JA (1955) Ann Text Belg 4:231
Siregar JP, Mohd SS, Rahman MZ, Dahlan KZ (2011) Pertanika J Sci Technol 191:161
Akita K, Kase MJ (1967) Polym Sci A I 5:833
Remiro PM, Cortazar M, Calahorra E, Calafel M (2002) Polym Degrad Stab 78:83
Chu NJ (1970) J Appl Polym Sci 14:3129
Lopattananon N, Panawarangkul K, Sahakaro K, Ellis B (2006) J Appl Polym Sci 102:1974
Pineapple Paper Furniture by Yothaka (2008) [Online]. http://inhabitat.com/pineapple-paper-furniture-by-yothaka/. Accessed 2 Oct 2011
Banik S, Dey SK, Nag D (2011) Indian J Fibre Text 36:172
Leao AL, Souza SF, Cherian BM, Frollini E, Thomas S, Pothan LA, Kottaisamy M (2010) Mol Cryst Liq Cryst 522:318
Abraham E, Deepa B, Pothana LA, Jacob M, Thomas S, Cvelbard U, Anandjiwala R (2011) Carbohydr Polym 86:1468
Cherian BM, Leão AL, de Souza SF, Costa LMM, de Olyveira GM, Kottaisamy M, Nagarajan ER, Thomas S (2011) Carbohydr Polym 86:1790
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The researchers would like to thank the Universiti Sains Malaysia, Penang for providing the Research Universiti (RU) Grant (1001/PTEKIND/814133) that has made this work possible.
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Wan Nadirah, W.O., Jawaid, M., Al Masri, A.A. et al. Cell Wall Morphology, Chemical and Thermal Analysis of Cultivated Pineapple Leaf Fibres for Industrial Applications. J Polym Environ 20, 404–411 (2012). https://doi.org/10.1007/s10924-011-0380-7
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DOI: https://doi.org/10.1007/s10924-011-0380-7