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Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3

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Abstract

This paper describes the CaTi1−xMnxO3 (x = 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO3 system through X-ray diffraction patterns (XRD), scanning electron microscopy + electron-dispersive spectroscopy (SEM + EDS), and vibrating sample magnetometry. Rietveld analysis of the XRDs at room temperature evidenced that the samples crystallized in the Pnma (62) space group. Likewise, the XRDs showed that lattice parameters decreased when increasing Mn content. The SEM + EDS results exhibited typical features of samples obtained by SSR at high temperatures. The zero-field cooling and field cooling curves of magnetization in temperatures ranging from 50 to 300 K showed paramagnetic behavior in the applied field for each Mn-doped sample with a possible weak ferromagnetic-like ordering. Conversely, the CaMnO3 sample exhibited antiferromagnetic ordering with TN near 113.26 K.

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Acknowledgements

COLCIENCIAS 785-2017 (Cesar Camilo Canaría Camargo) greatly contributed for the development of this study. Likewise, this study was supported by Centro de Microscopia Electrônica do Sul (CEME-Sul) of FURG by XRD and SEM measurements and Universidad Pedagógica y Tecnológica de Colombia.

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Authors and Affiliations

  1. Grupo Física de Materiales, Escuela de Física, Universidad Pedagógica Y Tecnológica de Colombia, Avenida Central del Norte 39-115, Tunja, Boyacá, 150003, Colombia

    I. M. Saavedra Gaona, C. Canaria & C. A. Parra Vargas

  2. Grupo de Investigación en Ingeniería Electrónica, Universidad Pedagógica Y Tecnológica de Colombia, Avenida Central del Norte 39-115, Tunja, Boyacá, 150003, Colombia

    E. W. Caro Anzola

  3. Grupo de Investigación en Telemática y TIC Aplicada a la Educación, Facultad de Ingeniería, Universidad Pedagógica Y Tecnológica de Colombia, Avenida Central del Norte 39-115, Tunja, Boyacá, 150003, Colombia

    M. A. Mendoza Moreno & C. L. Sánchez Sáenz

  4. Instituto de Matemática, Estatística e Física, Universidade Federal Do Rio Grande, Campus Carreiros, Avenida Itália Km 8, Bairro Carreiros, Rio Grande, Rio Grande do Sul, 96203-900, Brazil

    A. M. Turatti & J. L. Pimentel Jr

  5. Instituto de Física, Universidade Federal Do Rio Grande, Porto Alegre, Rio Grande Do Sul, 91570-970, Brazil

    F. Mesquita

Authors
  1. I. M. Saavedra Gaona
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  2. E. W. Caro Anzola
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  3. M. A. Mendoza Moreno
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  4. C. L. Sánchez Sáenz
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  5. C. Canaria
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  6. A. M. Turatti
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  7. J. L. Pimentel Jr
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  8. F. Mesquita
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  9. C. A. Parra Vargas
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Correspondence to I. M. Saavedra Gaona.

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Saavedra Gaona, I.M., Anzola, E.W.C., Moreno, M.A.M. et al. Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3. J Low Temp Phys 204, 85–94 (2021). https://doi.org/10.1007/s10909-021-02600-z

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  • DOI: https://doi.org/10.1007/s10909-021-02600-z

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