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Pressurized 4He in Cylindrical and in Hexagonal Pores

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We give a variational Monte Carlo description at T = 0 K of 4He filling under pressure a porous glass within the shadow wave function technique. We have considered as confining media two different smooth pores, one with a circular cross-section of radius R = 13 Å resembling a Gelsil pore, and the other with a hexagonal cross–section of side S = 14 Å resembling a FSM-16 pore. In all the studied cases the density profiles show a strong layering of the 4He atoms. As the density is increased, solidification takes place layer by layer, starting from the pore wall. Computing the one-body density matrix we are able to estimate the Bose–Einstein condensate fraction, which is still non–zero even when the whole system is in the solid phase.

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Rossi, M., Galli, D.E. & Reatto, L. Pressurized 4He in Cylindrical and in Hexagonal Pores. J Low Temp Phys 146, 95–114 (2007). https://doi.org/10.1007/s10909-006-9265-x

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