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Heteronuclear Hexacyanometallate(III) Coordination Polymers (Cd/Cr, Cd/Fe, Cd/Co) with 3-(Aminomethyl)pyridine: Synthesis, Characterization, and Catalytic Activities for the Peroxidative Oxidation of Benzylic Alcohols

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Abstract

Three new heteronuclear hexacyanometallate(III) coordination polymers (CPs), [Cd3(µ-3ampy)4(H2O)4Cr2(µ-CN)8(CN)4]n (1), [Cd3(µ-3ampy)2(H2O)2Fe2(µ-CN)5(CN)7]n (2) and [Cd3(µ-3ampy)4(H2O)4Co2(µ-CN)8(CN)4]n (3), were synthesized with 3-(aminomethyl)pyridine (3ampy) ligand. All CPs were characterized by FT-IR, Raman, elemental, thermal analysis as well as single crystal X-ray diffraction and powder X-ray diffraction techniques. The single crystal X-ray diffraction analyses shows that the CPs 1 and 3 are two-dimensional structures, whereas CP 2 is a three-dimensional structure where two adjacent metal ions ions are linked via 3ampy and CN bridges. The coordination spheres of all CPs show distorted octahedral geometries. CP 3 was mainly tested as heterogenous catalyst for peroxidative oxidation of benzyl alcohol and its derivatives (4-chloro, 4-bromo, 4-methyl, 4-metoxy and 4-nitro benzyl alcohol). From the results, the highest aldehyde formation was obtained from the oxidation of benzyl alcohol with overall yield as 100%. In addition, catalytic reactions exhibited high selectivity towards aldehyde and no over-oxidation product (carboxylic acid) was observed.

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Acknowledgements

The authors acknowledge Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.

Funding

This work has been financially supported by Eskişehir Osmangazi University, Scientific research Unit [Grant No: 2022-2561].

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Eskişehir Osmangazi University, 26040, Eskisehir, Turkey

    Seray Kekeç & Güneş Süheyla Kürkçüoğlu

  2. Department of Chemistry, Faculty of Science, Eskişehir Technical University, 26555, Eskisehir, Turkey

    Hakan Ünver

  3. Department of Occupat Health & Safety, School of Health, Sinop University, 57000, Sinop, Turkey

    Onur Şahin

  4. Department of Chemistry, Faculty of Science, Eskişehir Osmangazi University, 26040, Eskisehir, Turkey

    Okan Zafer Yeşilel

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  1. Seray Kekeç
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Kekeç, S., Kürkçüoğlu, G.S., Ünver, H. et al. Heteronuclear Hexacyanometallate(III) Coordination Polymers (Cd/Cr, Cd/Fe, Cd/Co) with 3-(Aminomethyl)pyridine: Synthesis, Characterization, and Catalytic Activities for the Peroxidative Oxidation of Benzylic Alcohols. J Inorg Organomet Polym 34, 1081–1091 (2024). https://doi.org/10.1007/s10904-023-02861-z

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