Abstract
Spun calcination introduces a novel approach for the development of materials suitable for optoelectronic applications, particularly carbon-based materials. In this study, we utilized the spun calcination technique to design rGO and rGO@CNF nanocomposites with the help of C20H38O11. By subjecting polymeric nanofibers to thermal reduction, we successfully achieved the formation of rGO and rGO@CNF, as confirmed by peak resolution in X-Ray diffraction analysis. The nanocomposites exhibited a crystalline phase, with average crystallite sizes of approximately 1.33 nm and 1.22 nm for rGO and rGO@CNF, respectively. The Raman spectroscopy shows intense G and D-bands observed in the spectra further supported the formation of these carbon-based materials, with IG/ID intensity ratios of approximately 0.85 and 0.87 for rGO and rGO@CNF, respectively. The photoluminescence study shows the structural growth of the nanocomposite indicated the diffusion of carbon surfaces, which revealed that both rGO and rGO@CNF shows lower electron-hole pair recombination rate. Consequently, these materials exhibited a considerable number of delocalized free electrons, leading to enhanced photoluminescence activity.
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Funding
Science and Engineering Research Board (SERB), Department of Science and Technology India, supported this work for providing the facilities and financial support to undertake the investigations. The section order no. of the project is (SPG/2021/004175).
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SK: Methodology, Writing- Original draft preparation, GAK: Methodology, Software, NK: Data Curation, Formal analysis, AG: Resources, Validation, MS: Investigation, Reviewing and Editing.
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Kumar, S., Kaur, G.A., Kumari, N. et al. Surface Modification of Carbon Nanofiber with C20H38O11 Polymer by Spun Calcination Method. J Inorg Organomet Polym 34, 336–345 (2024). https://doi.org/10.1007/s10904-023-02827-1
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DOI: https://doi.org/10.1007/s10904-023-02827-1