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Carboxymethyl Chitosan–Magnetite Nanocomposites Immobilized with Pd as Reusable Catalysts for the Reduction of 4-nitrophenol and Methylene Blue

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Abstract

This work presented the synthesis of magnetite nanoparticle (Fe3O4) coated with carboxymethyl chitosan (CMC)-based polymers with/without amino-rich poly(2-(diethyl amino)ethyl methacrylate (PDEAEMA) for the coordination with Pd and its use as a reusable catalyst for the reduction of 4-nitrophenol (4NP) and methylene blue (MB). The amino and hydroxy groups in CMC provided good water dispersibility and served as good ligands for coordination with Pd, while the abundant amino groups in PDEAEMA increased the immobilizing stability of Pd in the nanocomposite. It was found that the average diameter of Fe3O4 was 11.73 ± 2.12 nm in diameter and those of Pd was 5.91 ± 1.07 nm with the Pd contents of 0.06–7.62 wt%. The catalyst without PDEAEMA exhibited high catalytic activity for the reduction of both 4NP and MB than those having PDEAEMA. Interestingly, the catalyst containing PDEAEMA showed more recycling durability for the 4NP reduction than the other and these corresponded well to the Pd leaching results.

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Acknowledgements

This project is funded by National Research Council of Thailand (NRCT) and Naresuan University (N42A650330). U. Mahanitipong thanks the Science Achievement Scholarship of Thailand (SAST) for the scholarship.

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Authors and Affiliations

  1. Department of Chemistry and Center of Excellence in Biomaterials, Faculty of Science, Naresuan University, Phitsanulok, 65000, Thailand

    Usana Mahanitipong, Sukrita Chanthip & Metha Rutnakornpituk

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  1. Usana Mahanitipong
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  2. Sukrita Chanthip
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  3. Metha Rutnakornpituk
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UM wrote the manuscript text and prepared Figs. 1, 2, 3, 4, 5, 6 and 7; Table 2 and Supplementary information SC prepared Table 1. MR prepared Graphical abstract and mainly reviewed the manuscript.

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Correspondence to Metha Rutnakornpituk.

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Mahanitipong, U., Chanthip, S. & Rutnakornpituk, M. Carboxymethyl Chitosan–Magnetite Nanocomposites Immobilized with Pd as Reusable Catalysts for the Reduction of 4-nitrophenol and Methylene Blue. J Inorg Organomet Polym 33, 1716–1728 (2023). https://doi.org/10.1007/s10904-023-02603-1

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