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Effect of 1wt% GO, MWCNTs, SiO2-GO and SiO2-MWCNTs on Mechanical Properties and Corrosion Resistance of Double-Layer Zinc Silicate Coatings

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Abstract

A double-layer structure coating combining the advantages of GO shielding and the conductivity of MWCNTs was proposed. The sol–gel method was used to prepare SiO2-GO and SiO2-MWCNTs hybrid materials and 1wt% zinc silicate (ZS) double-layer structure composite coating was prepared. Mechanical strength and electrochemistry were tested to compare the effects of added phase and structure on the properties of the coating. The results showed that among the single-layer coatings, the zinc silicate coating with SiO2-GO had the best surface properties, the hardness of the coating reached 6H, the impact strength reached 75 300 g·cm, the SiO2-GO/ZS coating had hydrophobic properties, and the contact angle reached 92°. MWCNTs/ZS coating had very high interfacial bonding strength, and the average adhesion was 8.02 MPa, which was about 3 times higher than that of ZS coating. In terms of corrosion resistance, the double-layer structural coating of MWCNTs/ZS undercoat and SiO2-GO/ZS topcoat had the minimum corrosion current density and maximum impedance, which were 1.732 μA/cm2 and 23KΩ/cm2 respectively and could still maintain excellent cathodic protection under long-term immersion.

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Funding

This project was supported by the National Natural Science Foundation of China (Grant Nos. 51675232, 51775244) and the Excellent Teaching Team of the “Blue Project” of Jiangsu Universities.

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  1. Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment & Technology, School of Mechanical Engineering, Jiangnan University, Wuxi, Jiangsu, 214026, People’s Republic of China

    Yiyao Wang, Meiping Wu, Peipei Lu, Chenyu Wang, Xiaojie Shi, Xiu Ye & Xiaojin Miao

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Contributions

YW: Writing and correction of the paper, sample preparation, electrochemical testing and analysis; MW: Monitor and check, provide guidance; PL: Commentary and revision, discussion with YW; CW: SEM and EDS test, physical performance test; XS: Modify the statement and description of the article; XY: Cold spraying, provision of resources and instruments; XM: Proofread the paper, provide advice.

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Correspondence to Meiping Wu or Xiaojin Miao.

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Wang, Y., Wu, M., Lu, P. et al. Effect of 1wt% GO, MWCNTs, SiO2-GO and SiO2-MWCNTs on Mechanical Properties and Corrosion Resistance of Double-Layer Zinc Silicate Coatings. J Inorg Organomet Polym 32, 4384–4400 (2022). https://doi.org/10.1007/s10904-022-02449-z

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