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Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties

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Abstract

The reaction of Zn(NO3)2⋅6H2O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS)2] (1) and [Zn(ftpy)(NCS)2] (2) while two isostructural compound of [Zn(tpyOH)(NCS)2].DMSO (1.DMSO) and [Zn(ftpy)(NCS)2].DMSO (2.DMSO) were obtained during the crystallization in DMSO, respectively. Structurally, 1.DMSO and 2.DMSO reveal that the Zn(II) is penta-coordinated by two nitrogen atoms of NCS− and three nitrogen atoms from tpyOH or ftpy in a highly distorted square pyramidal geometry. Interestingly, 1.DMSO contains four crystallographically independent molecules, each of them is hydrogen-bonded to DMSO and adopts supramolecular structure constructed by OH…O hydrogen bonds. On the other hand, the reaction of CdCl2 with ftpy has been resulted in the formation of the new distorted square pyramid complex [Cd(ftpy)Cl2] (3). The crystal structure of 3 is stabilized by the extensive hydrogen bonds of C–H…Cl between H atoms of ftpy and the Cl atoms. Crystal structures of 2.DMSO and 3 reveal that these porous materials have voids, occupied by the solvents. The volume of voids in 2.DMSO and 3 are 542 and 555 Å 3, respectively. Hirshfeld surface analysis were used to identify and quantify the inter-molecular interactions such as H-bonds and π-stackings. Thermogravimetric and differential thermal analysis showed that three compounds possess great thermal stabilities, especially for 2 which is stable up to 373 °C. The luminescent properties of compounds were assigned to π–π* transitions.

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The data that support the findings of this study are available in the supplementary material of this article.

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Acknowledgements

We would like to thank the Research Council of K.N. Toosi University of Technology for financial support.

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Authors and Affiliations

  1. Faculty of Chemistry, K.N. Toosi University of Technology, P.O. Box 16315-1618, 15418, Tehran, Iran

    Badri Z. Momeni & Sanaz Kazemzade Anari

  2. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950, Wrocław, Poland

    Jan Janczak

  3. HetCat Switzerland, Gundeldingerstrasse 174, 4053, Basel, Switzerland

    Reza Fallahpour

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  1. Badri Z. Momeni
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Momeni, B.Z., Kazemzade Anari, S., Janczak, J. et al. Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties. J Inorg Organomet Polym 32, 2279–2297 (2022). https://doi.org/10.1007/s10904-022-02299-9

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