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Thermal pyrolysis and kinetic analysis of a ZnxCo1−x ZiF-8 metal–organic framework for recent applications

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Abstract

Zeolitic imidazolate frameworks (ZIFs) are interesting materials for use in several aspects: energy storage material, gas sensing, and photocatalysis. The thermal stability and pyrolysis process are crucial to determine the active phase of the material. A deep understanding of the pyrolysis mechanism is in demand. So, the thermodynamics and combustion process with different heating rates were examined, and the kinetic parameters were computed employing thermogravimetric tests. Based on the TG analysis of combustion, pyrolysis moves to the high-temperature region with an increase in heating rate. The decomposition process can be separated into dehydration (300–503 K) and pyrolysis reaction (703–1100 K). Three points of the decomposition process are performed by dynamical analysis owing to shifts of slopes, but the combustion process has only one stage. Dynamical parameters, for instance, the possible mechanism, the pre-exponential factor, and the apparent activation energy were obtained through comparison using the Kissinger formula. The thermodynamics analysis of the Zn1−xCox ZIF-8 materials is an effective way to explore the temperature influence on the process of pyrolysis, which can benefit in several recent applications.

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Acknowledgements

This work was produced with the financial support of the Academy of Scientific Research and Technology of Egypt; ScienceUP/GradeUp initiative: Grant Agreement No. (6553). Its contents are the sole responsibility of the authors and do not necessarily reflect the views of the Academy of Scientific Research and Technology.

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Authors and Affiliations

  1. Physics Department, Faculty of Science, Al-Azhar University, Assiut, 71542, Egypt

    E. R. Shaaban, A. M. Aboraia, S. O. Mohamoud & M. M. Abou halaka

  2. The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, Rostov-on-Don, Russia, 344090

    Vera V. Butova & A. V. Soldatov

Authors
  1. E. R. Shaaban
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  2. A. M. Aboraia
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  3. Vera V. Butova
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  4. S. O. Mohamoud
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  5. M. M. Abou halaka
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  6. A. V. Soldatov
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Correspondence to E. R. Shaaban.

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Shaaban, E.R., Aboraia, A.M., Butova, V.V. et al. Thermal pyrolysis and kinetic analysis of a ZnxCo1−x ZiF-8 metal–organic framework for recent applications. J Inorg Organomet Polym 32, 831–839 (2022). https://doi.org/10.1007/s10904-021-02181-0

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  • DOI: https://doi.org/10.1007/s10904-021-02181-0

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