Skip to main content
SpringerLink
Log in

Synthesis and Characterization of a Novel Preceramic Polymer for SiBNC-Ti Ceramics

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A ceramic precursor (PBSZ-Ti) with different Ti content for preparing SiBNC-Ti ceramics was synthesized by the polymer-derived method, with dicyclopentadienyltitanium dichloride, trichlorosilane, hexamethyldisilazane and boron trichloride as starting materials. FT-IR, NMR, EA and XPS were employed to characterize the compositions and structures of PBSZ-Ti and SiBNC-Ti ceramics, which indicated that PBSZ-Ti contained Si–N–B and B–N six-membered ring structures, and Ti element was successfully introduced into the polymeric structure. The micro-morphology and high temperature crystallization behavior of SiBNC-Ti ceramics were studied by XRD, Raman and SEM. The results show that the surface of the SiBNC-Ti ceramic is smooth and dense. The amorphous state of SiBNC-Ti ceramics could be maintained to 1500 °C in a N2 atmosphere and 1300 °C in air.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

Data Availability

All data generated or analysed during this study is included in this published article.

Code Availability

Not applicable.

References

  1. A. Kamal, B. Rajasekhar, A. Painuly, S. Packirisamy, J. Inorg. Organomet. Polym. Mater. 30, 1578–1588 (2020). https://doi.org/10.1007/s10904-019-01347-1

    Article  CAS  Google Scholar 

  2. X. Ji, C. Shao, H. Wang, J. Wang, J. Cheng, X. Long, T. Mao, Ceram. Int. 43, 7469–7476 (2017). https://doi.org/10.1016/j.ceramint.2017.03.022

    Article  CAS  Google Scholar 

  3. S. Lu, Z. Tang, T. Rogers, S. Wang, N. Feng, Y. Zhang, H. Zhang, Y. Liu, Ceram. Int. 47, 18984–18990 (2021). https://doi.org/10.1016/j.ceramint.2021.03.242

    Article  CAS  Google Scholar 

  4. S. Chen, Q. Zhang, X. Luan, R. Yu, S. Zhang, L. Cheng, Thin Solid Films 709, 138242 (2020). https://doi.org/10.1016/j.tsf.2020.138242

    Article  CAS  Google Scholar 

  5. X. Guo, D. Wang, Z. Guo, Z. Zhang, M. Cui, C. Xu, Surf. Coat. Technol. 350, 101–109 (2018). https://doi.org/10.1016/j.surfcoat.2018.06.091

    Article  CAS  Google Scholar 

  6. X. Luan, S. Gu, Q. Zhang, L. Cheng, R. Riedel, Sens. Actuators A 330, 112824 (2021). https://doi.org/10.1016/j.sna.2021.112824

    Article  CAS  Google Scholar 

  7. W. Yuan, Y. Wang, Z. Luo, F. Chen, H. Li, T. Zhao, Processes 9, 955 (2021). https://doi.org/10.3390/pr9060955

    Article  CAS  Google Scholar 

  8. C. Zhang, Y. Liu, Y. Cui, K. Chen, S. Peng, H. Zhang, K. Han, M. Yu, Ceram. Int. 44, 14878–14883 (2018). https://doi.org/10.1016/j.ceramint.2018.08.194

    Article  CAS  Google Scholar 

  9. D. Li, L. Yang, D. Jia, S. Wang, X. Duan, Q. Zhu, Y. Miao, J. Rao, Y. Zhou, Corros. Sci. 124, 103–120 (2017). https://doi.org/10.1016/j.corsci.2017.05.013

    Article  CAS  Google Scholar 

  10. P. Zhang, D. Jia, Z. Yang, X. Duan, Y. Zhou, J. Adv. Ceram. 1, 157–178 (2012). https://doi.org/10.1007/s40145-012-0017-x

    Article  CAS  Google Scholar 

  11. J. Wilfert, M. Jansen, J. Mater. Chem. 22, 9782–9786 (2012). https://doi.org/10.1039/C2JM16771A

    Article  CAS  Google Scholar 

  12. Z. Yu, Y. Pei, S. Lai, S. Li, Y. Feng, X. Liu, Ceram. Int. 43, 5949–5956 (2017). https://doi.org/10.1016/j.ceramint.2017.01.117

    Article  CAS  Google Scholar 

  13. E. Butchereit, K. Nickel, A. Müller, J. Am. Ceram. Soc. 84, 2184–2188 (2001). https://doi.org/10.1111/j.1151-2916.2001.tb00985.x

    Article  CAS  Google Scholar 

  14. D. Ye, D. Jia, Z. Yang, Z. Sun, P. Zhang, J. Alloys Compd. 506, 88–92 (2010). https://doi.org/10.1016/j.jallcom.2010.06.176

    Article  CAS  Google Scholar 

  15. A. Muller, P. Gerstel, E. Butchereit, K. Nickel, F. Aldinger, J. Eur. Ceram. Soc. 24, 3409–3417 (2004). https://doi.org/10.1016/j.jeurceramsoc.2003.10.018

    Article  CAS  Google Scholar 

  16. X. Long, C. Shao, H. Wang, J. Wang, Dalton Trans. 44, 15463–15469 (2015). https://doi.org/10.1039/C5DT02073E

    Article  CAS  PubMed  Google Scholar 

  17. X. Long, C. Shao, H. Wang, J. Wang, Ceram. Int. 42, 19206–19211 (2016). https://doi.org/10.1016/j.ceramint.2016.09.084

    Article  CAS  Google Scholar 

  18. Y. Miao, Z. Yang, B. Liang, D. Li, Q. Li, D. Jia, Y. Cheng, Y. Zhou, Corros. Sci. 132, 293–299 (2018). https://doi.org/10.1016/j.corsci.2018.01.003

    Article  CAS  Google Scholar 

  19. S. Wang, H. Wang, F. Meng, Y. Li, Key Eng. Mater. 512–515, 894–897 (2012). https://doi.org/10.4028/www.scientific.net/KEM.512-515.894

    Article  CAS  Google Scholar 

  20. S. Wang, Y. Zhang, Y. Sun, Y. Xu, M. Ying, J. Alloys Compd. 685, 828–835 (2016). https://doi.org/10.1016/j.jallcom.2016.06.250

    Article  CAS  Google Scholar 

  21. P. Zeman, S. Zuzjakova, P. Mares, R. Čerstvý, M. Zhang, J. Jiang, E. Meletis, J. Vlček, Ceram. Int. 42, 4853–4859 (2016). https://doi.org/10.1016/j.ceramint.2015.11.171

    Article  CAS  Google Scholar 

  22. W. Li, J. Wang, Z. Xie, H. Wang, Y. Tang, Mater. Lett. 78, 1–3 (2012). https://doi.org/10.1016/j.matlet.2012.02.068

    Article  CAS  Google Scholar 

  23. D. Bahloul, M. Pereira, C. Gerardin, J. Mater. Chem. 7, 109–116 (1997). https://doi.org/10.1039/A603165J

    Article  CAS  Google Scholar 

  24. Y. Blum, K. Schwartz, R. Laine, J. Mater. Sci. 24, 1707–1718 (1989). https://doi.org/10.1007/BF01105695

    Article  CAS  Google Scholar 

  25. P. Miele, B. Toury, D. Cornu, S. Bernard, J. Organomet. Chem. 690, 2809–2814 (2005). https://doi.org/10.1016/j.jorganchem.2005.02.039

    Article  CAS  Google Scholar 

  26. Z. Yu, H. Min, J. Zhan, L. Yang, Ceram. Int. 39, 3999–4007 (2013). https://doi.org/10.1016/j.ceramint.2012.10.250

    Article  CAS  Google Scholar 

  27. M. Pimenta, G. Dresselhaus, M. Dresselhaus, L. Cançado, A. Jorio, R. Saito, Phys. Chem. 9, 1276–1290 (2007). https://doi.org/10.1039/b613962k

    Article  CAS  Google Scholar 

  28. M. Bechelany, C. Salameh, A. Viard, L. Guichaoua, F. Rossignol, T. Chartier, S. Bernard, P. Miele, J. Eur. Ceram. Soc. 35, 1361–1374 (2015). https://doi.org/10.1016/j.jeurceramsoc.2014.11.021

    Article  CAS  Google Scholar 

  29. A. Ferrari, J. Robertson, Phys. Rev. B 61, 14095–14107 (2000). https://doi.org/10.1103/PhysRevB.61.14095

    Article  CAS  Google Scholar 

  30. Y. Wang, D. Alsmeyer, R. McCreery, Chem. Mater. 2, 557–563 (1990). https://doi.org/10.1021/cm00011a018

    Article  CAS  Google Scholar 

  31. D. Knight, W. White, J. Mater. Res. 4, 385–393 (1989). https://doi.org/10.1557/JMR.1989.0385

    Article  CAS  Google Scholar 

  32. S. Trassl, G. Motz, E. Rossler, G. Ziegler, J. Am. Ceram. Soc. 85, 239–244 (2002). https://doi.org/10.1111/j.1151-2916.2002.tb00072.x

    Article  CAS  Google Scholar 

  33. G. Shao, W. Peng, C. Ma, J. Am. Ceram. Soc. 100, 842–847 (2017). https://doi.org/10.1111/jace.14590

    Article  CAS  Google Scholar 

  34. M. Storch, D. Vrankovic, M. Graczyk-Zajac, R. Riedel, Solid State Ionics 315, 59–64 (2018). https://doi.org/10.1016/j.ssi.2017.11.032

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the fund of the Key Laboratory of National Defense Science and Technology (No. 6142906190510), the Fundamental Research Funds for the Central Universities (2232019D3-06), National Natural Science Foundation of China (Grant No. 51703025), and Natural Science Foundation of Shanghai (No. 15ZR1400400).

Funding

This study were funded by National Natural Science Foundation of China (No. 51703025), Natural Science Foundation of Shanghai (No. 15ZR1400400), The fund of the Key Laboratory of National Defense Science and Technology (No. 6142906190510) and The Fundamental Research Funds for the Central Universities.

Author information

Authors and Affiliations

  1. Shanghai High Performance Fibers and Composites Center (Province-Ministry Joint), College of Materials Science and Engineering, Donghua University, Shanghai, 201620, People’s Republic of China

    Yong Liu, Zicheng Tang, Shaofei Wang, Rogers Tusiime, Jian Shen, Yifan Zhang & Keqing Han

  2. The Key Laboratory of High-Performance Fiber and Product, Ministry of Education, Donghua University, Shanghai, 201620, People’s Republic of China

    Yong Liu & Keqing Han

  3. Science and Technology on Advanced Functional Composites Laboratory, Aerospace Research Institute of Materials and Processing Technology, Beijing, 100076, China

    Jidong Hu & Haikun Chen

Authors
  1. Yong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zicheng Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shaofei Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Rogers Tusiime
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jian Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jidong Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Haikun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Yifan Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Keqing Han
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

YL, KH contributed to the conception of the study. ZT, SW, JS performed the experiments. ZT, SW, YZ, RT performed data analysis and wrote the manuscript. JH, HC performed the analysis with constructive discussions.

Corresponding author

Correspondence to Keqing Han.

Ethics declarations

Conflict of interest

The authors declare that they have no conflicts of interest.

Ethical Approval

Not applicable.

Consent to Participate

Not applicable.

Consent for Publication

All authors have contributed to, read and approved the manuscript that is enclosed.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., Tang, Z., Wang, S. et al. Synthesis and Characterization of a Novel Preceramic Polymer for SiBNC-Ti Ceramics. J Inorg Organomet Polym 32, 646–655 (2022). https://doi.org/10.1007/s10904-021-02172-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-021-02172-1

Keywords

Search

Navigation