Skip to main content

Advertisement

SpringerLink
Log in

Fabrication of Multi-functionalized Graphene Oxide Doped Alginate Hybrid Spheres for Enhanced Fluoride Adsorption

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

In this current study, aminated graphene oxide (AGO) doped on alginate (Alg) matrix offers AGO@Alg hybrid spheres was developed to investigate its potential for retention of fluoride from water. The sophisticated characterization methods likely TGA, SEM, XPS and FTIR studies of AGO@Alg hybrid spheres were attained to recognize its physicochemical properties like thermal stability, morphology, elemental binding energy and functional groups determination. The responsible parameters for fluoride adsorption on AGO@Alg hybrid spheres were optimized under a batch mode to achieve improve defluoridation capacity (DC). The developed AGO@Alg hybrid spheres follow the electrostatic interaction mechanism on fluoride removal. The adsorption isotherms (Langmuir, Temkin, Dubinin–Radushkevich (D–R) and Fruendlich models), kinetics (reaction and diffusion based models) and thermodynamic parameters (ΔS°, ΔG° and ΔH°) were investigated at 303, 313 and 323 K. To minimize the cost-effectiveness of AGO@Alg hybrid spheres the reusability test was carried out. The suitability of AGO@Alg hybrid spheres was also analyzed for the fluoride contaminated field sample taken from fluoride prevalent village.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. N. Singh, S. Kumari, S. Khan, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 254, 119637 (2021)

    CAS  Google Scholar 

  2. S. Kumari, S. Khan, Sci. Rep. 7, 1–12 (2017)

    Google Scholar 

  3. C. Li, N. Chen, Y. Zhao, R. Li, C. Feng, Chemosphere 163, 81–89 (2016)

    CAS  PubMed  Google Scholar 

  4. J. Zhang, N. Chen, Z. Tang, Y. Yu, Q. Hu, C. Feng, Phys. Chem. Chem. Phys. 17, 12041–12050 (2015)

    CAS  PubMed  Google Scholar 

  5. A. Jeyaseelan, M. Naushad, N. Viswanathan, J. Chem. Eng. Data 65, 2990–3001 (2020)

    CAS  Google Scholar 

  6. M.V.N. Samrat, K.K. Rao, A.K. SenGupta, J. Riotte, J.R. Mudakavi, J. Water Process. Eng. 23, 327–337 (2018)

    Google Scholar 

  7. A. Azari, R.R. Kalantary, G. Ghanizadeh, B. Kakavandi, M. Farzadkia, E. Ahmadi, RSC Adv. 5, 87377–87391 (2015)

    CAS  Google Scholar 

  8. A. Jeyaseelan, N. Viswanathan, J. Chem. Eng. Data 65, 5328–5340 (2020)

    CAS  Google Scholar 

  9. S.M. Prabhu, S. Meenakshi, J. Water Process. Eng. 2, 96–104 (2014)

    Google Scholar 

  10. S. George, P. Pandit, A.B. Gupta, Water Res. 44, 3055–3064 (2010)

    CAS  PubMed  Google Scholar 

  11. J.A. Arcibar-Orozco, A.I. Flores-Rojas, J.R. Rangel-Mendez, P.E. Díaz-Flores, Environ. Technol. 41, 1554–1567 (2020)

    CAS  PubMed  Google Scholar 

  12. C.E. Choong, M. Kim, S. Yoon, G. Lee, C.M. Park, J. Taiwan Inst. Chem. Eng. 93, 306–314 (2018)

    CAS  Google Scholar 

  13. M.K. Uddin, S.S. Ahmed, M. Naushad, Desalin. Water Treat. 145, 232–248 (2019)

    CAS  Google Scholar 

  14. S. De Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Sustain. Mater. Technol. 9, 10–40 (2016)

    Google Scholar 

  15. E.F. Sheka, Y.A. Golubev, N.A. Popova, Nanomaterials 10, 2021 (2020)

    CAS  PubMed Central  Google Scholar 

  16. N. Ashraf, A. Majid, M. Rafique, M.B. Tahir, Chin. J. Phys. 66, 246 (2020)

    CAS  Google Scholar 

  17. S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Carbon 45, 1558–1565 (2007)

    CAS  Google Scholar 

  18. P. Steurer, R. Wissert, R. Thomann, R. Mülhaupt, Macromol. Rapid Commun. 30, 316–327 (2009)

    CAS  PubMed  Google Scholar 

  19. M.J. McAllister, J.L. Li, D.H. Adamson, H.C. Schniepp, A.A. Abdala, J. Liu, M. Herrera-Alonso, D.L. Milius, R. Car, R.K. Prud’homme, I.A. Aksay, Chem. Mater. 19, 4396–4404 (2007)

    CAS  Google Scholar 

  20. R. Hassandoost, S.R. Pouran, A. Khataee, Y. Orooji, S.W. Joo, J. Hazard. Mater. 376, 200–211 (2019)

    CAS  PubMed  Google Scholar 

  21. M.D. Firouzjaei, F.A. Afkhami, M.R. Esfahani, C.H. Turner, S. Nejati, J. Water Process. Eng. 34, 101180 (2020)

    Google Scholar 

  22. J. Wang, X. Duan, Q. Dong, F. Meng, X. Tan, S. Liu, S. Wang, Carbon 144, 781–790 (2019)

    CAS  Google Scholar 

  23. K. Zuo, X. Huang, X. Liu, E.M. Gil Garcia, J. Kim, A. Jain, L. Chen, P. Liang, A. Zepeda, R. Verduzco, J. Lou, Environ. Sci. Technol. 54, 13322–13332 (2020)

    CAS  PubMed  Google Scholar 

  24. M.A. Ahsan, V. Jabbari, M.T. Islam, R.S. Turley, N. Dominguez, H. Kim, E. Castro, J.A. Hernandez-Viezcas, M.L. Curry, J. Lopez, J.L. Gardea-Torresdey, Sci. Total Environ. 673, 306–317 (2019)

    CAS  PubMed  Google Scholar 

  25. S. Ploychompoo, Q. Liang, X. Zhou, C. Wei, H. Luo, Phys. E: Low-Dimens. Syst. Nanostruct. 125, 114377 (2021)

    CAS  Google Scholar 

  26. M.H. Saghi, B. Chabot, S. Rezania, M. Sillanpää, A.A. Mohammadi, M. Shams, A. Alahabadi, Sep. Purif. Technol. 270, 118645 (2021)

    Google Scholar 

  27. N. Singh, S. Kumari, N. Goyal, S. Khan, Environ. Nanotechnol. Monit. Manage. 15, 100444 (2021)

    Google Scholar 

  28. N. Singh, S. Kumari, S. Khan, Mater. Today Commun. 28, 102521 (2021)

    CAS  Google Scholar 

  29. M. Manzano, V. Aina, C.O. Arean, F. Balas, V. Cauda, M. Colilla, M.R. Delgado, M. Vallet-Regi, Chem. Eng. J. 137, 30–37 (2008)

    CAS  Google Scholar 

  30. M. Bilal, T. Rasheed, F. Nabeel, H.M. Iqbal, In Biofibers and Biopolymers for Biocomposites (Springer, Cham, 2020), pp. 135–157

    Google Scholar 

  31. G.E. Luckachan, C.K.S. Pillai, J. Polym. Environ. 19, 637–676 (2011)

    CAS  Google Scholar 

  32. N.M. Mahmoodi, J. Taiwan Inst. Chem. Eng. 44, 322–330 (2013)

    CAS  Google Scholar 

  33. K. Pandi, N. Viswanathan, RSC Adv. 6, 75905–75915 (2016)

    CAS  Google Scholar 

  34. B.S. Ge, T. Wang, H.X. Sun, W. Gao, H.R. Zhao, Polym. Adv. Technol. 29, 1334–1343 (2018)

    CAS  Google Scholar 

  35. K. Pandi, N. Viswanathan, J. Appl. Polym. Sci. (2015). https://doi.org/10.1002/app.41937

    Article  Google Scholar 

  36. J.E. Harwood, Water Res. 3, 273–280 (1969)

    CAS  Google Scholar 

  37. J.B. Wu, M.L. Lin, X. Cong, H.N. Liu, P.H. Tan, Chem. Soc. Rev. 47, 1822–1873 (2018)

    CAS  PubMed  Google Scholar 

  38. B. Wang, B. Luo, M. Liang, A. Wang, J. Wang, Y. Fang, Y. Chang, L. Zhi, Nanoscale 3, 5059–5066 (2011)

    CAS  PubMed  Google Scholar 

  39. S. Babu Maddinedi, B.K. Mandal, S.H. Patil, V.V. Andhalkar, S. Ranjan, N. Dasgupta, J. Photochem. Photobiol. B. 166, 252–258 (2017)

    Google Scholar 

  40. J.A. Luceño-Sánchez, G. Maties, C. Gonzalez-Arellano, A.M. Diez-Pascual, Nanomaterials 8, 870 (2018)

    PubMed Central  Google Scholar 

  41. S.K. Papageorgiou, E.P. Kouvelos, E.P. Favvas, A.A. Sapalidis, G.E. Romanos, F.K. Katsaros, Carbohydr. Res. 345, 469–473 (2010)

    CAS  Google Scholar 

  42. Z. Yi, L. Huajie, L. Mingchun, X. Meihua, J. Mol. Struct. 1209, 127973 (2020)

    CAS  Google Scholar 

  43. M. Sarvestani, R. Azadi, Appl. Organomet. Chem. 32, e3906 (2018)

    Google Scholar 

  44. V. Gopalakannan, N. Viswanathan, Int. J. Biol. Macromol. 72, 862–867 (2015)

    CAS  PubMed  Google Scholar 

  45. A. Navaee, A. Salimi, RSC Adv. 5, 59874–59880 (2015)

    CAS  Google Scholar 

  46. D. Hulicova-Jurcakova, M. Kodama, S. Shiraishi, H. Hatori, Z.H. Zhu, G.Q. Lu, Adv. Funct. Mater. 19, 1800–1809 (2009)

    CAS  Google Scholar 

  47. L.F. Lai, G.M. Huang, X.F. Wang, J. Weng, Carbon 48, 3145–3156 (2010)

    CAS  Google Scholar 

  48. C. Struzzi, M. Scardamaglia, N. Reckinger, H. Sezen, M. Amati, L. Gregoratti, J.F. Colomer, C. Ewels, R. Snyders, C. Bittencourt, Phys. Chem. Chem. Phys. 19, 31418–31428 (2017)

    CAS  PubMed  Google Scholar 

  49. N. Viswanathan, I. Aswin Kumar, S. Meenakshi, Int. J. Biol. Macromol. 133, 811–816 (2019)

    CAS  PubMed  Google Scholar 

  50. A. Jeyaseelan, M.D. Albaqami, N. Viswanathan, J. Environ. Chem. Eng. 9, 104995 (2020)

    Google Scholar 

  51. I. Langmuir, J. Am. Chem. Soc. 38, 2221–2295 (1916)

    CAS  Google Scholar 

  52. H.M.F. Freundlich, Z. Phys, Chem. 57, 385–470 (1906)

    CAS  Google Scholar 

  53. M.M. Dubinin, E.D. Zaverina, L.V. Radushkevich, J. Phys. Chem 21, 1351–1362 (1947)

    CAS  Google Scholar 

  54. A. Jeyaseelan, N. Viswanathan, J. Mol. Liq. 326, 115163 (2021)

    CAS  Google Scholar 

  55. I. Aswin Kumar, A. Jeyaseelan, N. Viswanathan, M. Naushad, A.J.M. Valente, J Solid State Chem. 302, 122446 (2021)

    CAS  Google Scholar 

  56. A.A. Khan, R.P. Singh, Colloids Surf. 24, 33–42 (1987)

    CAS  Google Scholar 

  57. H.N. Tran, S.J. You, H.P. Chao, J. Environ. Chem. Eng. 4, 2671–2682 (2016)

    CAS  Google Scholar 

  58. Y.S. Ho, G. McKay, Process Biochem. 34, 451–465 (1999)

    CAS  Google Scholar 

  59. Y.C. Wong, Y.S. Szeto, J. Appl. Polym. Sci. 92, 1633–1645 (2004)

    CAS  Google Scholar 

  60. H.A. Kramers, Physica 7, 284–304 (1940)

    CAS  Google Scholar 

  61. G.H. Graaf, H. Scholtens, E.J. Stamhuis, A.A.C.M. Beenackers, Chem. Eng. Sci. 45, 773–783 (1990)

    CAS  Google Scholar 

  62. A. Jeyaseelan, K.M.M. Katubi, N.S. Alsaiari, M. Naushad, N. Viswanathan, Diam. Relat. Mater. 117, 108446 (2021)

    CAS  Google Scholar 

  63. S.K. Swain, T. Patnaik, V.K. Singh, U. Jha, R.K. Patel, R.K. Dey, Chem. Eng. J. 171, 1218–1226 (2011)

    CAS  Google Scholar 

  64. K. Pandi, N. Viswanathan, Carbohydr. Polym. 112, 662–667 (2014)

    CAS  PubMed  Google Scholar 

  65. F. Ke, G. Luo, P. Chen, J. Jiang, Q. Yuan, H. Cai, C. Peng, X. Wan, J. Porous Mater. 23, 1065–1073 (2016)

    CAS  Google Scholar 

  66. N. Viswanathan, S. Meenakshi, Appl. Clay Sci. 48, 607–611 (2010)

    CAS  Google Scholar 

  67. R.L. Ramos, J. Ovalle-Turrubiartes, M.A. Sanchez-Castillo, Carbon 37, 609 (1999)

    CAS  Google Scholar 

  68. A. Jeyaseelan, N.S. Alsaiari, K.M.M. Katubi, M. Naushad, N. Viswanathan, Int. J. Biol. Macromol. 182, 1843–1851 (2021)

    CAS  PubMed  Google Scholar 

  69. A. Bansiwal, D. Thakre, N. Labhshetwar, S. Meshram, S. Rayalu, Colloids Surf. B. 129, 173 (2009)

    Google Scholar 

  70. C.S. Sundaram, N. Viswanathan, S. Meenakshi, J. Hazard. Mater. 172, 147–151 (2009)

    Google Scholar 

  71. K. Pandi, N. Viswanathan, Carbohydr. Polym. 134, 732–739 (2015)

    CAS  PubMed  Google Scholar 

  72. C. Sairam -Sundaram, N. Viswanathan, S. Meenakshi, J. Hazard. Mater. 163, 618–624 (2009)

    CAS  PubMed  Google Scholar 

  73. P. Liang, Y. Zhang, D. Wang, Y. Xu, L. Luo, J. Rare Earths 31, 817–822 (2013)

    CAS  Google Scholar 

  74. G. Sharma, A. Kumar, S. Sharma, M. Naushad, P. Dhiman, D.V.N. Vo, F.J. Stadler, Mater. Lett. 278, 128359 (2020)

    CAS  Google Scholar 

Download references

Acknowledgements

The authors (A. Jeyaseelan and N. Viswanathan) thank the Council of Scientific and Industrial Research (CSIR) (F.No. 01(2965)/19/EMR-II), New Delhi, India for the financial support to carry out this research work. The authors are grateful to the Researchers Supporting Project Number (RSP-2021/8), King Saud University, Riyadh, Saudi Arabia for the financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, Anna University, University College of Engineering - Dindigul, Dindigul, Tamilnadu, 624 622, India

    Antonysamy Jeyaseelan & Natrayasamy Viswanathan

  2. Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    Mu. Naushad

  3. Division of Electronics and Electrical Engineering, Dongguk University, Seoul, Seoul, 04620, South Korea

    Chinna Bathula

Authors
  1. Antonysamy Jeyaseelan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Natrayasamy Viswanathan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mu. Naushad
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chinna Bathula
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Natrayasamy Viswanathan.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 26 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jeyaseelan, A., Viswanathan, N., Naushad, M. et al. Fabrication of Multi-functionalized Graphene Oxide Doped Alginate Hybrid Spheres for Enhanced Fluoride Adsorption. J Inorg Organomet Polym 32, 216–228 (2022). https://doi.org/10.1007/s10904-021-02163-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-021-02163-2

Keywords

Search

Navigation