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Gamma Irradiation-Induced Preparation of Polyacrylonitrile Acrylamide Nano-silica for Removal of Some Hazardous Metals

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Abstract

Gamma-irradiation initiated polymerization was utilized to prepare polyacrylonitrile acrylamide nano-silica (P(AN-AM)-NS). Various analytical tools like XRD, FT-IR, SEM, TEM, and DTA and TGA were used to estimate the morphology, functional groups, and structure of P(AN-AM)-NS nanocomposite. The ability of P(AN-AM)-NS nanocomposite to remove Cs(I), Pb(II), Cd(II), Sr(II), and Cu(II) ions from the multi-component system was evaluated by batch techniques considering the influence of (shaking time, pH, reaction temperatures), and capacity. At the optimum pH, distribution coefficients have selectivity order; Pb2+  > Cs+  > Cu2+  > Cd2+  > Sr2+. The kinetic data obey pseudo-second-order models. The capacity was reduced by increasing the heating temperatures of solid powder. The thermodynamic parameters showed an endothermic and spontaneous. The investigation proved that P(AN-AM)-NS nanocomposite is a suitable organic–inorganic sorbent for the sorption of the studied ions from liquid solutions and could be considered as potential material for purification of effluent polluted with these ions.

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Acknowledgements

This work has been supported by the Egyptian Atomic Energy Authority. Great thanks to all members of the nuclear fuel technology department, Egyptian Atomic Energy Authority for supporting this work.

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  1. Hot Laboratories, and Waste Management Center, Egyptian Atomic Energy Authority, Cairo, 13759, Egypt

    Mohamed Ragab Abass, Eman Hassan EL-Masry & Wafaa Mohamed El-Kenany

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  1. Mohamed Ragab Abass
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  2. Eman Hassan EL-Masry
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  3. Wafaa Mohamed El-Kenany
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MRA: data curation, writing—original draft review and editing. EHEM: experimental work and editing. WMEK: experimental work and reviewing.

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Correspondence to Eman Hassan EL-Masry.

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Abass, M.R., EL-Masry, E.H. & El-Kenany, W.M. Gamma Irradiation-Induced Preparation of Polyacrylonitrile Acrylamide Nano-silica for Removal of Some Hazardous Metals. J Inorg Organomet Polym 32, 536–546 (2022). https://doi.org/10.1007/s10904-021-02156-1

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