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Condensation of Organoyttriumoxanalumoxanes with Chromium Acetylacetonate

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Abstract

The process of organoyttriumoxanealumoxanes co-condensation with chromium acetylacetonate has been studied, as a result chromium-containing organoyttriumoxanealumoxanes were obtained, which are ceramic-forming oligomers and may have fiber-forming properties. Their physicochemical characteristics have been determined by NMR, IR spectroscopy, SEM, TGA, XRD and elemental analysis. It has been found that when the molar ratio of chromium-containing organoyttriumoxanealumoxanes is Al/Y ≈ 2 and Al/Cr ≈ 180 they have fiber-forming properties. Polymer fibers were produced from chromium-containing organoyttriumoxanealumoxanes by melt spinning. The process of thermochemical transformation of synthesized chromium-containing organoyttriumoxanealumoxanes into the ceramic phase has been studied. It is found out that the pyrolysis of chromium-containing organoyttriumoxanealumoxanes leads to the formation of Y3(CrxAl1−x)5O12, YAlyCr1-yO3 and α-(Al2−xCrxO3). That is, these oligomers can be used to create a new generation of heatresistant, optically-transparent, corrosion—and radiation-resistant multicomponent ceramics based on aluminum, yttrium and chromium oxides.

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Acknowledgements

This work was supported by the russian foundation for basic research, project no. 17-03-00331 a.

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Authors and Affiliations

  1. State Research Institute for Chemistry and Technology of Organoelement Compounds, Moscow, Russia, 105118

    Galina I. Shcherbakova, Natalia B. Kutinova, Pavel A. Storozhenko, Maxim S. Varfolomeev & Aleksander I. Drachev

  2. Russian Technological University M.V. Lomonosov Institute of Fine Chemical Technology, Moscow, Russia, 119454

    Maxim K. Shaukhin & Aleksey D. Kirilin

  3. Moscow Aviation Institute (National Research University), Moscow, Russia, 125993

    Maxim S. Varfolomeev

  4. Baikov Institute of Metallurgy and Material Science RAS, Moscow, Russia, 119334

    Artem A. Ashmarin

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  1. Galina I. Shcherbakova
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Shcherbakova, G.I., Shaukhin, M.K., Kutinova, N.B. et al. Condensation of Organoyttriumoxanalumoxanes with Chromium Acetylacetonate. J Inorg Organomet Polym 31, 3460–3480 (2021). https://doi.org/10.1007/s10904-021-02026-w

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