Abstract
This work investigates the preparation of cadmium sulfide nanoparticles (CdS) embedded in the polymeric polyvinylchloride (PVC) matrix. PVC/CdS nanocomposite films were prepared via sol–gel method with deposition by spin-coating on glass substrates. Effects of CdS nanoparticles on the structural, morphological, optical and photocatalytic properties of the synthetized nanocomposite were studied. Results of XRD and Raman analysis confirm the formation of CdS nanoparticles with hexagonal phase in the PVC matrix, with average crystallite size between 17 to 69 nm. The UV–vis spectroscopy reveals that the transmission is between 80 and 95% in the visible region, and a direct energy bandgap between 4.07 eV for 3.85 eV. The PL emission spectra indicate the interstitial cadmium defect states. In addition, the surface modifier (PVC) exert great influence not only on the optical performance of the particles themselves but also on the size distribution of the particle in the PVC matrix. The photocatalytic study shows a good potential of PVC/CdS nanocomposites films for MB degradation under UV light irradiation.
Similar content being viewed by others
References
S. Coiai, E. Passaglia, A. Pucci, G. Ruggeri, Nanocomposites based on thermoplastic polymers and functional nanofiller for sensor applications. J. Mater. 8, 3377–3427 (2015). https://doi.org/10.3390/ma8063377
V. Mathur, K. Sharma, Small angle X-ray scattering analysis of PS/CdS, PVC/CdS & PMMA/CdS polymeric nanocomposites. JSSNT 12, 420–422 (2014). https://doi.org/10.1380/ejssnt.2014.420
M.A. Ramaz Anov, Y. Babayev, Preparation and structure nanocomposites based on zinc sulfide in polyvinylchloride. J. Non-Oxide Glasses 10, 1–6 (2018)
A.A. El-Sayed, A.M. Khalil, M. El-Shahat, N.Y. Khaireldin, S.T. Rabi, Antimicrobial activity of PVC-pyrazolone-silver nanocomposites. J. Macromol. Sci. A 53, 346–353 (2016). https://doi.org/10.1080/10601325.2016.1166000
J.M. Meichtry, C. Colbeau-Justin, G. Custo, M.I. Litter, TiO2-photocatalytic transformation of Cr (VI) in the presence of EDTA: comparison of different commercial photocatalysts and studies by time resolved microwave conductivity. J. Appl. Catal. B 144, 189–195 (2014). https://doi.org/10.1016/j.apcatb.2013.06.032
P. Devendran, T. Alagesan, K. Pandian, Single pot microwave synthesis of CdS nanoparticles in ionic liquid and their photocatalytic application. Asian J. Chem. 25, S79–S82 (2013)
C. Yang, C. Gong, T. Peng, K. Deng, L. Zan, High photocatalytic degradation activity of the polyvinyl chloride (PVC)–vitamin C (VC)–TiO2 nano-composite film. J. Hazard. Mater. 178, 152–156 (2010). https://doi.org/10.1016/j.jhazmat.2010.01.056
D. Wang, C. Bao, Q. Luo, R. Yin, X. Lib, J. An, Z. Xu, Improved visible-light photocatalytic activity and anti-photocorrosion of CdS nanoparticles surface-modified by conjugated derivatives from polyvinyl chloride. J. Environ. Chem. Eng. 3, 1578–1585 (2015). https://doi.org/10.1016/j.jece.2015.05.013
A. Khorsand Zaka, W.H. Abd Majid, M.E. Abrishami, R. Yousefi, X-ray analysis of ZnO nanoparticles by Williamson–Hall and size-strain plot methods. Solid State Sci. 13, 251–256 (2011). https://doi.org/10.1016/j.solidstatesciences.2010.11.024
R. Kaur, S.K. Tripathi, Study of conductivity switching mechanism of CdSe/PVP nanocomposite for memory device application. J. Microelectron. Eng. 133, 59–65 (2015). https://doi.org/10.1016/j.mee.2014.11.010
V.S. Solodovnichenko, V.A. Polyboyarov, A.A. Zhdanok, A.B. Arbuzov, E.S. Zapevalova, Y.G. Kryazhev, V.A. Likholobov, Synthesis of carbon materials by the short-term mechanochemical activation of polyvinyl chloride. J. Procedia Eng. 152, 747–752 (2016). https://doi.org/10.1016/j.proeng.2016.07.684
F. Kajzar, Organic Thin Films for Waveguiding Nonlinear Optics (CRC Press, Boca Raton, 1996), p. 829
J.K. Vij, Advances in Liquid Crystals, Advances in Chemical Physics (Wiley, Hoboken, 2009), pp. 259–261
R. Swanepoel, Determination of the thickness and optical constants of amorphous silicon. J. Phys. E 16, 1214–1222 (1983). https://doi.org/10.1088/0022-3735/16/12/023
M. Caglar, Y. Caglar, S. Ilican, The determination of the thickness and optical constants of the ZnO crystalline thin film by using envelope method. J. Optoelectron. Adv. Mater. 8, 1410–14130 (2006)
S. Chaure, N.B. Chaure, R.K. Pandey, A.K. Ray, Stoichiometric effects on optical properties of cadmium sulphide quantum dots. IET Circ. Devices Syst. 1, 215–219 (2007). https://doi.org/10.1049/iet-cds:20070048
V. Singh, P. Chauhan, Structural and optical characterization of CdS nanoparticles prepared by chemical precipitation method. J. Phys. Chem. Solids 70, 1074–1079 (2009). https://doi.org/10.1016/j.jpcs.2009.05.024
D. Wang, L. Shi, Q. Luo, X. Li, J. An, An efficient visible light photocatalyst prepared from TiO2 and polyvinyl chloride. J. Mater. Sci. 47, 2136–2145 (2012). https://doi.org/10.1007/s10853-011-6014-6
G. Nie, G. Li, L. Wang, X. Zhang, Nanocomposites of polymer brush and inorganicnanoparticles: preparation, characterization and application. Polym. Chem. 4, 753–769 (2016). https://doi.org/10.1039/C5PY01333J
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Rouabah, N., Boudine, B., Nazir, R. et al. Structural, Optical and Photocatalytic Properties of PVC/CdS Nanocomposites Prepared by Soft Chemistry Method. J Inorg Organomet Polym 31, 1102–1110 (2021). https://doi.org/10.1007/s10904-020-01752-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-020-01752-x