Skip to main content
SpringerLink
Log in

Synthesis of Bio-Nanomagnetite Using Poly(butylene adipate) and Poly(butylene adipate-co-terephthalate)

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Nano-scale magnetite presents fascinating opportunities in various fields. For example, they are used for removing pollution from water bodies as they can bind electrochemically to suspended particles so that they are settled as sludge. Applying biodegradability property to these nanomagnetites improves their usage. In this study, bio-nanomagnetite is synthesized using co-precipitation reaction in which nanoparticles are used as a base for mounting two biodegradable polymers, i.e. poly(butylene adipate) (PBA) and poly(butylene adipate-co-terephthalate) (PBAT). Proton nuclear magnetic resonance (1HNMR) and carbon nuclear magnetic resonance (13CNMR) spectra of synthesized polymers are presented. Fourier transform infrared spectroscopy (FTIR) of nano-particles is also presented. Biodegradation tests of bio-polymers including degradation under UV (ultraviolet) rays and in phosphate buffer show they can be degraded in biological conditions. Curves showing the progression of degradation are also presented. Relative size of the particles based on Debye–Scherrer relation is also obtained through X-ray powder diffraction (XRD) test and it is 9.12 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. L. Blaney, Lehigh Review 15, 33–81 (2007)

    Google Scholar 

  2. Bellis, M., Magnetic Compass. (2006). Inventors.com, https://inventors.about.com/library/inventors/blcompass.html

  3. A. Bahadur, S. Iqbal, A. Saeed, M.I. Bashir, M. Shoaib, M. Waqas, G. Shabir, A. Jabbar, Chem. Pap. 71(8), 1445–1451 (2017)

    CAS  Google Scholar 

  4. H. Lin, Y. Watanabe, M. Kimura, K. Hanabusa, H. Shirai, J. Appl. Polym. Sci. 87, 1239–1247 (2003)

    CAS  Google Scholar 

  5. P.C. Morais, V.K. Garge, A.C. Oliveira, R.B. Azevedo, D. Rabelo, E.C.D. Lima, Eur. Cell Mater. 3, 173–175 (2002)

    Google Scholar 

  6. L. Suber, S. Foglia, G.M. Ingo, N. Boukos, Appl. Organomet. Chem 15, 414–420 (2001)

    CAS  Google Scholar 

  7. Y.L. Hou, J.F. Yu, S. Gao, J. Mat. Chem. 13, 1983–1987 (2003)

    CAS  Google Scholar 

  8. R.S. Sapiezko, E. Matijevic, J. Colloid Interface Sci. 74, 405–422 (1980)

    Google Scholar 

  9. S.H. Sun, H. Zeng, J. Am. Chem. Soc. 124, 8204–8205 (2002)

    CAS  PubMed  Google Scholar 

  10. K. Woo, J. Hing, S. Choi, H.W. Lee, J.P. Ahn, C.S. Kim, S.W. Lee, Chem. Mat. 16, 2814–2418 (2004)

    CAS  Google Scholar 

  11. S.P. Gubin, Yu.A Koksharov, G.B. Khomutov, GYu. Yurkov, Russ. Chem. Rev. 74(6), 489 (2005)

  12. K.A. Kydralieva, G.I. Dzhardimalieva, A.A. Yurishcheva, S.J. Jorobekova, J. Inorg. Organomet. Polym. 26(6), 1212–1230 (2016)

    CAS  Google Scholar 

  13. L.L. Vatta, R.D. Sanderson, K.R. Kokh, Pure Appl. Chem. 78, 9 (2006)

    Google Scholar 

  14. A. Mirabi, ASh Rad, S. Nourani, TrAC-Trend. Anal. Chem. 74, 146 (2015)

    CAS  Google Scholar 

  15. F.V. Ferreira, L.S. Cividanes, R.F. Gouveia, L.M.F. Lona, Polym. Eng. And Sci. 59(2), 7–15 (2017)

    Google Scholar 

  16. S.S. Ray, M. Bousmina, Progress in Mater. Sci. 50, 962–1079 (2005)

    CAS  Google Scholar 

  17. B.V.M. Rodrigues, A.S. Silva, G.F.S. Melo, L.M.R. Vasconscellos, F.R. Marciano, A.O. Lobo, Mater. Sci. Eng. C 59, 782 (2016)

    CAS  Google Scholar 

  18. K. Van de Velde, P. Kiekens, Polym. Test. 21, 433 (2002)

    Google Scholar 

  19. R.A. Gross, B. Kalra, Science 297, 803 (2002)

    CAS  PubMed  Google Scholar 

  20. J.S. Pereira da Silva, J.M. Farias da Silva, B.G. Soares, S. Livi, Compos. B 129, 117 (2017)

    CAS  Google Scholar 

  21. G.F. Santana-Melo, B.V.M. Rodrigues, E. da Silva, R. Ricci, F.R. Marciano, T.J. Webster, L.M.R. Vasconcellos, A.O. Lobo, Colloids Surf B 155, 544 (2017)

    CAS  Google Scholar 

  22. J.G. de Castro, B.V.M. Rodrigues, R. Ricci, M.M. Costa, A.F.C. Ribeiro, F.R. Marciano, A.O. Lobo, RSC Adv. 6, 32615 (2016)

    Google Scholar 

  23. F. Muroi, Y. Tachibana, Y. Kobayashi, T. Sakurai, K. Kasuya, Polym. Degrad. Stab 129, 338–346 (2016)

    CAS  Google Scholar 

  24. A. Sangroniz, L. Sangroniz, N. Aranburu, M. Fernández, A. Santamaria, M. Iriarte, A. Etxeberria, Eur. Polym. J. 105, 348–358 (2018)

    CAS  Google Scholar 

  25. I. Vroman, L. Tighzert, Materials 2, 307 (2009)

    CAS  PubMed Central  Google Scholar 

  26. U. Witt, R.-J. M€uller, W.-D. Deckwer, J Environ. Polym. Degrad., 5, 81 (1997)

  27. R.-J. Muller, I. Kleeberg, W.-D. Deckwer, J. Biotechnol. 86, 87 (2001)

    CAS  PubMed  Google Scholar 

  28. Y. Ren, J. Hu, M. Yang, Y. Weng, J. Polym. Environ. 27(12), 2784–2792 (2019)

    CAS  Google Scholar 

  29. C.L. Morelli, N. Belgacem, R.E.S. Bretas, J. Bras, J. Appl. Polym. Sci. 133, 1 (2016)

    Google Scholar 

  30. K. Fukushima, A. Rasyida, M.C. Yang, Appl. Clay. Sci. 80–81, 291 (2013)

    Google Scholar 

  31. Y. Someya, Y. Sugahara, M. Shibata, J. Appl. Polym. Sci. 95, 386 (2005)

    CAS  Google Scholar 

  32. I.F. Pinheiro, A.R. Morales, L.H. Mei, Cellulose 21, 4381 (2014)

    CAS  Google Scholar 

  33. F. Le Digabel, N. Boquillon, P. Dole, B. Monties, L. Averous, J. Appl. Polym. Sci. 93, 428 (2004)

    Google Scholar 

  34. T. Mukherjee, M. Czaka, N. Kao, R.K. Gupta, H.J. Choi, S. Bhattacharya, Carbohydr. Polym. 102, 537 (2014)

    CAS  PubMed  Google Scholar 

  35. L. Liu, Y. Zhang, F. Lv, B. Yang, and X. Meng, Polym. Compos. (2015)

  36. S. Muniyasamy, M.M. Reddy, M. Misra, A. Mohanty, Ind. Crops Prod. 43, 812 (2013)

    CAS  Google Scholar 

  37. H. Moustafa, C. Guizani, and A. Dufresne, J. Appl. Polym. Sci., 134, (2017)

  38. D. Meng, J. Xie, G.I.N. Waterhouse, K. Zhang, Q. Zhao, S. Wang, S. Qiu, K. Chen, J. Li, C. Ma, Y. Pan, J. Xu, J. Appl. Polym. Sci. 136, 48485 (2019)

    Google Scholar 

  39. M.A.B.S. Nunes, V.A.D. Marinho, G.A.M. Falcão, E.L. Canedo, M.A.G. Bardi, L.H. Carvalho, J. Pote. 70, 281–288 (2018)

    CAS  Google Scholar 

  40. J.S. Pereira da Silva, J.M. Farias da Silva, B.G. Soares, S. Livi, J. ComB 129, 117–123 (2017)

    CAS  Google Scholar 

  41. L. Lendvai, A. Apostolov, J. Karger-Kocsis, J. Carb. Polym. 173, 566–572 (2017)

    CAS  Google Scholar 

  42. B. Bittmann, R. Bouza, L. Barral, M.V. Gonalez-Rodriguez, M.-J. Abad, Polym. Compos. 33, 2022 (2012)

    CAS  Google Scholar 

  43. J. Varshosaz, K. Arabloo, N. Sarrami, E. Ghassami, E.Y. Kachouei, M. Kouhi, A. Jahanian-Najafabadi, Drug Dev. Ind. Pharm 46, 484–497 (2020)

    CAS  PubMed  Google Scholar 

  44. A. Azizi, J. Inorg. Organomet. Polym., (2020)

  45. S. Kashi, S.A. Hadigheh, R. Varley, Polym. 10, 582 (2018)

    Google Scholar 

  46. R. Venkatesan, N. Rajeswari, Polym. Adv. Technol. 28(12), 1699–1706 (2017)

    CAS  Google Scholar 

  47. B. Bittmann, R. Bouza, L. Barral, R. Bellas, A. Cid, Polym. Compos. 39(3), 915–923 (2016)

    Google Scholar 

  48. R. Venkatesan, N. Rajeswari, Adv. Compos. Hybrid. Mater. 1, 731–740 (2018)

    CAS  Google Scholar 

  49. L.F. Wang, J.W. Rhim, S.I. Hong, LWT 68, 454–461 (2016)

    CAS  Google Scholar 

  50. N.K. Shrivastava, O.S. Wooi, A. Hassan, I.M. Inuwa, Mal. J. Fund. Appl. Sci. 14(4), 425–431 (2018)

    Google Scholar 

  51. P.G. Ren, X.H. Liu, F. Ren, G.J. Zhong, X. Ji, L. Xu, Polym. Test. 58, 173–180 (2017)

    CAS  Google Scholar 

  52. A. Rasyida, K. Fukushima, M-C Yang, Mater. Sci. Eng., 223 (2016)

  53. S. Shankar, J.W. Rhim, Food Packag. Shelf. Life 21, 2214–2894 (2019)

    Google Scholar 

  54. H.T. Wang, J.M. Wang, T.M. Wu, Polym. Int. 68, 1531–1537 (2019)

    CAS  Google Scholar 

  55. P. Zhao, W. Liu, Q. Wu, and J. Ren, J. Nanomater., 4 (2010)

  56. X. Lu, J. Zhao, X. Yang, P. Xiao, Polym. Test. 60, 58–67 (2017)

    CAS  Google Scholar 

  57. P. Ma, L. Jiang, M. Yu, W. Dong, M. Chen, A.C.S. Sustain, Chem. Eng. 4(12), 6417–6426 (2016)

    CAS  Google Scholar 

  58. Q. Xing, D. Ruch, P. Dubois, L. Wu, W.J. Wang, A.C.S. Sustain, Chem. Eng. 5, 10342–10351 (2017)

    CAS  Google Scholar 

  59. H. Moustafa, H. Galliard, L. Vidal, A. Dufresne, Eur. Polym. J. 87, 188–199 (2017)

    CAS  Google Scholar 

  60. F.V. Ferreira, M. Mariano, L.S.S. Lepesqueur, I.F. Pinheiro, L.G. Santos, J. Burga-Sanchez, D.H.S. Souza, C.Y. Koga-Ito, A.A. Teizeira-Neto, L.H.I. Mei, R.F. Gouveia, L.M.F. Lona, Mater. Sci. Eng. C 98, 800–807 (2019)

    CAS  Google Scholar 

  61. I. F. Pinheiro, F. V. Ferreira, G. F. Alves, A. Rodolfo Jr., A. R. Morales, and L. H. I. Mei, J. Polym. Environ., 27, pages757–766 (2019)

  62. R. f. S. Barbosa, A. G. Souza, D. S. Rosa, Polym. Compos., (2020)

  63. F. P. La Mantia, M. Morreale, L. Botta, M.C. Mistretta, M. Ceraulo, and R. Scaffaro, Polym. Degrad. Stab. In press. DOI 10.1016/j.polymdegradstab.2017.07.011

  64. A. Diaz, R. Katsarava, J. Puiggalı, Int. J. Mol. Sci. 15, 7064 (2014)

    CAS  PubMed  PubMed Central  Google Scholar 

  65. R. Al-Itry, K. Lamnawar, A. Maazouz, Polym. Degrad. Stab. 97, 1898 (2012)

    CAS  Google Scholar 

  66. D. Witzke, Introduction to Properties (Michigan State University, Engineering and Prospects of Polylactide Polymers, 1997)

    Google Scholar 

  67. R. Al-try, K. Lamnawar, A. Maazouz, Polym. Degrad. Stab. 97, 1898–1914 (2012)

    Google Scholar 

  68. T. Kijchavengkul, R. Auras, R. Rubino, M. Ngouajio, R.T. Fernandez, Chemosphere 71, 1607–1616 (2008)

    CAS  PubMed  Google Scholar 

  69. T. Kijchavengkul, R. Auras, M. Rubino, Polym. Test. 27, 55–60 (2008)

    CAS  Google Scholar 

  70. L.H., Buxbaum, Angew. Chem. Int. Edit., 7, 182–190 (1968)

  71. A. Rivaton, J.-L. Gardette, Angew. Makromol. Chem. 261(262), 173–188 (1998)

    Google Scholar 

  72. W. Schnabel, Polymer Degradation: Principles and Practical Applications (Hanser, New York, 1992)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Payam Noor University of Mashhad, Mashhad, Iran

    F. Hosseini & Z. Es’haghi

Authors
  1. F. Hosseini
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Es’haghi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Hosseini.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hosseini, F., Es’haghi, Z. Synthesis of Bio-Nanomagnetite Using Poly(butylene adipate) and Poly(butylene adipate-co-terephthalate). J Inorg Organomet Polym 30, 4361–4371 (2020). https://doi.org/10.1007/s10904-020-01584-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01584-9

Keywords

Search

Navigation