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Copper Porphyrin Immobilized on MCM-41 Surface by Using Aminopropyl as Coupling Agent and Its Use in Electrochemical Oxygen Determination

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Abstract

Copper porphyrin was immobilized inside of MCM-41 pores using two different methods, by direct addition of copper porphyrin into the MCM-41 pores and by using aminopropyl group as coupling and spacing group. In the second method the aminopropyl group was previously bonded to copper porphyrin ring, resulting in material with higher copper porphyrin amount and dispersion. The materials were characterized by Cu elemental analysis using microwave plasma-atomic emission spectroscopy, X-ray diffraction, N2 adsorption desorption isotherms and ultraviolet and visible spectroscopy. Carbon paste electrode made with material obtained by second method was used, for the first time, as electrochemical sensors for oxygen determination, showing linear response for current intensity for oxygen concentration in the range of 3.05–23.41 mg L−1. The detection limit was 0.89 mg L−1 and the sensitivity was 3.79 µA L mg−1. These characteristics make this system very promising to be applied as electrochemical sensor for oxygen determination.

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Acknowledgements

The authors are grateful to CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico), FAPERGS (Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul) and CAPES (Coordenação de Aperfeiçoamento Pessoal de Nível Superior) for financial support and Grants (MCT/CNPq/MEC/CAPES Casadinho/Procad Processo 552197/2011-4). The authors thank also LabMeQui for MP-AES analyses.

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Authors and Affiliations

  1. Centro de Ciências Químicas, Farmacêuticas e de Alimentos, Universidade Federal de Pelotas (UFPel), Pelotas, RS, 96.010-900, Brazil

    Lara Machado Pereira Montenegro, Luana Vohlbrecht de Souza, Karina Oliveira Lima & Daniela Bianchini

  2. Instituto de Química, Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS, 91.501-970, Brazil

    Luana Vohlbrecht de Souza, Franciele de Mattos Morawski, Edilson Valmir Benvenutti & Leliz Ticona Arenas

  3. Centro de Ciências Naturais e Humanas, Universidade Federal do ABC (UFABC), Santo André, SP, 09.210-580, Brazil

    Hueder Paulo Moisés de Oliveira

  4. Instituto de Engenharia Biomédica, Universidade Anhembi Morumbi, São José dos Campos, SP, 12.247-016, Brazil

    Adjaci Uchôa Fernandes

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  1. Lara Machado Pereira Montenegro
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  2. Luana Vohlbrecht de Souza
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  9. Daniela Bianchini
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Correspondence to Daniela Bianchini.

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Montenegro, L.M.P., de Souza, L.V., Lima, K.O. et al. Copper Porphyrin Immobilized on MCM-41 Surface by Using Aminopropyl as Coupling Agent and Its Use in Electrochemical Oxygen Determination. J Inorg Organomet Polym 28, 2518–2524 (2018). https://doi.org/10.1007/s10904-018-0919-3

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  • DOI: https://doi.org/10.1007/s10904-018-0919-3

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