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Preparation and Characterization of Dual-Template Molecularly Imprinted Membrane with High Flux Based on Blending the Inorganic Nanoparticles

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Abstract

In this study, the dual-template molecularly imprinted composite membrane (D-MIM) was synthesized using ferulic acid and cinnamic acid as the mixed templates, α-methacrylic acid as functional monomer, ethylene glycol dimethacrylate as crosslinker, 2,2-azobisisobutyronitrile as photoinitiator inducing polymerization reaction, furthermore blended nanoparticles so as to improve mechanical strength and pure water flux of membrane. This paper has researched that the effect of variety of nanoparticles and its quantity, the quantity of photoinitiator, total template–functional monomer (T/F) ratio on performance of prepared membrane. The study has founded optimum parameters of synthesis: nanoparticles 18 nm TiO2 of 1 wt%, photoinitiator of 0.3 g, T/F ratio is 1:3. Under the above conditions, D-MIM would present a high separation efficiency of template molecules (ferulic acid and cinnamic acid) and the analogues (caffeic acid and syringic acid) with the permeation rate of about 100%. However, the permeation rate of glucose which has an analogous formula weight and extremely different structure is about 60%. From the foregoing, it showed that the D-MIM has specific selectively to the template molecules and its analogues, but the substances which have obvious distinctions in structure would present low permeation rate. It can be seen that D-MIM can identify the same kind of substance with specificity. Therefore, it can be used in the enrichment and separation of some active ingredients of traditional Chinese medicine, the detection of toxic substances in food and so on. Finally, the scanning electron microscope and FT-IR spectrometer has been used to visualize the structure morphology of the prepared membrane and to quantity the surface characteristics.

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References

  1. P.A. Cormack, A.Z. Elorza, J. Chromatogr. B 804, 173–182 (2004)

    Article  CAS  Google Scholar 

  2. G. Wulff, Angew. Chem. 107, 1958–1979 (1995)

    Article  Google Scholar 

  3. G. Vlatakis, L.I. Andersson, R. Müller, K. Mosbach, Nature 361, 645–647 (1993)

    Article  CAS  Google Scholar 

  4. N.D. Zakaria, N.A. Yusof, J. Haron, A.H. Abdullah, Int. J. Mol. Sci. 10, 354–365 (2009)

    Article  CAS  Google Scholar 

  5. J. Haginaka, H. Takehira, K. Hosoya, N. Tanaka, J. Chromatogr. A 816, 113–121 (1998)

    Article  CAS  Google Scholar 

  6. R. Sancho, C. Minguillón, Chem. Soc. Rev. 38, 797–805 (2009)

    Article  CAS  Google Scholar 

  7. K. Puzio, B. Claude, L. Amalric, C. Berho, E. Grellet, S. Bayoudh, R. Nehmé, P. Morin, J. Chromatogr. A 1361, 1–8 (2014)

    Article  CAS  Google Scholar 

  8. C. Long, Z. Mai, Y. Yang, B. Zhu, X. Xu, L. Lu, X. Zou, J. Chromatogr. A 1216, 2275–2281 (2009)

    Article  CAS  Google Scholar 

  9. H. Zhang, L. Ye, K. Mosbach, J. Mol. Recognit. 19, 248–259 (2006)

    Article  CAS  Google Scholar 

  10. Z. Altintas, M. Gittens, A. Guerreiro, K.A. Thompson, J. Walker, S. Piletsky, I.E. Tothill, Anal. Chem. 87, 6801–6807 (2015)

    Article  CAS  Google Scholar 

  11. X. Li, Y. He, F. Zhao, W. Zhang, Z. Ye, RSC Adv. 5, 56534–56540 (2015)

    Article  CAS  Google Scholar 

  12. S. Boonpangrak, M.J. Whitcombe, V. Prachayasittikul, K. Mosbach, L. Ye, Biosens. Bioelectron. 22, 349–354 (2006)

    Article  CAS  Google Scholar 

  13. J. Yin, Y. Cui, G. Yang, H. Wang, Chem. Commun. 46, 7688–7690 (2010)

    Article  CAS  Google Scholar 

  14. G. Cirillo, F. Iemma, F. Puoci, O. Parisi, M. Curcio, U. Spizzirri, N. Picci, J. Drug Target. 17, 72–77 (2009)

    Article  CAS  Google Scholar 

  15. W. Cummins, P. Duggan, P. McLoughlin, Biosens. Bioelectron. 22, 372–380 (2006)

    Article  CAS  Google Scholar 

  16. C. Michailof, P. Manesiotis, C. Panayiotou, J. Chromatogr. A 1182, 25–33 (2008)

    Article  CAS  Google Scholar 

  17. F.L. Dickert, P. Achatz, K. Halikias, Fresen. J. Anal. Chem. 371, 11–15 (2001)

    Article  CAS  Google Scholar 

  18. X. Xia, E.P. Lai, B. Örmeci, Environ. Sci. Pollut. Res. 20, 3331–3339 (2013)

    Article  CAS  Google Scholar 

  19. R. Suedee, T. Srichana, T. Chuchome, U. Kongmark, J. Chromatogr. B 811, 191–200 (2004)

    Article  CAS  Google Scholar 

  20. H.J. Im, Y. Yang, L.R. Allain, C.E. Barnes, S. Dai, Z. Xue, Environ. Sci. Technol. 34, 2209–2214 (2000)

    Article  CAS  Google Scholar 

  21. J. Zhang, F. Li, X.-H. Wang, D. Xu, Y.P. Huang, Z.S. Liu, Eur. Polym. J. 80, 134–144 (2016)

    Article  Google Scholar 

  22. Y.P. Duan, C.M. Dai, Y.L. Zhang, Anal. Chim. Acta 758, 93–100 (2013)

    Article  CAS  Google Scholar 

  23. C.M. Dai, J. Zhang, Y.L. Zhang, X.F. Zhou, Y.P. Duan, S.G. Liu, Environ. Sci. Pollut. Res. Int. 20, 5492–5501 (2013)

    Article  CAS  Google Scholar 

  24. C.M. Dai, J. Zhang, Y.L. Zhang, X.F. Zhou, Y.P. Duan, S.G. Liu, Chem. Eng. J. 211–212, 302–309 (2012)

    Article  Google Scholar 

  25. Y. Guo, T. Guo, Chem. Commun. 49, 1073–1075 (2013)

    Article  CAS  Google Scholar 

  26. J. Liu, H. Song, J. Liu, Y. Liu, L. Li, H. Tang, Y. Li, Talanta 134, 761–767 (2015)

    Article  CAS  Google Scholar 

  27. G.O. Yahaya, B.J. Brisdon, M. Maxwell, R. England, J. Appl. Polym. Sci. 82, 808–817 (2001)

    Article  CAS  Google Scholar 

  28. K. Yang, G.N. Wang, H.Z. Liu, J. Liu, J.P. Wang, J. Chromatogr. B 1046, 65–72 (2017)

    Article  CAS  Google Scholar 

  29. X. Zheng, F. Zhang, E. Liu, X. Xu, Y. Yan, ACS Appl. Mater. Interfaces 9, 730–739 (2017)

    Article  CAS  Google Scholar 

  30. K. Sreenivasan, J. Appl. Polym. Sci. 82, 889–893 (2010)

    Article  Google Scholar 

  31. K. Sreenivasan, R. Sivakumar, J. Appl. Polym. Sci. 71, 1823–1826 (1999)

    Article  CAS  Google Scholar 

  32. M. Ulbricht, Polymer 47, 2217–2262 (2006)

    Article  CAS  Google Scholar 

  33. F. Trotta, M. Biasizzo, F. Caldera, Membranes 2, 440–477 (2012)

    Article  CAS  Google Scholar 

  34. C. Algieri, E. Drioli, L. Guzzo, L. Donato, Sensors 14, 13863–13912 (2014)

    Article  Google Scholar 

  35. A. Beltran, F. Borrull, R. Marcé, P. Cormack, TrAC Trends Anal. Chem. 29, 1363–1375 (2010)

    Article  CAS  Google Scholar 

  36. C. Alexander, H.S. Andersson, L.I. Andersson, R.J. Ansell, N. Kirsch, I.A. Nicholls, J. O’Mahony, M.J. Whitcombe, J. Mol. Recognit. 19, 106–180 (2006)

    Article  CAS  Google Scholar 

  37. K.A. Lokhandwala, I. Pinnau, Z. He, K.D. Amo, A.R. DaCosta, J.G. Wijmans, R.W. Baker, J. Membr. Sci. 346, 270–279 (2010)

    Article  CAS  Google Scholar 

  38. F.G. Tamayo, A. Martin-Esteban, J. Chromatogr. A 1098, 116–122 (2005)

    Article  CAS  Google Scholar 

  39. J. He, G. Fang, Q. Deng, S. Wang, Anal. Chim. Acta 692, 57–62 (2011)

    Article  CAS  Google Scholar 

  40. G.S. Jiang, S.A. Zhong, L. Chen, I. Blakey, A. Whitaker, Radiat. Phys. Chem. 80, 130–135 (2011)

    Article  CAS  Google Scholar 

  41. S.H. Choi, D.H. Kim, A.V. Raghu, K.R. Reddy, H.-I. Lee, K.S. Yoon, H.M. Jeong, B.K. Kim, J. Macromol. Sci. B 51, 197–207 (2012)

    Article  CAS  Google Scholar 

  42. R.S. Dong, A.V. Raghu, K.R. Reddy, M.J. Han, J. Am. Coll. Dent. 40, 240–243 (2015)

    Google Scholar 

  43. S.J. Han, H.I. Lee, M.J. Han, B.K. Kim, A.V. Raghu, K.R. Reddy, J. Macromol. Sci. B 53, 1193–1204 (2014)

    Article  CAS  Google Scholar 

  44. M.U. Khan, K.R. Reddy, T. Snguanwongchai, E. Haque, V.G. Gomes, Colloid Polym. Sci. 294, 1–12 (2016)

    Article  Google Scholar 

  45. W. Marashdeh, J.O. Iroh, J. Appl. Polym. Sci. 134, 45372 (2017)

    Article  Google Scholar 

  46. S. Nomura, F. Lundberg, M. Stollenwerk, K. Nakamura, Å. Ljungh, J. Biomed. Mater. Res. 38, 35–42 (2015)

    Article  Google Scholar 

  47. K. Raghava Reddy, V.G. Gomes, M. Hassan, Mater. Res. Express 1, 015012 (2014)

    Article  Google Scholar 

  48. K.R. Reddy, K.V. Karthik, S.B.B. Prasad, S.K. Soni, M.J. Han, A.V. Raghu, Polyhedron 120, 169–174 (2016)

    Article  CAS  Google Scholar 

  49. K.R. Reddy, K.P. Lee, A.I. Gopalan, J. Nanosci. Nanotechnol. 7, 3117 (2007)

    Article  CAS  Google Scholar 

  50. K.R. Reddy, K.P. Lee, A.I. Gopalan, J. Appl. Polym. Sci. 106, 1181–1191 (2007)

    Article  CAS  Google Scholar 

  51. K.R. Reddy, K.P. Lee, Y. Lee, A.I. Gopalan, Mater. Lett. 62, 1815–1818 (2008)

    Article  CAS  Google Scholar 

  52. M.h.. Wei, H.y.. Chen, S. Wang, W.y.. Jiang, Y. Wang, Z.f.. Wu, J. Inorg. Organomet. Polym. Mater. 27, 586–597 (2017)

    Article  CAS  Google Scholar 

  53. J. Svenson, H.S. Andersson, S.A. Piletsky, I.A. Nicholls, J. Mol. Recognit. 11, 83–86 (1998)

    Article  CAS  Google Scholar 

  54. S. Striegler, E. Tewes, Eur. J. Inorg. Chem. 2002, 487–495 (2002)

    Article  Google Scholar 

  55. G. Lancelot, J. Am. Chem. Soc. 99, 7037–7042 (1977)

    Article  CAS  Google Scholar 

  56. Y. Lu, C. Li, H. Zhang, X. Liu, Anal. Chim. Acta 489, 33–43 (2003)

    Article  CAS  Google Scholar 

  57. M.R. Olthof, P.C. Hollman, M.B. Katan, J. Nutr. 131, 66–71 (2001)

    CAS  Google Scholar 

  58. M.N. Clifford, J. Sci. Food Agric. 80, 1033–1043 (2000)

    Article  CAS  Google Scholar 

  59. R.W. Jiang, K.M. Lau, P.M. Hon, T.C. Mak, K.S. Woo, K.P. Fung, Curr. Med. Chem. 12, 237–246 (2005)

    Article  CAS  Google Scholar 

  60. R. Ikeda, H. Uyama, S. Kobayashi, Macromolecules 29, 3053–3054 (1996)

    Article  CAS  Google Scholar 

  61. A. Itoh, K. Isoda, M. Kondoh, M. Kawase, A. Watari, M. Kobayashi, M. Tamesada, K. Yagi, Biol. Pharm. Bull. 33, 983–987 (2010)

    Article  CAS  Google Scholar 

  62. L. Donato, G. Chiappetta, E. Drioli, Sep. Sci. Technol. 46, 1555–1562 (2011)

    Article  CAS  Google Scholar 

  63. Y. Wu, X. Liu, M. Meng, P. Lv, M. Yan, X. Wei, H. Li, Y. Yan, C. Li, J. Membr. Sci. 490, 169–178 (2015)

    Article  CAS  Google Scholar 

  64. J.W. Cho, K.I. Sul, Polymer 42, 727–736 (2001)

    Article  Google Scholar 

  65. P. Fan, B. Wang, Korean J. Chem. Eng. 26, 1813–1820 (2009)

    Article  CAS  Google Scholar 

  66. T. Sergeyeva, O. Brovko, E. Piletska, S. Piletsky, L. Goncharova, L. Karabanova, L. Sergeyeva, A. El’Skaya, Anal. Chim. Acta 582, 311–319 (2007)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Life Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China

    Mei-hua Wei, Shu Wang, Wan-ying Jiang, Hong-yan Chen, Yi Wang & Tao Meng

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  1. Mei-hua Wei
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Correspondence to Shu Wang.

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Wei, Mh., Wang, S., Jiang, Wy. et al. Preparation and Characterization of Dual-Template Molecularly Imprinted Membrane with High Flux Based on Blending the Inorganic Nanoparticles. J Inorg Organomet Polym 28, 295–307 (2018). https://doi.org/10.1007/s10904-017-0716-4

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