Skip to main content
SpringerLink
Log in

Magnetic Properties and Cation Distribution of Bimetallic (Mn–Co) Doped NiFe2O4 Nanoparticles

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Nickel ferrite (NiFe2O4), an inverse spinel crystal structure and a soft transition metal oxide, contemplated as a good magnetic semiconducting material with low coercivity and saturation magnetization (M s). In this study, Ni1−2xMnxCoxFe2O4 (0.0 ≤ x ≤ 0.5) nanoparticles were synthesized by the microwave assisted approach with citric acid as fuel. The effect of both cobalt and manganese substitution on the morphological, structural, and magnetic properties of the NiFe2O4 nanoparticles were studied. X-ray powder diffraction patterns confirm their complete conversion to NiFe2O4 crystal phase and the increase in lattice constant provides evidence for the effect of both Co and Mn substitution. SEM images divulge the nano-size of the prepared products with speck morphology. Magnetic properties of the final products were evaluated using Vibrating Sample Magnetometer and 57Fe Mössbauer spectroscopy. The results from both analyses suggested the M s and coercive field of NiFe2O4 NPs increases as the concentration of Co and Mn increase and Ms getting closer to the bulk value.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M. Kishimoto, Y. Sakurai, T. Ajima, J. Appl. Phys 76, 7506–7509 (1994)

    Article  CAS  Google Scholar 

  2. A. Manikandan, L.J. Kennedy, M. Bououdina, J.J. Vijaya, J. Magn. Magn. Mater. 349, 249–258 (2014)

    Article  CAS  Google Scholar 

  3. M. Pardavi-Horvath, J. Magn. Magn. Mater 215, 171–183 (2000)

    Article  Google Scholar 

  4. M.V. Vellayappan, S.K. Jaganathan, A. Manikandan, RSC Adv. 6, 114859–114878 (2016)

    Article  CAS  Google Scholar 

  5. C. Sun, J.S.H. Lee, M. Zhang, Adv. Drug Deliv. Rev. 60, 1252–1265 (2008)

    Article  CAS  Google Scholar 

  6. A. Teber, K. Cil, T. Yilmaz, B. Eraslan, D.U.G. Surucu, A. Baykal, R. Bansal, Aerospace 4, 2–20 (2017)

    Article  Google Scholar 

  7. S. Joshi, M. Kumar, S. Chhoker, G. Srivastava, M. Jewariya, V.N. Singh, J. Mol. Struct. 1076, 55–62 (2014)

    Article  CAS  Google Scholar 

  8. A. Alarifi, N.M. Deraz, S. Shaban, J. Alloys Compds. 486, 501–506 (2009)

    Article  CAS  Google Scholar 

  9. H. Zhu, R. Jiang, Y. Qian, F.R. Li, J. Yao, S. Jiang, Appl. Surf. Sci. 369, 1–10 (2016)

    Article  CAS  Google Scholar 

  10. F. Wu, X. Wang, M.L.H. Xu, Ceram. Int. 42, 16666–16670 (2016)

    Article  CAS  Google Scholar 

  11. J. Yan, Y. Huang, X. Chen, C. Wei, Synth. Met. doi:10.1016/j.synthmet.2016.09.018

  12. H. Chen, J. Yan, H. Wu, Y. Zhang, S. Liu, J. Power Sources 324, 499–508 (2016)

    Article  CAS  Google Scholar 

  13. S.K. Pradhan, S. Bid, M. Gateshki, V. Petkov, Mater. Chem. Phys. 93, 224–230 (2005)

    Article  CAS  Google Scholar 

  14. K. Maaz, S. Karim, A. Mumtaz, S.K. Hasanain, J. Liu, J.L. Duan, J. Magn. Magn. Mater 321, 1838–1842 (2009)

    Article  CAS  Google Scholar 

  15. D.Y. Li, Y.K. Sun, P.Z. Gao, X.L. Zhang, H.L. Ge, Ceram. Int. 40, 16529–16534 (2014)

    Article  CAS  Google Scholar 

  16. M.M. Hessien, N.Y. Mostafa, O.H. Abd-Elkader, J. Magn. Magn. Mater 398, 109–115 (2016)

    Article  CAS  Google Scholar 

  17. M. Morales, H. Lassri, A. Biondo, A. Rossi, E. Baggio-Saitovitch, J. Magn. Magn. Mater 256, 93–99 (2003)

    Article  CAS  Google Scholar 

  18. Y.M. Al Angari, J. Magn. Magn. Mater 323, 1835–1839 (2011)

    Article  CAS  Google Scholar 

  19. M.S. Lee, J.Y. Lee, D.W. Lee, D.J. Moon, K.Y. Lee, Int. J. Hydrog. Energy 37, 11218–11226 (2012)

    Article  CAS  Google Scholar 

  20. K. Panwar, S. Tiwari, K. Bapna, N.L. Heda, R.J. Choudhary, D.M. Phase, B.L. Ahuja, J. Magn. Magn. Mater 421, 25–30 (2017)

    Article  CAS  Google Scholar 

  21. R. Topkaya, H. Güngüneş, Ş. Eryiğit, E. Sagar, A. Shirsath, A. Yıldız, Baykal, Ceram. Int. 42, 13773–13782 (2016)

    Article  CAS  Google Scholar 

  22. C.T. Cherian, J. Sundaramurthy, M.V. Reddy, P.S. .Kumar, K. Mani, D. Pliszka, C.H. Sow, S. Ramakrishna, B.V.R. Chowdari, ACS Appl. Mater. Interfaces 5, 9957–9963 (2013)

    Article  CAS  Google Scholar 

  23. U. Kurtan, H. Güngüneş, H. Sözeri, A. Baykal, Ceram. Int. 42, 7987–7992 (2016)

    Article  CAS  Google Scholar 

  24. H. Kavas, A. Baykal, M.S. Toprak, Y. Köseoğlu, M. Sertkol, B. Aktaş, J. Alloys Compd. 479, 49–55 (2009)

    Article  CAS  Google Scholar 

  25. B. Md Amir, M. Ünal, H. Geleri, SagarE. Güngüneş, A. Shirsath, Baykal, Superlattice Microstruct. 88, 450–466 (2015)

    Article  Google Scholar 

  26. R.D. Waldron, Phys. Rev. 99, 1727–1735 (1955)

    Article  CAS  Google Scholar 

  27. B. Md. Amir, SagarE. Ünal, M. Shirsath, M. Geleri, A. Sertkol, Baykal, Superlattice Microstruct. 85, 747–760 (2015)

    Article  Google Scholar 

  28. S. Güner, A. Baykal, Md. Amir, H. Güngünes, M. Geleri, H. Sözeri, E. Sagar, M. Shirsath, Sertkol, J. Alloys Compd. 688, 675–686 (2016)

    Article  Google Scholar 

  29. A. Manikandan, M. Durka, S.A. Antony, J. Inorg. Organomet. Polym. Mater. 25, 1019–1031 (2015)

    Article  CAS  Google Scholar 

  30. S. Jayasree, A. Manikandan, A.M.U. Mohideen, C. Barathiraja, S.A. Antony, Adv. Sci. Eng. Med. 7, 672–682 (2015)

    Article  CAS  Google Scholar 

  31. A. Baykal, Ş. Eryiğit, R. Topkaya, H. Güngüneş,A. Yıldız, U. Kurtan, S.E. Shirsath, Md. Amir, Ceram. Int. 43, 4746–4752 (2017)

    Article  CAS  Google Scholar 

  32. S. Joshi, M. Kumar, J. Supercond. Novel Magn. 29, 1561–1572 (2016)

    Article  CAS  Google Scholar 

  33. H. Sözeri, F. Genç, B. Ünal, A. Baykal, B. Aktaş, J. Alloys Compd. 660, 324–335 (2016)

    Article  Google Scholar 

  34. A.M. Jacintha, A. Manikandan, K. Chinnaraj, A.S. Arul, P. Neeraja, J. Nanosci. Nanotechnol. 15, 9732–9740 (2015)

    Article  CAS  Google Scholar 

  35. V. Manikandan, A. Vanitha, E. Ranjith Kumar, S. Kavita, J. Magn. Magn. Mater. 426, 11–17 (2017)

    Article  CAS  Google Scholar 

  36. J. Singh, C. Singh, D. Kaur, H. Zaki, I.A.A. Latif, S.B. Narang, R. Jotania, S.R. Mishra, R. Joshi, P. Dhruv, M. Ghimire, S.E. Shirsath, S.S. Meena, J. Alloys Compd. 695, 1112–1121 (2017)

    Article  CAS  Google Scholar 

  37. M. Siddique, N.M. Butt, Phys. B 405 4211–4215 (2010)

    Article  CAS  Google Scholar 

  38. S.P. Yadav, S.S. Shinde, P. Bhatt, S.S. Meena, K.Y. Rajpure, J. Alloys Compd. 646, 550–556 (2015)

    Article  CAS  Google Scholar 

  39. R.J. Joseyphus, R.J. Joseyphus, A. Narayanasamy, K. Shinoda, B. Jeyadevan, K. Tohji, J. Phys. Chem. Solids 67, 1510–1517 (2006)

    Article  CAS  Google Scholar 

  40. A. Lakshman, P.S.V. Subba Rao, K.H. Rao, Mater. Lett. 60, 7–10 (2006)

    Article  CAS  Google Scholar 

  41. J.P. Hodges, S. Short, J.D. Jorgensen, X. Xiong, B. Dabrovski, S.M. Mini, C.W. Kimball, J. Solid State Chem. 151, 190–209 (2000)

    Article  CAS  Google Scholar 

  42. A.M. Gismelseed, A.A. Yousif, Phys. B 370, 215–222 (2005)

    Article  CAS  Google Scholar 

  43. M.A. Amer, T.M. Meaz, A.G. Mostafa, M. El-Kastawi, A.I. Ghoneim, Ceram. Int. 40, 241–248 (2014)

    Article  CAS  Google Scholar 

  44. K. Krieble, C.C.H. Lo, Y. Melikhov, J.E. Snyder, J. Appl. Phys. 99, 08R102 (2006)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Nano-Medicine Research, Institute for Research & Medical Consultations (IRMC), University of Dammam, P.O. Box 1982, Dammam, 31441, Saudi Arabia

    A. Baykala & Sarah M. Asiri

  2. Department of Chemistry, Middle East Technical University (METU), Eskişehir Yolu, Ankara, Turkey

    Ş. Eryiğit

  3. Faculty of Engineering, Department of Chemistry, Istanbul University, 34320 Avcilar, Istanbul, Turkey

    Md Amir

  4. Department of Physics, Hitit University, 19030 Çevre Yolu Bulvarı, Çorum, Turkey

    H. Güngüneş

  5. TUBITAK-UME, National Metrology Institute, PO Box 54, 41470, Gebze, Kocaeli, Turkey

    H. Sözeri

  6. Spin Device Technology Center, Engineering Faculty, Shinshu University, Nagano, 380-8553, Japan

    Sagar E. Shirsath

  7. Department of Physics, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey

    M. Sertkol

Authors
  1. A. Baykala
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ş. Eryiğit
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Md Amir
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Güngüneş
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. H. Sözeri
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sagar E. Shirsath
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. Sertkol
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Sarah M. Asiri
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Baykala.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baykala, A., Eryiğit, Ş., Amir, M. et al. Magnetic Properties and Cation Distribution of Bimetallic (Mn–Co) Doped NiFe2O4 Nanoparticles. J Inorg Organomet Polym 27, 1893–1900 (2017). https://doi.org/10.1007/s10904-017-0659-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-017-0659-9

Keywords

Search

Navigation