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Syntheses, Crystal Structures and Magnetic Properties of Co(II) Coordination Polymers Based on a Rigid Imidazole Derivative

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Abstract

Two new Co(II)-based coordination polymers, [Co(bib)(SO4)(H2O)2]n·nH2O (1) and [Co(bib)(bptc)0.5(H2O)2]n (2) [bib = 1,4-bis (imidazol-1-yl) benzene, H4bptc = 3,3′,5,5′-biphenyltetracarboxylic acid] have been successfully synthesized under solvothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, X-ray powder diffraction and thermogravimetric analysis. The structure analysis reveals that complex 1 exhibits a novel one-dimensional double chain with μ-O atom of SO4 2− anion bridging the 1D [Co(bib)]∞ chain, while complex 2 shows a 2D (4, 4) net work with deprotonated H4bptc links 1D [Co(bib)]∞ chain. The organic carboxylic acid competes with inorganic acid on the architectures of Co(II) coordination polymers. Furthermore, magnetic properties of 1 and 2 are measured and show antiferromagnetic characters.

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Acknowledgements

The work was supported by National Natural Science Foundation of China (No. 21676215) and the Doctoral Scientific Research Foundation of Xi’an Shiyou University (No. 2016BS31).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xi’an Shiyou University, No.18, East Section Second Dianzi Road, Xi’an, 710065, Shaanxi, China

    Wu-Juan Sun, Cong-Yu Ke, Qun-Zheng Zhang & Xun-Li Zhang

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  1. Wu-Juan Sun
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  2. Cong-Yu Ke
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Correspondence to Wu-Juan Sun.

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Sun, WJ., Ke, CY., Zhang, QZ. et al. Syntheses, Crystal Structures and Magnetic Properties of Co(II) Coordination Polymers Based on a Rigid Imidazole Derivative. J Inorg Organomet Polym 27, 186–193 (2017). https://doi.org/10.1007/s10904-016-0462-z

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  • DOI: https://doi.org/10.1007/s10904-016-0462-z

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