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Four Novel Coordination Polymers Based on Flexible 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene Ligand: Synthesis, Structure, Luminescence and Magnetic Properties

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Abstract

Four new metal–organic coordination polymers, [Co5(btx)2(NDC)4(μ3-OH)2(H2O)2]·H2O}n(1), [Co(btx)(IP)]n(2), [Mn(btx)(NIP)(H2O)]n(3), {[Zn(btx)2(H2O)2]·2NO3·2H2O}n(4) (btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene; H2NDC = 1,4-naphthalenedicarboxylic acid; H2IP = 5-hydroxyisophthalic acid; H2NIP = 5-nitroisophthalic acid) were synthesized under hydrothermal conditions and characterized by techniques of single-crystal X-ray diffraction analysis, elemental analysis, infrared spectra (IR) and thermogravimetric analysis (TGA). The resulting MOFs analyses demonstrate that complex 1 displays a rare 3D 10-connected framework with the point symbol of {36·434·53·62} based on pentanuclear [Co5(μ3-OH)2(COO)8] cluster. Complex 2 presents a 5- connected 2D layer structure with the point symbol of {48·62}. Complex 3 features 4-connected threefold interpenetrating 3D network structure with the {65·8} point symbol. Complex 4 shows a 2D architecture. The variable-temperature magnetic susceptibility data show that the complex 1 exhibits antiferromagnetic interaction. Different to complex 1, the complex 2, 3 both show weak ferromagnetic interaction. Furthermore, the luminescence of complex 4 was also studied.

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References

  1. H. Li, M. Eddaoudi, M. O’Keeffe, and Q. M. Yaghi (1999). Nature 420, 276.

    Article  CAS  Google Scholar 

  2. H. Furukawa, K. E. Cordova, M. O’Keeffe, and Q. M. Yaghi (2013). Science 341, 1230444.

    Article  CAS  PubMed  Google Scholar 

  3. N. Huang, K. C. Wang, H. Drake, P. Y. Cai, J. D. Pang, J. L. Li, S. Che, L. Huang, Q. Wang, and H. C. Zhou (2018). J. Am. Chem. Soc. 140, 6383.

    Article  CAS  PubMed  Google Scholar 

  4. Y. Bai, Y. B. Dou, L. H. Xie, W. Rutledge, J. R. Li, and H. C. Zhou (2016). Chem. Soc. Rev. 45, 2327.

    Article  CAS  PubMed  Google Scholar 

  5. J. W. Liu, L. F. Chen, H. Cui, J. Y. Zhang, L. Zhang, and C. Y. Su (2014). Chem. Soc. Rev. 43, 6011.

    Article  CAS  PubMed  Google Scholar 

  6. Y. M. Zhang, S. Yuan, G. Day, X. Wang, X. Y. Yang, and H. C. Zhou (2018). Coord. Chem. Rev. 354, 28.

    Article  CAS  Google Scholar 

  7. Z. H. Li, T. M. Rayder, L. S. Luo, J. A. Byers, and C. K. Tsung (2018). J. Am. Chem. Soc. 140, 8082.

    Article  CAS  PubMed  Google Scholar 

  8. S. Y. Liu, D. D. Zhou, C. T. He, P. Q. Liao, X. N. Cheng, Y. T. Xu, J. W. Ye, J. P. Zhang, and X. M. Chen (2016). Angew. Chem. Int. Ed. 53, 16021.

    Article  CAS  Google Scholar 

  9. L. D. Hao, X. Y. Li, M. J. Hurlock, X. M. Tu, and Q. Zhang (2018). Chem. Commun. 54, 11817.

    Article  CAS  Google Scholar 

  10. S. Y. Lin, P. M. Usov, and A. J. Morris (2018). Chem. Commun. 54, 6965.

    Article  CAS  Google Scholar 

  11. J. D. Pang, S. Yuan, J. S. Qin, C. P. Liu, C. Lollar, M. Y. Wu, D. Q. Yuan, H. C. Zhou, and M. C. Hong (2018). J. Am. Chem. Soc. 139, 16939.

    Article  CAS  Google Scholar 

  12. Y. L. Wei, H. W. Hou, L. K. Li, Y. T. Fan, and Y. Zhu (2005). Cryst. Growth Des. 5, 1405.

    Article  CAS  Google Scholar 

  13. H. Y. Li, L. H. Cao, Y. L. Wei, H. Xu, and S. Q. Zang (2015). Cryst Eng Comm. 17, 6297.

    Article  CAS  Google Scholar 

  14. S. Mochizuki, T. Kitao, and Takashi Uemura (2018). Chem. Commun. 54, 11843.

    Article  CAS  Google Scholar 

  15. X. F. Xue, Y. Q. Liu, Y. B. Xing, X. Y. Wang, and W. Li (2018). J. Inorg. Organomet. Polym Mater. 28, 820.

    Article  CAS  Google Scholar 

  16. X. L. Wang, X. T. Sha, G. C. Liu, A. X. Tian, and H. Y. Lin (2016). Inorg. Chim. Acta 440, 94.

    Article  CAS  Google Scholar 

  17. G. Aromí, L. A. Barrios, O. Roubeau, and P. Gamez (2011). Coord. Chem. Rev. 255, 485.

    Article  CAS  Google Scholar 

  18. P. P. Sun, Q. Chen, X. Zhu, B. L. Li, and H. Y. Li (2013). Polyhedron 52, 1009.

    Article  CAS  Google Scholar 

  19. J. Qi, Y. Z. Tong, G. T. Tang, Q. L. Wang, L. C. Li, Y. Ma, G. M. Yang, and D. Z. Liao (2015). Polyhedron 90, 123.

    Article  CAS  Google Scholar 

  20. L. Liu, B. Han, X. Q. Liang, Z. Yang, J. T. Jia, F. X. Sun, and G. S. Zhu (2013). J. Mol. Struct. 1047, 338.

    Article  CAS  Google Scholar 

  21. L. R. Lu, M. Shao, Z. X. Wang, X. He, and M. X. Li (2017). Inorg. Chem. Commun. 79, 25.

    Article  CAS  Google Scholar 

  22. X. F. Xue, Y. Q. Liu, Q. Liu, X. Y. Wang, W. Li, and J. H. Peng (2018). J Clust Sci. 29, 625.

    Article  CAS  Google Scholar 

  23. W. Q. Kan, S. Z. Wen, Y. H. Kan, H. Y. Hu, L. Yang, and D. Li (2015). Inorg. Chem. Commun. 61, 85.

    Article  CAS  Google Scholar 

  24. B. F. Meng, Y. Q. Liu, Y. B. Xing, X. Y. Wang, and W. Li (2016). Inorg. Chem. Commun. 73, 142.

    Article  CAS  Google Scholar 

  25. B. Xu, J. Xie, H. M. Hu, X. L. Yang, F. X. Dong, M. L. Yang, and G. L. Xue (2014). Cryst. Growth Des. 14, 1629.

    Article  CAS  Google Scholar 

  26. L. Chen, L. Zhang, S. L. Li, Y. Q. Qiu, K. Z. Shao, X. L. Wang, and Z. M. Su (2013). CrystEngComm 15, 8214.

    Article  CAS  Google Scholar 

  27. Y. F. Peng, B. Z. Li, J. H. Zhou, B. L. Li, and Y. Zhang (2004). Chin. J. Struct. Chem. 23, 985.

    CAS  Google Scholar 

  28. R.J. Hill, D.L. Long, N.R. Champness, P. Hubberstey, M.Acc. Schröder (2005) Chem. Res. 38, 337.

  29. L. Zhang, L. Liu, C. Huang, X. Han, L. Guo, H. Xu, H. Hou, and Y. Fan (2015). Cryst. Growth Des. 15, 3426.

    Article  CAS  Google Scholar 

  30. X. L. Wang, F. F. Sui, H. Y. Lin, J. W. Zhang, and G. C. Liu (2014). Cryst. Growth Des. 14, 3438.

    Article  CAS  Google Scholar 

  31. X. F. Xue, Y. Q. Liu, Y. B. Xing, X. Y. Wang, and W. Li (2018). J Clust Sci. 29, 121.

    Article  CAS  Google Scholar 

  32. Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang, and K. L. Lu (2001). Inorg. Chem. 40, 6426.

    Article  CAS  PubMed  Google Scholar 

  33. L. Yang, W. Jin, and J. Lin (2000). Polyhedron 19, 93.

    Article  CAS  Google Scholar 

  34. J. J. Liu, C. X. He, F. X. Cheng, and C. C. Huang (2017). Z. Anorg. Allg. Chem. 643, 548.

    Article  CAS  Google Scholar 

  35. J. Y. Liang, W. Y. Zhang, Y. T. Yan, Y. L. Wu, G. P. Li, W. Q. Tong, and Y. Y. Wang (2018). Z. Anorg. Allg. Chem. 644, 504.

    Article  CAS  Google Scholar 

  36. Y. T. Yan, W. Y. Zhang, F. Zhang, F. Cao, R. F. Yang, Y. Y. Wang, and L. Hou (2018). Dalton Trans. 47, 1682.

    Article  CAS  PubMed  Google Scholar 

  37. C. I. Yang, P. H. Chuang, G. H. Lee, S. M. Peng, and K. L. Lu (2012). Inorg. Chem. 51, 757.

    Article  CAS  PubMed  Google Scholar 

  38. J. M. Hao, L. N. Wang, K. Van Hecke, and G. H. Cui (2014). Inorg. Chem. Commun. 41, 43.

    Article  CAS  Google Scholar 

  39. L. L. Wen, Z. D. Lu, J. G. Lin, Z. F. Tian, H. Z. Zhu, and Q. J. Meng (2007). Cryst. Growth Des. 7, 93.

    Article  CAS  Google Scholar 

  40. L. P. Zhang, J. F. Ma, J. Yang, Y. Y. Pang, and J. C. Ma (2010). Inorg. Chem. 49, 1535.

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Scientific Research Foundation for the Introduced Talents of Kunming University of Science and Technology (No. KKSY201507026), the Analysis Testing Fund of Kunming University of Science and Technology (No. 2017T20040109, No. 2018M20162111054), the Joint Fund of National Natural Science Foundation of China and Yunnan (Grant No. U1502273), and National Key Basic Research Program (973 Program, Grant No. 2014CB643406).

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Authors and Affiliations

  1. Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Xiaofei Xue, Yuqi Liu, Qiang Liu, Xinying Wang & Wei Li

  2. The State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, 650093, People’s Republic of China

    Wei Li

  3. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, People’s Republic of China

    Wei Li

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  1. Xiaofei Xue
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Correspondence to Yuqi Liu.

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Xue, X., Liu, Y., Liu, Q. et al. Four Novel Coordination Polymers Based on Flexible 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene Ligand: Synthesis, Structure, Luminescence and Magnetic Properties. J Clust Sci 30, 777–787 (2019). https://doi.org/10.1007/s10876-019-01539-2

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