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Synthesis and Structural and Initial Cancer Cell Line Characterization of Organotin Polyesters from Dipicolinic Acid

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Abstract

The interfacial polymerization is employed to produce high polymer poly(ester ethers) from the reaction of the salt of dipicolinic acid and various organotin dihalides. They are rapidly synthesized with yield increasing as the length of the organotin alkyl chain increases. Infrared spectroscopy shows the formation of new bands derived from the Sn–O and Sn–O(CO) linkages. IR also shows that the products exist as a combination of molecular geometries about the tin atom. MALDI MS shows formation of ion fragment clusters to five and six units in length. The products show good inhibition of a variety of cancer cell lines including two pancreatic cancer cell lines.

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References

  1. C. Carraher, M.R. Roner, J. Organomet. Chem. 751, 67 (2014)

    Article  CAS  Google Scholar 

  2. A. Sengupta, C. Shende, S. Farquharson, F. Inscore, Int. J. Spectrosc. 5, 176 (2012)

    Google Scholar 

  3. T. Sliemandagger, W. Nicholson, Appl. Environ. Microbiol. 67, 1274 (2001)

    Article  Google Scholar 

  4. M. Kirillova, M. Da Silva, A. Kirilov, J. De Silva, A. Pombeiro, Inorg. Chim. Acta. 360, 506 (2007)

    Article  CAS  Google Scholar 

  5. Z. Vargova, V. Zeleoak, I. Cisaova, K. Gyoryova, Thermochim. Acta 423, 149 (2004)

    Article  CAS  Google Scholar 

  6. T. Ohsugi, H. Sumi, J. Food Biochem. 35, 370 (2011)

    Article  CAS  Google Scholar 

  7. A. Colak, F. Colak, O. Yesilel, O. Buyukgungor, J. Coord. Chem. 62, 1650 (2009)

    Article  CAS  Google Scholar 

  8. H. Ilkimen, C. Yenikaya, M. Sari, M. Bulbul, E. Tunca, Y. Suzen, Polyhedron 61, 56 (2013)

    Article  CAS  Google Scholar 

  9. C. Yenijaya, N. Buhyukkidan, M. Sari, R. Keslis, H. Ilkimen, M. Bulbul, O. Buyukgungor, J. Coord. Chem. 64, 3353 (2011)

    Article  Google Scholar 

  10. H. Weng, B. Yan, Inorg. Chem. Commun. 63, 11 (2016)

    Article  CAS  Google Scholar 

  11. R.-Z. Du, Y.-Y. Wang, Y.-Y. Xie, H.-T. Li, T.-F. Liu, J. Mol. Struct. 1108, 96 (2016)

    Article  CAS  Google Scholar 

  12. M. Ghadermazi, Z. Derikvad, A. Zahedi, A. Shokrollahi, S. Nasin, A. Rudbari, Monatschfte Chemie 146, 1257 (2015)

    Article  CAS  Google Scholar 

  13. G. Kumar, G. Kuman, R. Gupta, Inorg. Chim. Acta 425, 260 (2015)

    Article  CAS  Google Scholar 

  14. S. Sharif, O. Sabin, B. Khan, I. Ullah Khan, J. Coord. Chem. 68, 2725 (2015)

    Article  CAS  Google Scholar 

  15. H. Li, Syn. React. Inorg. Metal-Org. Nano-Metal Chem. 45, 1664 (2015)

    Article  CAS  Google Scholar 

  16. C. Carraher, J. Inorg. Organometal. Polym. Mat. 15, 121 (2005)

    Article  CAS  Google Scholar 

  17. C. Carraher, M. Roner, R. Lambert, L. Arroyo, L. Miller, J. Inorg. Organomet. Polym. 25, 1414 (2015)

    Article  CAS  Google Scholar 

  18. C. Carraher, N.T.C. Truong, M. Roner, A. Moric-Johnson, N. Sookdeo, N. Trang, Inorg. Chim. Acta 423, 83–92 (2014)

    Article  CAS  Google Scholar 

  19. C. Carraher, A. Morrison, M. Roner, A. Moric, N. Trang, J. Inorg. Organomet. Polym. 24, 182 (2014)

    Article  CAS  Google Scholar 

  20. M. Barber, R.S. Bordoli, R.D. Sedwick, A.N. Tyler, Nature 293, 270 (1981)

    Article  CAS  Google Scholar 

  21. L.K. Liu, K.L. Busch, R.G. Cooks, Anal. Chem. 53, 109 (1981)

    Article  CAS  Google Scholar 

  22. K. Tanaka, H. Waki, Y. Ido, S. Akita, Y. Yoshida, T. Yoshida, Rapid Commun. Mass Spectrom. 2, 151 (1988)

    Article  CAS  Google Scholar 

  23. M. Karas, F. Hillenkamp, Anal. Chem. 60, 2299 (1988)

    Article  CAS  Google Scholar 

  24. C. Carraher, G. Barot, A. Battin, J. Polym. Mater. 26, 17 (2009)

    CAS  Google Scholar 

  25. C. Carraher, T. Sabir, C.L. Carraher, J. Polym. Mater. 23, 143 (2006)

    CAS  Google Scholar 

  26. C. Carraher, T. Sabir, C.L. Carraher, Inorganic Organometallic Macromolecules (Springer, New York, 2008), p. 329

    Book  Google Scholar 

  27. C. Carraher, M. Roner, C.L. Carraher, R. Crichton, K. Black, J. Macromol. Sci. 52, 867–886 (2015)

    Article  CAS  Google Scholar 

  28. C. Carraher, V. Suresh, M. Roner, J. Polym. Mater. 32, 151 (2015)

    Google Scholar 

  29. C. Carraher, M.R. Roner, K. Shahi, G. Barot, Materials 4, 801 (2011)

    Article  CAS  Google Scholar 

  30. C. Carraher, M.R. Roner, M. Ayhoub, N. Pham, A. Moric-Johnson, Polym. Mater. Polym. Biomat. 64, 311 (2015)

    Article  CAS  Google Scholar 

  31. C. Carraher, M.R. Roner, K. Shahi, A. Moric-Johnson, L. Miller, G. Barot, A. Battin, N. Trang, N. Sookdeo, Z. Islam, Int. J. Poly. Mater. 64, 800–814 (2015)

    Article  CAS  Google Scholar 

  32. C. Carraher, M.R. Roner, K. Shahi, G. Barot, Materials 4, 801 (2011)

    Article  CAS  Google Scholar 

  33. G. Barot, M.R. Roner, Y. Naoshima, K. Nago, K. Shahi, C. Carraher, J. Inorg. Organomet. Polym. 19, 12 (2009)

    Article  CAS  Google Scholar 

  34. C. Carraher, M.R. Roner, K. Shahi, Y. Ashida, G. Barot, J. Inorg. Organomet. Polym. 18, 180 (2008)

    Article  CAS  Google Scholar 

  35. C. Carraher, M. Ayoub, M.R. Roner, A. Moric, N.T. Trang, J. Chin. Adv. Mater. Soc. 1, 65 (2013)

    Article  CAS  Google Scholar 

  36. C. Carraher, M.R. Roner, K. Shahi, A. Battin, G. Barot, T. Arnold, J. Polym. Mater. 31, 1 (2014)

    CAS  Google Scholar 

  37. C. Carraher, M.R. Roner, K. Shahi, A. Moric-Johnson, L. Miller, G. Barot, A. Battin, N. Trang, M. Alhuniti, J. Inorg. Organomet. Polym. 25, 386 (2015)

    Article  CAS  Google Scholar 

  38. C. Carraher, M.R. Roner, M. Ayoub, R. Crichton, A. Moric-Johnson, L. Miller, K. Black, J. Macromol. Sci. 53, 328 (2016)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431, USA

    Charles E. Carraher Jr., Paul P. Slawek, Jeffrey D. Einkauf & Floyd Russell

  2. Department of Biology, University of Texas Arlington, Arlington, TX, 76010, USA

    Michael R. Roner, Alisa Moric-Johnson & Lindsey C. Miller

Authors
  1. Charles E. Carraher Jr.
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  2. Paul P. Slawek
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  3. Michael R. Roner
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  4. Alisa Moric-Johnson
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  5. Lindsey C. Miller
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  6. Jeffrey D. Einkauf
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  7. Floyd Russell
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Correspondence to Charles E. Carraher Jr..

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Dedication

This paper recognizes the many contributions that Professor Dr. Anatoli D. Pomogailo made to the field of polymers and chemistry in general. He is a dear friend and fellow comrade and we greatly miss him.

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Carraher, C.E., Slawek, P.P., Roner, M.R. et al. Synthesis and Structural and Initial Cancer Cell Line Characterization of Organotin Polyesters from Dipicolinic Acid. J Inorg Organomet Polym 26, 1338–1350 (2016). https://doi.org/10.1007/s10904-016-0424-5

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  • DOI: https://doi.org/10.1007/s10904-016-0424-5

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