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Syntheses, Structures, Magnetism and Fluorescence Studies of Two 1D Cu(II) Coordination Polymers Based on Bipyridyl Ligands

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Abstract

Two one-dimesional (1D) coordination polymers (CPs) [Cu2(μ 2-OAc)4(μ 2-bpt)] n (1) and [Cu(μ t-DMF)(μ t-NO3)2(μ 2-bpmh)] n (2) (DMF = N,N-dimethylformamide) based on copper(II) salts and 3,5-bis(4-pyridyl)-1,2,4-triazole (bpt) and 1,2-bis(pyridin-4-ylmethylene)hydrazine (bpmh) have been synthesized under different conditions, respectively; and characterized by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analyses, powder X-ray diffraction, fluorescence analysis, fourier transforming infrared and ultraviolet–visible spectroscopies. CP 1 shows an infinite 1D zigzag chain with paddle-wheel shaped [Cu2(μ 2-OAc)4] secondary building units (SBUs) and μ 2-bpt V-shaped dipyridyl ligands. The Cu···Cu distance in the [Cu2(μ 2-OAc)4] core is 2.631(18) Å, supporting the Cu···Cu interaction. Cu(II) in CP 2 also adopts five-coordinated mode but in trigonal bipyramidal geometry which is completed by three O atoms from nitrates and DMF and also two N atoms from adjacent bpmh to form an infinite 1D linear chain. Furthermore, the magnetism property of CP 1 was investigated. Its results show that CP 1 indicated antiferromagnetic behavior. In addition, CPs 1 and 2 display fluorescence quenching compared with corresponding free ligands at room temperature.

Graphical Abstract

CPs 1 and 2 were hydrothermally synthesized and solution interdiffusion procedure, respectively. Both of which show 1D infinite zigzag chain but pack in different patterns. CP 1 shows an infinite 1D zigzag chain with paddle-wheel shaped [Cu2(μ 2-OAc)4] secondary building units (SBUs) and μ 2-bpt V-shaped dipyridyl ligands. Cu(II) in CP 2 also adopts five-coordinated mode but in trigonal bipyramidal geometry which is completed by three O atoms from nitrates and DMF and also two N atoms from adjacent bpmh to form an infinite 1D linear chain. CP 1 shows antiferromagnetic behavior. Both CPs 1 and 2 display fluorescence quenching compared with corresponding free ligands at room temperature.

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Acknowledgments

Financial support from the National Natural Science Foundation of China (51432006, 50925207 and 51172100), the Ministry of Science and Technology of China for the International Science Linkages Program (2009DFA50620 and 2011DFG52970), the Ministry of Education of China for the Changjiang Innovation Research Team (IRT1064), the Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project (B13025), and Jiangsu Innovation Research Team are gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Molecular Engineering and Advanced Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China

    Huajian Zhao & Chi Zhang

  2. China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Chi Zhang

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  1. Huajian Zhao
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  2. Chi Zhang
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Correspondence to Huajian Zhao or Chi Zhang.

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Zhao, H., Zhang, C. Syntheses, Structures, Magnetism and Fluorescence Studies of Two 1D Cu(II) Coordination Polymers Based on Bipyridyl Ligands. J Inorg Organomet Polym 25, 912–920 (2015). https://doi.org/10.1007/s10904-015-0188-3

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