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Synthesis, Structural Characterization, Properties of a Silver Coordination Polymer Based on [1,1′-Biphenyl]-2,4,4′,6-tetracarboxylic Acid (H4BPTC)

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Abstract

A new silver coordination polymer [Ag4(BPTC)]n has been synthesized by solvothermal reaction of AgNO3 and H4BPTC. The X-ray crystal structural analysis indicates that 1 is a 2D coordinated framework, which contains argentophilic interactions and Ag–C interactions. The thermal stability and luminescent properties were also investigated. In addition, it was found to be efficient catalyst for the Sonogashira reaction.

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Acknowledgments

This work was supported by the Aid Project for the Leading Young Teachers in Henan Provincial Institutions of Higher Education of China (2013GGJS-151), Innovation Scientists and Technicians Troop Construction Projects of Henan Province, and the Science Foundation of Henan Education Department (14A150049).

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Authors and Affiliations

  1. College of Life Science, Luoyang Normal University, Luoyang, 471022, Henan, China

    Hong-Mei Li

  2. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, China

    Chen Xu & Xin-Hua Lou

Authors
  1. Hong-Mei Li
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  2. Chen Xu
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  3. Xin-Hua Lou
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Correspondence to Chen Xu.

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Li, HM., Xu, C. & Lou, XH. Synthesis, Structural Characterization, Properties of a Silver Coordination Polymer Based on [1,1′-Biphenyl]-2,4,4′,6-tetracarboxylic Acid (H4BPTC). J Inorg Organomet Polym 25, 832–836 (2015). https://doi.org/10.1007/s10904-015-0166-9

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  • DOI: https://doi.org/10.1007/s10904-015-0166-9

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