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Synthesis, Structure and Properties of Three New Polymers Based on 5-(Pyridin-3-yl)isophthalic Acid

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Abstract

Three new metal–organic complexes [Fe(pyip)(H2O)2]n (1), [Co(pyip)(H2O)2]n (2) and [Ni(pyip)(H2O)2]n (3) have been synthesized and characterized based on the carboxylic acid with N donor ligand (H2pyip=5-(Pyridin-3-yl)isophthalic acid). X-ray structure analysis reveals that complexes 1–3 showed identical 3-D supramolecular architecture that adopt different metal center. They all crystallize in hexagonal space group P6(5) and exhibited exclusive coordination mode. One of the H2pyip adopt bidentate chelate coordination mode and the other coordination carboxylate oxygen atom adopts the single dentate bridging mode. Moreover, the two novel complexes were characterized by IR spectrum, elemental analysis, fluorescent properties, thermogravimetric analysis and powder X-ray diffraction.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (21267003), P.R. China, the Natural Science Foundation of Guangxi (053020), P.R. China and Guangxi University for Nationalities.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, Peoples Rebublic of China

    Kai-Fei Wu, Fen Jiang, Han Xiao, Xian-Li Bai, Shao-Yin Mo & Yu Feng

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  1. Kai-Fei Wu
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Correspondence to Yu Feng.

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Wu, KF., Jiang, F., Xiao, H. et al. Synthesis, Structure and Properties of Three New Polymers Based on 5-(Pyridin-3-yl)isophthalic Acid. J Inorg Organomet Polym 25, 755–762 (2015). https://doi.org/10.1007/s10904-014-0154-5

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  • DOI: https://doi.org/10.1007/s10904-014-0154-5

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