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Facile Synthesis of Intelligent Polymers Modified Gold Nanoparticles in Aqueous Solution

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Abstract

This paper describes the synthesis of gold nanoparticles (GNPs) stabilized with intelligent poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA). First, the dithioester-terminated PDMAEMA was prepared by the reversible addition-fragmentation chain transfer technique. Then, the dithioester-terminated PDMAEMA was reduced to a thiol-terminated polymer PDMAEMA-SH. PDMAEMA coated GNPs (Au@PDMAEMA NPs) were synthesized in situ from HAuCl4 aqueous solution by using NaBH4 as a reductant and thiolated PDMAEMA as a stabilizer through Au–S bond. The optical and physical properties of GNPs were characterized by UV–Vis spectroscopy, transmission electron microscopy, X-ray diffraction as well as thermogravimetric analysis. The size and shape of GNPs could be controlled by tuning both the [PDMAEMA]:[HAuCl4] molar ratio and the solution pH. It is believed that these highly biocompatible GNPs have potential biomedical applications.

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Scheme 1
Fig. 1We are very sorry, we found that the molecular structure in Fig.1 is wrong. We changed it, please download in the attachment.
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References

  1. J. Nam, N. Won, H. Jin, H. Chung, S. Kim, J. Am. Chem. Soc. 131, 13639 (2009)

    Article  CAS  Google Scholar 

  2. C.M. Cobley, J. Chen, E.C. Cho, L.V. Wang, Y.N. Xia, Chem. Soc. Rev. 40, 44 (2011)

    Article  CAS  Google Scholar 

  3. M.C. Daniel, D. Astruc, Chem. Rev. 104, 293 (2004)

    Article  CAS  Google Scholar 

  4. R. Sardar, A.M. Funston, P. Mulvaney, Langmuir 25, 13840 (2009)

    Article  CAS  Google Scholar 

  5. N. Khlebtsov, L. Dykman, Chem. Soc. Rev. 40, 1647 (2011)

    Article  CAS  Google Scholar 

  6. D.X. Li, Q. He, Y. Yang, H. Möhwald, J.B. Li, Macromolecules 41, 7254 (2008)

    Article  CAS  Google Scholar 

  7. M. Nuopponen, H. Tenhu, Langmuir 23, 5352 (2007)

    Article  CAS  Google Scholar 

  8. H. Guan, W. Wang, X.F. Liu, J.Z. Liang, Colloids Surf. A 448, 147 (2014)

    Article  CAS  Google Scholar 

  9. S. Sistach, M. Beija, V. Rahal, A. Brûlet, J.D. Marty, M. Destarac, C. Mingotaud, Chem. Mater. 22, 3712 (2010)

    Article  CAS  Google Scholar 

  10. P.W. Zheng, X.W. Jiang, X. Zhang, W.Q. Zhang, L.Q. Shi, Langmuir 22, 9393 (2006)

    Article  CAS  Google Scholar 

  11. M.T. Popescu, C. Tsitsilianis, ACS Macro. Lett. 2, 222 (2013)

    Article  CAS  Google Scholar 

  12. D.X. Li, Q. He, J.B. Li, Adv. Colloid Interface Sci. 149, 28 (2009)

    Article  CAS  Google Scholar 

  13. J. Gao, X.Y. Huang, H. Liu, F. Zan, J.C. Ren, Langmuir 28, 4464 (2012)

    Article  CAS  Google Scholar 

  14. I. Blakey, Z. Merican, K.J. Thurecht, Langmuir 29, 8266 (2013)

    Article  CAS  Google Scholar 

  15. Y.N. Wen, X.S. Jiang, G.L. Yin, J. Yin, Chem. Commun., 6595 (2009)

  16. S.Z. Luo, J. Xu, Y.F. Zhang, S.Y. Liu, C. Wu, J. Phys. Chem. B 109, 22159 (2005)

    Article  CAS  Google Scholar 

  17. A.P. Majewski, U. Stahlschmidt, V. Jérôme, R. Freitag, A.H.E. Müller, H. Schmalz, Biomacromolecules 14, 3081 (2013)

    Article  CAS  Google Scholar 

  18. X.J. Huang, Y. Xiao, W. Zhang, M.D. Lang, Appl. Surf. Sci. 258, 2655 (2012)

    Article  CAS  Google Scholar 

  19. A.E. Smith, X.W. Xu, T.U. Abell, S.E. Kirkland, R.M. Hensarling, C.L. Mccormick, Macromolecules 42, 2958 (2009)

    Article  CAS  Google Scholar 

  20. L.Y. Li, W.D. He, W.T. Li, K.R. Zhang, T.T. Pan, Z.L. Ding, B.Y. Zhang, J. Polym. Sci. Part A 48, 5018 (2010)

    Article  CAS  Google Scholar 

  21. X. Chen, D.Y. Zhao, L.Z. Zhao, Y.L. Aa, R.J. Ma, L.Q. Shi, Q.J. He, L. Chen, Sci. China Ser. B 52, 1372 (2009)

    Article  CAS  Google Scholar 

  22. R.T.A. Maya dunne, E. Rizzardo, J. Chiefari, J. Krstina, G. Moad, A. Postma, S.H. Thang, Macromolecules 33, 243 (2000)

    Article  CAS  Google Scholar 

  23. N. Reum, C. Fink-Straube, T. Klein, R.W. Hartmann, C.M. Lehr, M. Schneider, Langmuir 26, 16901 (2010)

    Article  CAS  Google Scholar 

  24. H.W. Duan, M. Kuang, D.Y. Wang, D.G. Kurth, H. Möhwald, Angew. Chem. Int. Ed. 44, 1717 (2005)

    Article  CAS  Google Scholar 

  25. C.H. Wang, C.J. Liu, C.L. Wang, T.E. Hua, J.M. Obliosca, K.H. Lee, Y. Hwu, C.S. Yang, R.S. Liu, H.M. Lin, J.H. Je, G. Margaritondo, J. Phys. D 41, 195301 (2008)

    Article  Google Scholar 

  26. J.B. Song, L. Cheng, A.P. Liu, J. Yin, M. Kuang, H.W. Duan, J. Am. Chem. Soc. 133, 10760 (2011)

    Article  CAS  Google Scholar 

  27. R.G. Shimmin, A.B. Schoch, P.V. Braun, Langmuir 20, 5613 (2004)

    Article  CAS  Google Scholar 

  28. S.K. Jewrajka, U. Chatterjee, J. Polym. Sci. Part. A 44, 1841 (2006)

    Article  CAS  Google Scholar 

  29. Z.Q. Zhang, Y.H. Wu, Langmuir 26, 9214 (2010)

    Article  CAS  Google Scholar 

  30. H. Hu, X.D. Fan, Z.L. Cao, Polymer 46, 9514 (2005)

    Article  CAS  Google Scholar 

  31. D.X. Li, Q. He, Y. Cui, J.B. Li, Chem. Mater. 19, 412 (2007)

    Article  CAS  Google Scholar 

  32. R. Sardar, N.S. Bjorge, J.S. Shumaker-Parry, Macromolecules 41, 4347 (2008)

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support from the Science and Technology Development Program of Henan province of China (132300410235 and 122102210228) is gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Fine Chemical and Engineering, Henan University, Kaifeng, 475004, Henan, People’s Republic of China

    Cuiping Zhai, Xuejun Liu, Xia Chen, Lina Li, Fang Sun & Huiting Ma

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  1. Cuiping Zhai
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  2. Xuejun Liu
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  3. Xia Chen
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  4. Lina Li
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  5. Fang Sun
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  6. Huiting Ma
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Correspondence to Xuejun Liu.

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Zhai, C., Liu, X., Chen, X. et al. Facile Synthesis of Intelligent Polymers Modified Gold Nanoparticles in Aqueous Solution. J Inorg Organomet Polym 25, 687–693 (2015). https://doi.org/10.1007/s10904-014-0146-5

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  • DOI: https://doi.org/10.1007/s10904-014-0146-5

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