Abstract
Three new MOFs, namely [Ni(pip)(H2O)2] (1), [Ba(pip)(H2O)] (2), [Zn(pip)] (3), based on 6-(3-pyridyl)isophthalic acid (H2pip) were obtained and characterized by single-crystal X-ray diffraction, elemental analyses, PXRD, IR and TGA. By adjusting the reaction solvent, temperature and selecting different metal centers, compounds 1 and 2 possess 1D and 2D network, respectively, compound 3 show a 3D network containing a paddlewheel secondary building unit [SBU, Zn2(COO)4] with the Schläfli symbol (4·62)2(42·610·83). The structural differences among compounds 1–3 exhibit the backbone of such mixed N- and O-donor atoms organic ligands can be used to construct diverse dimensional MOFs by adjusting the reaction environment. Furthermore, the luminescence properties of compounds 2 and 3 were investigated, and both of them exhibit intense fluorescent emissions in the solid state at room temperature.
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Y.Y. Liu, Y.P. Chen, T.F. Liu, A.A. Yakovenko, A.M. Raiffa, H.C. Zhou, CrystEngComm 15, 968 (2013)
L.Q. Han, Y. Yan, F.X. Sun, K. Cai, B. Borjigin, X.J. Zhao, F.Y. Qu, G.S. Zhu, Cryst. Growth Des. 13, 1458 (2013)
H. Furukawa, F. Gandara, Y.B. Zhang, J.C. Jiang, W.L. Queen, M.R. Hudson, O.M. Yaghi, J. Am. Chem. Soc. 136, 4369 (2014)
S.S. Chen, P. Wang, S. Takamizawa, T.A. Okamura, M. Chen, W.Y. Sun, Dalton Trans. 43, 6012 (2014)
P. Wang, L. Luo, J. Fan, G.C. Lv, Y. Song, W.Y. Sun, Microporous and Mesoporous Materials 175, 116 (2013)
S.J. Wang, S.S. Xiong, L.X. Song, Z.Y. Wang, CrystEngComm 11, 896 (2009)
G.X. Jin, J.P. Ma, Y.-B. Dong, J. Mol. Struct. 1052, 146 (2013)
Z.P. Deng, Z.Y. Zhang, L.H. Huo, S.W. Ng, H. Zhao, S. Gao, CrystEngComm 14, 6548 (2012)
H.M. He, F.X. Sun, T. Borjigin, N. Zhao, G.S. Zhu, Dalton Trans. 43, 3716 (2014)
Y.B. Xie, H. Yang, Z.U. Wang, Y.Y. Liu, H.C. Zhou, J.R. Li, Chem. Commun. 50, 563 (2014)
P. Phuengphai, S. Youngme, P. Kongsaeree, C. Pakawatchai, N. Chaichit, S.J. Teat, P. Gamez, J. Reedijk, CrystEngComm 11, 1723 (2009)
N.N. Adarsh, P. Sahoo, P. Dastidar, Cryst. Growth Des. 10, 4976 (2010)
P. Kanoo, K.L. Gurunatha, T.K. Maji, Cryst. Growth Des. 9, 4147 (2009)
C.H. Zhan, F. Wang, Y. Kang, J. Zhang, Inorg. Chem. 51, 523 (2012)
J. Sun, D. Sun, S. Yuan, D.X. Tian, L.L. Zhang, X.P. Wang, D.F. Sun, Chem. Eur. J. 18, 16525 (2012)
C. Volkringer, T. Loiseau, N. Guillou, G. Férey, M. Haouas, F. Taulelle, N. Audebrand, I. Margiolaki, D. Popov, M. Burghammer, C. Riekel, Cryst. Growth Des. 9, 2927 (2009)
X.L. Zhao, W.Y. Sun, CrystEngComm 16, 3247 (2014)
SAINT Software Reference Manual (Bruker Analytical X-ray System Inc., Madison, 1998), p.243
G.M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures (University of Göttingen, Germany, 1997), p.246
L.J. Farrugia, J. Appl. Crystallogr. 32, 837 (1999)
A.L. Spek, J. Appl. Crystallogr. 36, 7 (2003)
A.L. Spek, PLATON: A Multipurpose Crystallographic Tool (Utrecht University, Utrecht, 2006)
U.H.F. Buna, Chem. Rev. 100, 1605 (2000)
S. Zang, Y. Su, Y.Z. Li, J. Lin, X. Duan, Q. Meng, S. Gao, CrystEngComm 11, 122 (2009)
J.Q. Liu, Y.N. Zhang, Y.Y. Wang, J.C. Jin, E.K. Lermontova, Q.Z. Shi, Dalton Trans. 24, 5365 (2009)
G. Yu, S.W. Yin, Y. Liu, Z.G. Shuai, D. Zhu, J. Am. Chem. Soc. 125, 14816 (2003)
R. Singh, M. Ahmad, P.K. Bharadwaj, Cryst. Growth Des. 12, 5025 (2012)
K.L. Zhang, J.B. Zhang, C.Y. Jing, L. Zhang, R.I. Walton, P.Z. Zhu, S.W. Ng, J. Solid State Chem. 211, 8 (2014)
C.A. Bauer, T.V. Timofeeva, T.B. Settersten, B.D. Patterson, V.H. Liu, B.A. Simmons, M.D. Allendorf, J. Am. Chem. Soc. 129, 7136 (2007)
S.L. Zheng, J.H. Yang, X.L. Yu, X.M. Chen, W.T. Wong, Inorg. Chem. 43, 830 (2004)
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This work was financially supported by the National Native Science Foundation of China (21371028).
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Zhang, Y., Zhang, X., Zhu, B. et al. Syntheses, Crystal Structure, and Luminescence Properties of Three Metal–Organic Compounds Bearing Diverse Dimensionalities Based on Mixed N- and O-Donor Organic Ligands. J Inorg Organomet Polym 25, 635–644 (2015). https://doi.org/10.1007/s10904-014-0129-6
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DOI: https://doi.org/10.1007/s10904-014-0129-6