Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structures, Luminescence, Biological and Catalytic Properties of Two d10 Metal-Organic Coordination Polymers Constructed from Mixed Ligands

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two d10 metal-organic coordination polymers, [Cd2(4-cpa)4(bmip)2]n (1) and [Zn(4-cpa)2(4,4′-bpy)]n (2), [4-cpa = 4-chlorophenylacetate, bmip = 1,3-bis(2-methylimidazoly)propane, 4,4′-bpy = 4,4′-bipyridine], were hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies indicated that both 1 and 2 display analogous wave-like infinite chain structures. The two coordination polymers are further extended into 3D supramolecular structures through π···π stacking interactions and C–H···O hydrogen bonds for 1 and π···π stacking interactions, C–H···π stacking interactions and C–H···O hydrogen bonds for 2. Both 1 and 2 emit the intense blue luminescence at room temperature. The 4-Hcpa ligand and complexes 1 and 2 have been screened for their herbicidal activities against Brassica napus L. and Echinochloa crusgalli L. The results are compared with the activity of quizalofop-P-ethyl. Both compounds exhibit high catalytic properties on degradation of methyl orange in Fenton-like process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Scheme 2
Fig. 8

Similar content being viewed by others

References

  1. J.C. Geng, L. Qin, X. Du, S.L. Xiao, G.H. Cui, Z. Anorg, Allg. Chem. 638(7–8), 1233 (2012)

    Article  CAS  Google Scholar 

  2. J.R. Long, O.M. Yaghi, Chem. Soc. Rev. 38, 1213 (2009)

    Article  CAS  Google Scholar 

  3. Y.G. Huang, F.L. Jiang, M.C. Hong, Coord. Chem. Rev. 253, 2814 (2009)

    Article  CAS  Google Scholar 

  4. D. Ma, Y. Li, Z. Li, Chem. Commun. 47, 7377 (2011)

    Article  CAS  Google Scholar 

  5. K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R. Long, Chem. Rev. 112, 724 (2012)

    Article  CAS  Google Scholar 

  6. G. Zhang, G. Yang, Q. Chen, J.S. Ma, Cryst. Growth Des. 5, 661 (2005)

    Article  CAS  Google Scholar 

  7. R.W. Saalfrank, I. Bernt, M.M. Chowdhury, F. Hammpel, G.B.M. Vaughan, Chem. Eur. J. 7, 2765 (2001)

    Article  CAS  Google Scholar 

  8. J.Q. Liu, J. Coord. Chem. 64, 1503 (2011)

    Article  CAS  Google Scholar 

  9. J.Y. Lee, D.H. Olson, L. Pan, T.J. Emge, J. Li, Adv. Funct. Mater. 17, 1255 (2007)

    Article  CAS  Google Scholar 

  10. M. Iqbal, I. Ahmad, S. Ali, N. Muhammad, S. Ahmad, M. Sohail, Polyhedron 50, 524 (2013)

    Article  CAS  Google Scholar 

  11. K. Biradha, M. Sarkar, L. Rajput, Chem. Commun. 40, 4169 (2006)

    Article  Google Scholar 

  12. H.J. Hao, F.J. Liu, H.F. Su, Z.H. Wang, D.F. Wang, R.B. Huang, L.S. Zheng, CrystEngComm 14, 6726 (2012)

    Article  CAS  Google Scholar 

  13. T.F. Liu, W.F. Wu, C.Q. Wan, C.H. He, C.H. Jiao, G.H. Cui, J. Coord. Chem. 64, 975 (2011)

    Article  CAS  Google Scholar 

  14. J.Q. Liu, Y.S. Huang, Y.Y. Zhao, Z.B. Jia, Cryst. Growth Des. 11, 569 (2011)

    Article  CAS  Google Scholar 

  15. B.L. Wang, R.G. Duggleby, Z.M. Li, J.G. Wang, Y.H. Li, S.H. Wang, H.B. Song, Pest Manag. Sci. 61, 407 (2005)

    Article  CAS  Google Scholar 

  16. L.G. Devi, S.G. Kumar, K.M. Reddy, C. Munikrishnappa, J. Hazard. Mater. 35, 459 (2009)

    Article  Google Scholar 

  17. Bruker, APEXII Software (Version 6.3.1), Bruker AXS Inc., Madison, WI, USA, 2004

  18. S. Parkin, B. Moezzi, H. Hope, J. Appl. Crystallogr. 28, 53 (1995)

    Article  CAS  Google Scholar 

  19. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  20. S.Q. Xia, S.M. Hu, J.C. Dai, X.T. Wu, Z.Y. Fu, J.J. Zhang, W.X. Du, Polyhedron 23, 1003 (2004)

    Article  CAS  Google Scholar 

  21. W. Bi, R. Cao, D. Sun, D. Yuan, X. Li, Y. Wang, X. Li, M. Hong, Chem. Commun. 18, 2104 (2004)

    Article  Google Scholar 

  22. E. Schon, D.A. Plattner, P. Chen, Inorg. Chem. 43, 3164 (2004)

    Article  Google Scholar 

  23. J. Li, J.H. Zhou, Y.Z. Li, L.H. Weng, X.T. Chen, Z. Yu, Z. Xue, Inorg. Chem. Commun. 7, 538 (2004)

    Article  CAS  Google Scholar 

  24. Y. Zheng, D.M. Xu, S.X. Liu, Inorg. Chim. Acta 294, 163 (1999)

    Article  CAS  Google Scholar 

  25. M.A. Braverman, R.L. LaDuca, Cryst. Growth Des. 7, 2343 (2007)

    Article  CAS  Google Scholar 

  26. Q.G. Zhai, C.Z. Lu, X.Y. Wu, S.R. Batten, Cryst. Growth Des. 7, 2332 (2007)

    Article  CAS  Google Scholar 

  27. Z. Li, M. Li, X.P. Zhou, T. Wu, D. Li, S.W. Ng, Cryst. Growth Des. 7, 1992 (2007)

    Article  CAS  Google Scholar 

  28. T.M. Sterling, J.C. Hall, Mechanism of action of natural auxins and the auxinic herbicides, in Herbicide Activity: Toxicology, Biochemistry and Molecular Biology, ed. by R.M. Roe, J.D. Burton, R.J. Kuhr (IOS Press, Amsterdam, The Netherlands, 1997), pp. 111–141

    Google Scholar 

  29. K. Grossmann, J. Plant Growth Regul. 22, 109 (2003)

    Article  CAS  Google Scholar 

  30. O.E. Offiong, E. Nfor, A.A. Ayi, S. Martelli, Transit. Metal Chem. 25, 369 (2000)

    Article  CAS  Google Scholar 

  31. L. Jiang, H. Wang, M. Wang, X. Teng, Molecules 15, 1074 (2010)

    Article  CAS  Google Scholar 

  32. Y. Morita, E. Matsumura, H. Tsujibo, M. Yasuda, Y. Sakagami, Y. Okabe, N. Ishida, Y. Inamori, Biol. Pharm. Bull. 24, 607 (2001)

    Article  CAS  Google Scholar 

  33. E. Haquea, J.E. Lee, I.T. Jang, Y.K. Hwang, J.S. Chang, J. Jegal, S.H. Jhung, J. Hazard. Mater. 181, 535 (2010)

    Article  Google Scholar 

  34. M. Ocampo, Persulfate Activation by Organic Compounds, Thesis for the Doctorate of Washington State University, 2009

  35. J.M. Liu, X. Lin, C.J. Wei, L.D. Li, Microchim. Acta 148, 267 (2004)

    Article  CAS  Google Scholar 

  36. L. Qin, S.L. Xiao, P.J. Ma, G.H. Cui, Transit. Met. Chem. 38, 627 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (13KJD430003) and Project of Nanjing Science and Technology Development Planning Guidance (2012ZD002).

Author information

Authors and Affiliations

  1. School of Material Engineering, Jinling Institute of Technology, Nanjing, 211169, People’s Republic of China

    Zhi-Qiang Feng, Xiao-Li Yang & Yuan-Feng Ye

Authors
  1. Zhi-Qiang Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiao-Li Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yuan-Feng Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhi-Qiang Feng.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 579 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Feng, ZQ., Yang, XL. & Ye, YF. Synthesis, Crystal Structures, Luminescence, Biological and Catalytic Properties of Two d10 Metal-Organic Coordination Polymers Constructed from Mixed Ligands. J Inorg Organomet Polym 24, 684–693 (2014). https://doi.org/10.1007/s10904-014-0043-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0043-y

Keywords

Search

Navigation