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Assembly and Property Study of a Keggin-Based Inorganic–Organic Supramolecular Compound

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Abstract

By introducing mixed organic ligands (pytz and 4,4′-bipy) into a Keggin POM system, a new Keggin POM-based supramolecular compound, [Cu3(bipy)4(pytz)2(H2O)6][HSiMo12O40]2·8H2O (1) (pytz = 5-(pyridyl)tetrazolate, bipy = 4,4′-bipy) was hydrothermally synthesized and characterized by routine methods. Crystal structure analysis reveals that the title compound contains both right- and left-helical chains, and these helical chains are further connected together forming an interesting mesh network via sharing the [Cu3(bipy)4(pytz)2(H2O)6] subunits. Finally, the 1D pillar-like chains link the mesh nets to construct a 3D supramolecular structure of 1. In addition, compound 1 shows good photocatalytic activity for the degradation of Rhodamine B dye.

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References

  1. J.M. Lehn, Angew. Chem. 102, 1347–1362 (1990)

    Article  CAS  Google Scholar 

  2. J.M. Lehn, Angew. Chem. Int. Ed. 29, 1304–1319 (1990)

    Article  Google Scholar 

  3. M. Yoshizawa, J.K. Klosterman, M. Fujita, Angew. Chem. 48, 3418–3438 (2009)

    Article  CAS  Google Scholar 

  4. P. Mal, B. Breiner, K. Rissanen, J.R. Nitschke, Science 324, 1697–1699 (2009)

    Article  CAS  Google Scholar 

  5. T.F. Liu, Y. Liu, W.M. Xuan, Y. Cui, Angew. Chem. Int. Ed. 49, 4121–4124 (2010)

    Article  CAS  Google Scholar 

  6. I. Dance, M. Scudder, J. Chem. Soc. Dalton Trans. 3755–3769 (1996)

  7. A. Müller, M.T. Pope, F. Peters, D. Gatteschi, Chem. Rev. 98, 239–272 (1998)

    Article  Google Scholar 

  8. P. Mialane, A. Dolbecq, L. Lisnard, A. Mallard, J. Marrot, F. Secheresse, Angew. Angew. Chem. Int. Ed. 41, 2398–2401 (2002)

    Article  CAS  Google Scholar 

  9. C. du Peloux, P. Mialane, A. Dolbecq, J. Marrot, F. Secheresse, Angew. Chem. Int. Ed. 41, 2808–2810 (2002)

    Article  Google Scholar 

  10. E. Coronado, J.R. Galan-Mascaros, C. Gimenez-Saiz, C.J. Gomez-Garcıa, C. Rovira, J. Tarres, S. Triki, J. Veciana, J. Mater. Chem. 8, 313–317 (1998)

    Article  CAS  Google Scholar 

  11. E. Coronado, C. Gimenez-Saiz, C.J. Gomez-Garcıa, S.C. Capelli, Angew. Chem. Int. Ed. 43, 3022–3025 (2004)

    Article  CAS  Google Scholar 

  12. D.E. Katsoulis, Chem. Rev. 98, 359–388 (1998)

    Article  CAS  Google Scholar 

  13. T. Ruether, M. Bond, W.R. Jackson, W. Roy, Green Chem. 5, 364–366 (2003)

    Article  CAS  Google Scholar 

  14. M.Q. Hu, Y.M. Xu, Chemosphere. 54, 431–434 (2004)

    Article  CAS  Google Scholar 

  15. E. Fontananova, L. Donato, E. Drioli, L.C. Lopez, P. Favia, R. d’Agostino. Chem. Mater. 18, 1561–1568 (2006)

    Article  CAS  Google Scholar 

  16. C.C. Chen, W. Zhao, P.X. Lei, J.C. Zhao, N. Serponer, Chem. Eur. J. 10, 1956–1965 (2004)

    Article  CAS  Google Scholar 

  17. Y. Guo, Y. Wang, C. Hu, Y. Wang, E. Wang, Chem. Mater. 12, 3501–3508 (2000)

    Article  CAS  Google Scholar 

  18. G. Peng, Y. Wang, C. Hu, Appl. Catal., A. 218, 91–99 (2001)

    Article  CAS  Google Scholar 

  19. D. Schaming, R. Farha, H.L. Xu, M. Goldmann, L. Ruhlmann, Langmuir. 27, 132–143 (2011)

    Article  CAS  Google Scholar 

  20. C.C. Chen, X.Z. Li, W.H. Ma, J.C. Zhao, J. Phys. Chem. B. 106, 318–324 (2002)

    Article  CAS  Google Scholar 

  21. Y.H. Guo, C.W. Hu, J. Mol. Catal. A: Chem. 262, 136–148 (2007)

    Article  CAS  Google Scholar 

  22. F. Lefebvre, Chem. Commun. 756–757 (1992)

  23. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature. 359, 710–712 (1992)

    Article  CAS  Google Scholar 

  24. T. Blasco, A. Corma, A. Martinez, P. Martinez-Escolano, J. Catal. 177, 306–313 (1998)

    Article  CAS  Google Scholar 

  25. A. Maldotti, A. Molinari, F. Bigi, J. Catal. 253, 312–317 (2008)

    Article  CAS  Google Scholar 

  26. M. Craven, R. Yahya, E. Kozhevnikova, R. Boomishankar, C.M. Robertson, A. Steiner, I. Kozhevnikov, Chem. Commun. 49, 349–351 (2013)

    Article  CAS  Google Scholar 

  27. Y. Kikukawa, Y. Kuroda, K. Yamaguchi, N. Mizuno, Angew. Chem. Int. Ed. 51, 2434–2437 (2012)

    Article  CAS  Google Scholar 

  28. K. Darling, T.M. Smith, J. Vargas, C.J. O’Connor, J. Zubieta, Inorg. Chem. Commun. 32, 1–4 (2013)

    Article  CAS  Google Scholar 

  29. S.T. Zheng, J. Zhang, X.X. Li, W.H. Fang, G.Y. Yang, J. Am. Chem. Soc. 132, 15102–15103 (2010)

    Article  CAS  Google Scholar 

  30. S.G. Mitchell, C. Streb, H.N. Miras, T. Boyd, D.L. Long, L. Cronin, Nat. Chem. 2, 308–312 (2010)

    Article  CAS  Google Scholar 

  31. C.Y. Sun, S.X. Liu, D.D. Liang, K.Z. Shao, Y.H. Ren, Z.M. Su, J. Am. Chem. Soc. 131, 1883–1888 (2009)

    Article  CAS  Google Scholar 

  32. A.X. Tian, J. Ying, J. Peng, J.Q. Sha, H.J. Pang, P.P. Zhang, Y. Chen, M. Zhu, Z.M. Su, Cryst. Growth Des. 8, 3717–3724 (2008)

    Article  CAS  Google Scholar 

  33. J.Q. Sha, M.T. Li, J.W. Sun, P.F. Yan, G.M. Li, L. Zhang, Chem. Asian J. 8, 2254–2261 (2013)

    Article  CAS  Google Scholar 

  34. E. Fournier, F. Lebrun, M. Drouin, A. Decken, P.D. Harvey, Inorg. Chem. 43, 3127–31351 (2004)

    Article  CAS  Google Scholar 

  35. E.Q. Gao, S.Q. Bai, Z.M. Wang, C.H. Yan, Dalton Trans. 1759–1764 (2003)

  36. G.M. Sheldrick, SHELXS-97 (University of Göottingen, Germany, Program for solution of crystal structures, 1997)

    Google Scholar 

  37. G.M. Sheldrick, SHELXL-97 (University of Göottingen, Germany, Program for refinement of crystal structures, 1997)

    Google Scholar 

  38. I.D. Brown, D. Altermatt, Acta Crystallogy. Sect. B. 41, 244–247 (1985)

    Article  Google Scholar 

  39. Q.G. Zhai, X.Y. Wu, S.M. Chen, Z.G. Zhao, C.Z. Lu, Inorg. Chem. 46, 5046–5058 (2007)

    Article  CAS  Google Scholar 

  40. M.T. Pope, Heteropoly and Isopoly Oxometalates (Springer, New York, 1983)

    Book  Google Scholar 

  41. M.Y. Dong, Q. Lin, H.M. Su, D. Chen, T. Zhang, Q.Z. Wu, S.P. Li, Cryst. Growth Des. 11, 5002–5009 (2011)

    Article  CAS  Google Scholar 

  42. Y.H. Guo, Y.H. Wang, C.W. Hu, Y.H. Wang, E.B. Wang, Y.C. Zhou, S.H. Feng, Chem. Mater. 12, 3501–3508 (2000)

    Article  CAS  Google Scholar 

  43. C.C. Chen, Q. Wang, P.X. Lei, W.J. Song, W.H. Ma, J.C. Zhao, Environ. Sci. Technol. 40, 3965–3970 (2006)

    Article  CAS  Google Scholar 

  44. C.M. Xue, S.X. Li, L. Zhang, J.Q. Sha, T.Y. Zheng, Q.N. Zhang, L. Li, J. Inorg. Organomet Polym. 23, 1468–1476 (2013)

    Article  CAS  Google Scholar 

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Acknowledgments

The present study has been supported in part by NSFC(51273056, 21202091, 51303045), NSF of Heilongjiang (E201118, E201144, LBH-Q12021), Abroad Person with Ability Foundation of Heilongjiang Province (2010Td03, 1251G070, and 1252CGZH09), Innovation Fellowship Foundation of Heilongjiang University (Hdtd2010-11).

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Authors and Affiliations

  1. Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, Harbin, 150080, People’s Republic of China

    Zhiyao Sun, Cheng Wang, Disi Lu, Yang Gao, Wenhui Hao & Pengfei Yan

  2. College of Life Science, Heilongjiang University, Harbin, 150080, People’s Republic of China

    Wei Wang

  3. School of Chemical Engineering and Materials, Heilongjiang University, Harbin, 150080, People’s Republic of China

    Shuhong Wang & Cheng Wang

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  1. Zhiyao Sun
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  2. Wei Wang
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  4. Cheng Wang
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Correspondence to Cheng Wang.

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Supplementary Data

Crystallographic data and CCDC can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Tables of selected bond lengths (Å), bond angles (deg) and Figures, IR, XRPD for compound are provided in supporting information.

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Sun, Z., Wang, W., Wang, S. et al. Assembly and Property Study of a Keggin-Based Inorganic–Organic Supramolecular Compound. J Inorg Organomet Polym 24, 706–712 (2014). https://doi.org/10.1007/s10904-014-0030-3

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  • DOI: https://doi.org/10.1007/s10904-014-0030-3

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