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Hydrothermal Synthesis, Characterization and Electrocatalytic/Photocatalytic Activities of New Polyoxometalate Based Hybrid Compound

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Abstract

In this paper, we report the hydrothermal synthesis and physicochemical characterization of a complicated high-dimensional and high-connected POM-based hybrid compound, namely, [Ag3(pytz)2(H2O)]2.[HAgGeMo12O40]·H2O, which has been synthesized by reactions of pyridyltetrazoles and Keggin POMs. X-ray diffraction and crystallographic analyses reveals that the new compound exhibits POMs chains pillaring transition-metal complexes, which represents the highest coordination number of Keggin POMs up to date. Moreover, the new compound bulk-modified carbon-paste electrode (1-CPE) displays good electrocatalytic activity toward the reduction of nitrite, and the result of the photocatalytic activities indicates that the new compound presents better degradation activity and may be a potential photocatalyst to oxidative decomposition of rhodamine B dye in the presence of crystals [Ag3(pytz)2(H2O)]2·[HAgGeMo12O40]·H2O catalyst under ultraviolet-light irradiation.

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Acknowledgments

This work is financially supported by the Education Ministry Foundation (12531696) of Heilongjiang Province.

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Authors and Affiliations

  1. The Provincial Key Laboratory of Biological Medicine Formulation, Jiamusi University, Jiamusi, 154007, People’s Republic of China

    Chun-Mei Xue, Shu-Xian Li, Lei Zhang, Jing-Quan Sha, Tao-Ye Zheng, Qian-Nan Zhang & Liang Li

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  1. Chun-Mei Xue
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  2. Shu-Xian Li
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Correspondence to Jing-Quan Sha.

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Xue, CM., Li, SX., Zhang, L. et al. Hydrothermal Synthesis, Characterization and Electrocatalytic/Photocatalytic Activities of New Polyoxometalate Based Hybrid Compound. J Inorg Organomet Polym 23, 1468–1476 (2013). https://doi.org/10.1007/s10904-013-9951-5

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