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Synthesis and Hydrogen Storage Properties of Palladium Nanoparticle–Organic Frameworks

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Abstract

We report a simple synthesis of aggregates of individual Pd colloidal nanoparticles linked by bridging ligands that may be used to advance the strong hydrogen storage properties of palladium nanoparticles. The aggregates were characterized by transmission electron microscopy and infrared spectroscopy. The bridged aggregates showed up to 1.0 wt% hydrogen absorption, about 6.7 times that of pristine isocyanide-protected Pd nanoparticles.

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Acknowledgments

We thank Ms. Kimiyo Saeki and Dr. Aiko Kamitsubo of the Elemental Analysis Center of the University of Tokyo for elemental analysis. This work was financially supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Coordination Programming” (area 2107, No. 21108002) from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

    Yuki Yamamoto, Mariko Miyachi, Yoshinori Yamanoi & Hiroshi Nishihara

  2. Hydrogen R&D Group, Hydrogen & Fuel Cell Research Laboratory, Research & Development Division, JX Nippon Oil & Energy Corporation, 8 Chidori-cho, Naka-ku, Yokohama, 231-0815, Japan

    Ai Minoda, Shunsuke Maekawa, Shinji Oshima & Yoshihiro Kobori

Authors
  1. Yuki Yamamoto
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  2. Mariko Miyachi
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  3. Yoshinori Yamanoi
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  4. Ai Minoda
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  5. Shunsuke Maekawa
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  6. Shinji Oshima
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  7. Yoshihiro Kobori
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  8. Hiroshi Nishihara
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Correspondence to Yoshinori Yamanoi or Hiroshi Nishihara.

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Yamamoto, Y., Miyachi, M., Yamanoi, Y. et al. Synthesis and Hydrogen Storage Properties of Palladium Nanoparticle–Organic Frameworks. J Inorg Organomet Polym 24, 208–213 (2014). https://doi.org/10.1007/s10904-013-9925-7

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  • DOI: https://doi.org/10.1007/s10904-013-9925-7

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