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Synthesis, Structures and Luminescent Properties of Two New Cd(II) Coordination Polymers Based on V-Shaped 3,3′,4,4′-Oxidiphthalic Acid

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Abstract

Two new Cd(II) coordination polymers, namely [Cd2(H2OA)2(μ2-H2O)(H2O)6] n ·3nH2O (1) and [Cd2(H2OA)(phen)2] n ·nH2O (2) (H4OA = 3,3′,4,4′-oxidiphthalic acid, phen = 1,10-phenanthroline) have been synthesized by combining H4OA or H4OA and phen with Cd(II) salts under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 features a hydrogen-bond directed two-dimensional (2D) layered structure constructed from alternating left- and right-handed double strand helical chains, 2 represents a one-dimensional (1D) chain structure with the phen molecules dangling on it, which is further extended into a three-dimensional (3D) supramolecular framework through strong face-to-face π···π interactions. In addition, luminescent properties of these two compounds were also investigated in the solid state at room temperature.

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Acknowledgments

We are grateful for the financial support from the Natural Science Foundation of Hebei Province, China (B2012210004 and E2011210009), and the Foundation of Hebei Education Department, China (2009475).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang, 050043, People’s Republic of China

    Yan-Xue Chen, Jin-Hui Yang & Bing-Yi Chen

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  1. Yan-Xue Chen
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  2. Jin-Hui Yang
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Correspondence to Yan-Xue Chen.

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Chen, YX., Yang, JH. & Chen, BY. Synthesis, Structures and Luminescent Properties of Two New Cd(II) Coordination Polymers Based on V-Shaped 3,3′,4,4′-Oxidiphthalic Acid. J Inorg Organomet Polym 23, 1233–1239 (2013). https://doi.org/10.1007/s10904-013-9913-y

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  • DOI: https://doi.org/10.1007/s10904-013-9913-y

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