Skip to main content
SpringerLink
Log in

Hydrothermal Synthesis of a Nano-sized Mercury(II) N–N–O Donor Coordination Compound

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A novel nano-structures mercury(II) coordination compound, [Hg (HPCIH) I2] (1), (“HPCIH” is the abbreviation of 2-pyridinecarbaldehyde isonicotinoyl hydrazone) has been synthesized by a hydrothermal method that produces the coordination compound at nano size. The new nanostructure was characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction elemental analysis and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal structure of this complex shows that each mercury(II) center is five coordinated with two N-donor and one O-donor atoms from “HPCIH” ligand and two iodo anions. Self-assembly of this complexes is realized by CH····I, I····I and π–π stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)

    Article  CAS  Google Scholar 

  2. J.-P. Zhang, S.-L. Zheng, X.-C. Huang, X.-M. Chen, Angew. Chem. Int. Ed. 43, 206 (2004)

    Article  CAS  Google Scholar 

  3. S. Kitagawa, R. Kitaura, S.I. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)

    Article  CAS  Google Scholar 

  4. X.-H. Bu, M.-L. Tong, H.-C. Chang, S. Kitagawa, S.R. Batten, Angew. Chem. Int. Ed. 43, 192 (2004)

    Article  CAS  Google Scholar 

  5. C.N.R. Rao, S. Natarajan, R. Vaidhyanathan, Angew. Chem. Int. Ed. 43, 1466 (2004)

    Article  CAS  Google Scholar 

  6. O.R. Evans, W.-B. Lin, Acc. Chem. Res. 35, 511 (2002)

    Article  CAS  Google Scholar 

  7. B. Zhao, P. Cheng, Y. Dai, C. Cheng, D.-Z. Liao, S.-P. Yan, Z.-H. Jiang, G.-L. Wang, Angew. Chem. Int. Ed. 42, 934 (2003)

    Article  CAS  Google Scholar 

  8. G. Fe′rey, C. Serre, C. Mellot-Draznieks, F. Millange, S. Surble, J. Dutour, I. Margiolaki, Angew. Chem. Int. Ed. 43, 6296 (2004)

    Article  Google Scholar 

  9. P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1999)

    Article  Google Scholar 

  10. R.J. Hill, D.-L. Long, N.R. Champness, P. Hubberstey, M. Schröder, Acc. Chem. Res. 38, 337 (2005)

    Article  Google Scholar 

  11. C. Hu, I. Kalf, U. Englert, Cryst. Eng. Comm. 9, 603 (2007)

    CAS  Google Scholar 

  12. S. Nayak, P. Gamez, B. Kozlevcar, A. Pevec, O. Roubeau, S. Denhen, Polyhedron 29, 2291 (2010)

    Article  CAS  Google Scholar 

  13. G.G. Mohamed, M.M. Omar, A.A. Ibrahim, Spectrochim. Acta Part A 75, 678 (2010)

    Article  Google Scholar 

  14. C. Maxim, T.D. Pasatoiu, VCh. Kravtsov, S. Shova, ChA Muryn, R.E.P. Winpenny, F. Tuna, M. Andruh, Inorg. Chem. 361, 3903 (2008)

    CAS  Google Scholar 

  15. P. Gomez-Saiz, R. Gil-Garcia, M.A. Maestro, J. Luis Pizarro, M. Isabel Arriortua, L. Lezama, T. Rojo, M. Gonzalez-Alvarez, J. Garcia-Tojal, J. Inorg. Biochem. 102, 1910 (2008)

    Article  CAS  Google Scholar 

  16. S. Nigam, M.M. Patel, A. Ray, J. Phys. Chem. Solids 61, 1389 (2000)

    Article  CAS  Google Scholar 

  17. N.Ch. Kasuga, K. Sekino, M. Ishikawa, A. Honda, M. Yokoyama, S. Nakano, N. Shimada, Ch. Koumo, K. Nomiya, J. Inorg. Biochem. 96, 298 (2003)

    Article  CAS  Google Scholar 

  18. N.Ch. Kasuga, K. Sekino, Vh Koumo, N. Shimada, M. Ishikawa, K. Nomiya, J. Inorg. Biochem. 84, 55 (2001)

    Article  CAS  Google Scholar 

  19. N.Ch. Kasuga, K. Onodera, S. Nakano, K. Hayashi, K. Nomiya, J. Inorg. Biochem. 100, 1176 (2004)

    Article  Google Scholar 

  20. S. Chandra, A. Kumar, Spectrochim. Acta Part A 66, 1347 (2007)

    Article  Google Scholar 

  21. C. Hu, I. Kalf, U. Englert, Cryst. Eng. Comm. 9, 603 (2007)

    CAS  Google Scholar 

  22. A.R. Mahjoub, A. Morsali, Polyhedron 21, 1223 (2002)

    Article  CAS  Google Scholar 

  23. Y.-Y. Yang, W. Guo, MDu Inorg, Chem. Commun. 13, 1195 (2010)

    CAS  Google Scholar 

  24. J-d. Lin, J-w. Chen, S-w. Du, Cryst. Growth Des. 8, 3345 (2008)

    Article  CAS  Google Scholar 

  25. J. Yang, B. Wu, F. Zhuge, J. Liang, C. Jia, Y.-Y. Wang, N. Tang, X.-J. Yang, Q.-Z. Shi, Cryst. Growth Des. 10, 2331 (2010)

    Article  CAS  Google Scholar 

  26. P. Banerjee, S. Kar, A. Bhaumik, G.H. Lee, S.M. Peng, S. Goswami, Eur. J. Inorg. Chem. 2007, 835 (2007)

  27. J.-C. Dai, X.-T. Wu, Z.-Y. Fu, C.-P. Cui, S.-M. Hu, W.-X. Du, L.-M. Wu, H.-H. Zhang, R.-Q. Sun, Inorg. Chem. 41, 1391 (2002)

    Article  CAS  Google Scholar 

  28. Y.-B. Dong, X. Zhao, R.-Q. Huang, M.D. Smith, H.C. Loye, Inorg. Chem. 43, 5603 (2004)

    Article  CAS  Google Scholar 

  29. X. Wang, C. Qin, E. Wang, Y. Li, N. Hao, C. Hu, L. Xu, Inorg. Chem. 43, 1850 (2004)

    Article  CAS  Google Scholar 

  30. J. Otsuki, N. Omokawa, K. Yoshiba, I. Yoshikawa, T. Akasaka, T. Suenobu, T. Takido, K. Araki, S. Fukuzumi, Inorg. Chem. 42, 3057 (2003)

    Article  CAS  Google Scholar 

  31. P.V. Bernhardt, P. Chin, D.R. Richardson, J. Biol. Inorg. Chem. 6, 801 (2001)

    Article  CAS  Google Scholar 

  32. A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 32, 115 (1999)

    Article  CAS  Google Scholar 

  33. G.M. Sheldrick, A short history of SHELX. Acta Crystallogr. A 64(1), 112 (2007)

    Article  Google Scholar 

  34. J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997)

    Article  CAS  Google Scholar 

  35. L.K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edn, Part B. (Wiley, New York, 1997), pp. 124–126

  36. J.M. Harrowfield, H. Miyamae, B.W. Skelton, A.A. Soudi, A.H. White, Aust. J. Chem. 49, 1165 (1996) (and references therein)

    Article  Google Scholar 

  37. T. Dorn, C. Janiak, K. Abu-Shandi, Cryst. Eng. Comm. 7, 633 (2005)

    CAS  Google Scholar 

  38. D.L. Reger, R.F. Semeniuc, V. Rassolov, M.D. Smith, Inorg. Chem. 43, 537 (2004)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is funded by the World Class University Grant KRF R32-2008-000-20082-0 of the National Research Foundation of Korea.

Author information

Authors and Affiliations

  1. School of Mechanical Engineering, Yeungnam University, Gyongsan, 712-749, South Korea

    Younes Hanifehpour & Sang Woo Joo

  2. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Younes Hanifehpour, Samaneh Khanalilou & Elham Paknahad

  3. Department of Chemistry, Azarbaijan University of Shahid Madani, Tabriz, Iran

    Moayad Hossaini Sadr & Behzad Soltani

Authors
  1. Younes Hanifehpour
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Samaneh Khanalilou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Elham Paknahad
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sang Woo Joo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Moayad Hossaini Sadr
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Behzad Soltani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sang Woo Joo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hanifehpour, Y., Khanalilou, S., Paknahad, E. et al. Hydrothermal Synthesis of a Nano-sized Mercury(II) N–N–O Donor Coordination Compound. J Inorg Organomet Polym 22, 1248–1253 (2012). https://doi.org/10.1007/s10904-012-9731-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-012-9731-7

Keywords

Search

Navigation