Skip to main content
SpringerLink
Log in

Two d10 Coordination Polymers Based on the Substitutional Aromatic Multicarboxylate and N-donor Co-ligands: Syntheses, Structures and Luminescent Properties

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two new coordination polymers, formulated as Zn(3-NPA)(1,4-bimb) (1) and Cd(3-NPA)(1,2-bimb)(H2O) (2) (3-NPAH2 = 3-nitrophthalic acid, 1,4-bimb = 1,4-bis(imidazol-1 -ylmethyl)benzene, 1,2-bimb = 1,2-bis(imidazol-1-ylmethyl)-benzene) have been synthesized by hydrothermal reactions of the semirigid neutral ligand 1,4-bimb or 1,2-bimb with metal ions in the presence of 3-nitro phthalic acid. The two compounds were characterized by infrared spectroscopy, elemental analysis, thermo gravimetric analysis and single-crystal X-ray diffraction analysis. Polymer 1 possesses a new two-dimensional puckered rectangular grid architecture, with the 1,4-bimb ligands displaying a cis-conformation. In polymer 2, the 3-NPA2− anions coordinate the Cd(II) ions in a tetra dentate mode to form a dimer unit, which is connected by the 1,2-bimb ligands resulting in a single layer. Intra layer hydrogen bond interactions are found between the water molecule and carboxylate oxygen atoms. Weak π···π interactions are observed between the layers through the benzene rings from the adjacent 3-NPA2− and 1,2-bimb ligands. In addition, the luminescent properties of the two compounds were also investigated in this paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. O.M. Yaghi, M. O’Keeffe, N.W. Ocking, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)

    Article  CAS  Google Scholar 

  2. B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  3. K. Biradha, C.-Y. Su, J.J. Vittal, Cryst. Growth Des. 11, 875 (2011)

    Article  CAS  Google Scholar 

  4. A. Demessence, J.R. Long, Chem. Eur. J. 16, 5902 (2010)

    CAS  Google Scholar 

  5. B.F. Abrahams, M.J. Grannas, T.A. Hudson, R. Robson, Angew. Chem. Int. Ed. 49, 1087 (2010)

    Article  CAS  Google Scholar 

  6. X.-J. Ke, D.-S. Li, M. Du, Inorg. Chem. Commun. 14, 788 (2011)

    Article  CAS  Google Scholar 

  7. C.N.R. Rao, S. Natarajan, Angew. Chem. Int. Ed. 43, 1466 (2004)

    Article  CAS  Google Scholar 

  8. M.D. Allendof, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Chem. Soc. Rev. 38, 1330 (2009)

    Article  Google Scholar 

  9. J.Y. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.T. Nguyen, J.T. Hupp, Chem. Soc. Rev. 38, 1450 (2009)

    Article  CAS  Google Scholar 

  10. L.J. Murray, M. Dincǎ, J.R. Long, Chem. Soc. Rev. 38, 1294 (2009)

    Article  CAS  Google Scholar 

  11. M. Kurmoo, Chem. Soc. Rev. 38, 1353 (2009)

    Article  CAS  Google Scholar 

  12. P.M. Forster, N. Stock, A.K. Cheetham, Angew. Chem. Int. Ed. 44, 7608 (2005)

    Article  CAS  Google Scholar 

  13. Y.-F. Zhou, B.-Y. Lou, D.-Q. Yuan, Y.-Q. Xu, F.-L. Jiang, M.-H. Hong, Inorg. Chim. Acta 358, 3057 (2005)

    Article  CAS  Google Scholar 

  14. S.-M. Chen, C.-Z. Lu, Q.-Z. Zhang, J.-H. Liu, X.-Y. Wu, Eur. J. Inorg. Chem. 2005, 423 (2005)

  15. L. Brammer, Chem. Soc. Rev. 33, 476 (2004)

    Article  CAS  Google Scholar 

  16. S.R. Seide, P.J. Stang, Acc. Chem. Res. 35, 972 (2002)

    Article  Google Scholar 

  17. D.L. Caulder, K.N. Raymond, Acc. Chem. Res. 32, 975 (1999)

    Article  CAS  Google Scholar 

  18. X.-L. Lü, H. Wu, J.-F. Ma, J. Yang, Polyhedron 30, 1579 (2011)

    Article  Google Scholar 

  19. Y.-S. Song, B. Yan, Z.-X. Chen, Appl. Organometal. Chem. 21, 150 (2007)

    Article  CAS  Google Scholar 

  20. Y. Huang, B. Yan, M. Shao, Z.-X. Chen, J. Mol. Struct. 871, 59 (2007)

    Article  CAS  Google Scholar 

  21. X.-Q. Shen, H.-B. Qiao, Z.-J. Li, H.-Y. Zhang, H.-L. Liu, R. Yang, P.-K. Chen, H.-W. Hou, Inorg. Chim. Acta 359, 642 (2006)

    Article  CAS  Google Scholar 

  22. Y.-H. Deng, J. Liu, B. Wu, C. Ambrus, T.D. Keene, O. Waldmann, S.-X. Liu, S. Decurtins, X.-J. Yang, Eur. J. Inorg. Chem. 2002, 1712 (2008)

    Article  Google Scholar 

  23. B.F. Hoskins, R. Robson, D.A. Slizys, J. Am. Chem. Soc. 119, 2952 (1997)

    Article  CAS  Google Scholar 

  24. SAINT, Bruker AXS Inc., Madison, 2004

  25. G.M. Sheldrick, SHELXS-97, program for crystal structure solution (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  26. G.M. Sheldrick, SHELXL-97, program for crystal structure refinement (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  27. L.-Y. Zhang, G.-F. Liu, S.-L. Zheng, B.-H. Ye, X.-M. Zhang, X.-M. Chen, Eur. J. Inorg. Chem. 2003, 2965 (2003)

    Article  Google Scholar 

  28. J.-C. Dai, X.-T. Wu, S.-M. Hu, Z.-Y. Fu, J.-J. Zhang, W.-X. Du, H.-H. Zhang, R.-Q. Sun, Eur. J. Inorg. Chem. 2004, 2096 (2004)

    Article  Google Scholar 

  29. K. Nakamoto, Infrared and Raman spectra of inorganic and coordinated compounds, 5th edn. (Wiley, New York, 1997)

    Google Scholar 

  30. G.-X. Liu, Y.-Q. Huang, Q. Chu, T.A. Okamura, W.-Y. Sun, H. Liang, N. Ueyama, Cryst. Growth Des. 8, 3233 (2008)

    Article  CAS  Google Scholar 

  31. J. Tao, X. Yin, Z.-B. Wei, R.-B. Huang, L.-S. Zheng, Eur. J. Inorg. Chem. 2004, 125 (2004)

    Article  Google Scholar 

  32. W. Chen, J.-Y. Wang, C. Chen, Q. Yue, H.-M. Yuan, J.-S. Chen, S.-N. Wang, Inorg. Chem. 42, 944 (2004)

    Article  Google Scholar 

  33. L. Wang, M. Yang, G.-H. Li, Z. Shi, S.-H. Feng, Inorg. Chem. 45, 2474 (2006)

    Article  CAS  Google Scholar 

  34. B.-L. Wu, D.-Q. Yuan, F.-L. Jiang, R.-H. Wang, L. Han, Y.-F. Zhou, M.-C. Hong, Eur. J. Inorg. Chem. 2004, 2695 (2004)

    Article  Google Scholar 

  35. G.-X. Liu, K. Zhu, H.-M. Xu, S. Nishihara, R.-Y. Huang, X.-M. Ren, Cryst. Eng. Commun. 11, 2784 (2009)

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21101019), Anhui Natural Science Foundation of China (No. 090414190) and the Materials Key Subject of Chizhou College (2011XK04). We also thank Prof. Dr. Li-Min Zheng and Dr. Tao Zheng at Nanjing University for the physical properties measurements.

Author information

Authors and Affiliations

  1. Department of Chemistry and Food Science, Center of Chemical Materials and Engineering Experiment, Chizhou College, Chizhou, 247000, People’s Republic of China

    Pengfei Wang, Guozhi Wu, Ruixia Wang & Xin Wang

Authors
  1. Pengfei Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Guozhi Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ruixia Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Pengfei Wang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 141 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, P., Wu, G., Wang, R. et al. Two d10 Coordination Polymers Based on the Substitutional Aromatic Multicarboxylate and N-donor Co-ligands: Syntheses, Structures and Luminescent Properties. J Inorg Organomet Polym 22, 1028–1033 (2012). https://doi.org/10.1007/s10904-012-9698-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-012-9698-4

Keywords

Search

Navigation