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Assembly of Polyoxometalate-Based Composite Materials

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Abstract

This paper is a review the polyoxometalate-based composite materials, including polyoxometalate incorporated Langmuir and Langmuir–Blodgett, layer-by-layer multilayers and novel honeycomb films, self-assembly structures of modified polyoxometalate complexes (e.g., onion-like structures, new inorganic–organic–inorganic vesicles, thermotropic and lyotropic liquid crystalline structures, gels), and amino acid- and protein-polyoxometalate nanorods and nanoparticles. Polyoxometalate-embedded layer-by-layer multilayer films show electrocatalytic or photochemical activity; and, novel photoluminescent honeycomb films templated by microwater droplets are reviewed. Inorganic–organic–inorganic hybrid vesicles display the potential as nano-switches. In addition, amino acid- and protein-polyoxometalate composite nanostructures indicate potential antimicrobial applications. Therefore, the polyoxometalate-based composite materials have promising applications in electrochemistry, photochemistry and biomedicine.

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Acknowledgments

This work was financially supported by the NSFC (Grant No. 20625307, 21103071), Natural Science Foundation of Shandong Province, China (Grant No. ZR2011BQ016), and the National Basic Research Program of China (973 Program 2009CB930103).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, People’s Republic of China

    Dawei Fan & Qin Wei

  2. Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan, 250100, People’s Republic of China

    Jingcheng Hao

  3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, People’s Republic of China

    Jingcheng Hao

Authors
  1. Dawei Fan
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  2. Jingcheng Hao
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  3. Qin Wei
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Correspondence to Dawei Fan.

Additional information

Presented in part at the 1st International Congress on Advanced Materials held in Jinan, PRC, from May 12–17, 2011.

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Fan, D., Hao, J. & Wei, Q. Assembly of Polyoxometalate-Based Composite Materials. J Inorg Organomet Polym 22, 301–306 (2012). https://doi.org/10.1007/s10904-012-9665-0

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