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Syntheses and Crystal Structures of Di- and Trimethyltin Carboxylates: Ladders and 1D Zig–Zag Chains Polymers

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Abstract

A series of organotin(IV) carboxylates complexes; namely, [(Me2Sn)4O2(RCOO)4] (R = C12H15 1, C9H11 2, C8H8ClO 3, C7H9 4) and [Me3(RCOO)]n (R = C12H15 5, C9H11 6, C8H8ClO 7, C7H9 8) have been synthesized. All complexes were characterized by elemental analysis, FT-IR, and NMR (1H, 13C and 119Sn) spectroscopy. Among them, the structures of complexes 1–3 and 5–8 were also determined by X-ray crystallography. The structural analysis showed that complexes 1–3 are the same tetranuclear monomer, and complexes 5–8 are the same 1D zigzag chain coordination polymer. Furthermore, each complex 1, 2 and 3, can form a supramolecular chain through weak intermolecular interactions.

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Acknowledgments

We thank the National Nature Science Foundation of China (20971096) for financial supported.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Ru-Fen Zhang, Bao-Ying Zhang, Yun Ren & Chun-Lin Ma

  2. Taishan University, Taian, 271021, People’s Republic of China

    Chun-Lin Ma

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  1. Ru-Fen Zhang
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  2. Bao-Ying Zhang
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Correspondence to Chun-Lin Ma.

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Zhang, RF., Zhang, BY., Ren, Y. et al. Syntheses and Crystal Structures of Di- and Trimethyltin Carboxylates: Ladders and 1D Zig–Zag Chains Polymers. J Inorg Organomet Polym 22, 149–157 (2012). https://doi.org/10.1007/s10904-011-9572-9

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