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One-dimensional Coordination Polymer as New Precursor for Preparation of Fe2O3 Nano-particles

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Abstract

A Fe(II) one-dimensional coordination polymer, [Fe(pyterpy)2](SCN)2.MeOH (1), which pyterpy is 4′-(4-Pyridyl)-2,2′:6′,2′-terpyridine, has been synthesized by using branched tube and characterized by elemental analysis, X-ray powder diffraction (XRD) and IR spectroscopy. Iron(III) oxide nano-particles were obtained by thermolysis of compound 1 in oleic acid (surfactant) at 286 °C under air atmosphere. The Fe2O3 nano-particles were characterized by XRD and scanning electron microscopy. This study demonstrates that the Fe(II) coordination polymers are suitable precursors for the simple one-pot preparation of iron oxide nano-materials.

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Acknowledgments

Support of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran

    Azadeh Mehrani & Ali Morsali

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  1. Azadeh Mehrani
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  2. Ali Morsali
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Correspondence to Ali Morsali.

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Mehrani, A., Morsali, A. One-dimensional Coordination Polymer as New Precursor for Preparation of Fe2O3 Nano-particles. J Inorg Organomet Polym 21, 476–479 (2011). https://doi.org/10.1007/s10904-011-9476-8

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  • DOI: https://doi.org/10.1007/s10904-011-9476-8

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