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Bioactive Organotin Materials: Synthesis, Characterization and Antimicrobial Investigation

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Abstract

Antimicrobial properties of some newly prepared oil based organotin polymers by the condensation reaction between fatty amide diol (N,N′-bis(2-hydroxyethyl) castoroil fatty amide) obtained from castoroil and organotin dihydroxides (dibutyltin dihydroxide, dimethyltin dihydroxide and diphenyltin dihydroxide) have been studied by employing both Gram-positive (Lactobacillus, Staphylococcus aureus) and Gram-negative (Pseudomonas putida, Pseudomonas fluorescens, E. coli) bacteria. The structural studies of these three polymers were carried out by FTIR, 1HNMR and 13 CNMR spectroscopic techniques. Standard laboratory methods were used to study the physiochemical characteristics like acid value, hydroxyl value, saponification value, iodine value, specific gravity and viscosity. A comparative study of the thermal stability was analysed by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). All three polymers have been found fairly active against the tested bacterial species.

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References

  1. J.A. Zubita, J.J. Zuckerman, Inorg. Chem. 24, 251 (1985)

    Article  Google Scholar 

  2. G.K. Sandhu, R. Gupta, S.S. Sandhu, R.V. Parish, Polyhedron 4, 81 (1985)

    Article  CAS  Google Scholar 

  3. T.P. Lochart, F. Davison, Organometallics 6, 2471 (1987)

    Article  Google Scholar 

  4. I.W. Nowell, J.S. Brooks, G. Beech, R. Hill, J. Organomet. Chem. 244, 119 (1983)

    Article  CAS  Google Scholar 

  5. M.N. Cooksley, D.N. Parham, Surf. Coat. 2, 280 (1966)

    CAS  Google Scholar 

  6. G.J.M. Vander Kerk, J.G.A. Luijten, J. Appl. Chem. 6, 314 (1954)

    Google Scholar 

  7. G.J.M. Vander Kerk, J.G.A. Luijten, J. Appl. Chem. 6, 56 (1954)

    Article  Google Scholar 

  8. R. Bleicher, C. Carraher, J. Polym. Mater. Sci. Eng. 86, 289 (2002)

    CAS  Google Scholar 

  9. M. Roner, C. Carraher, A. Zhao, J. Roehr, K. Bassett, D. Seigmann-Louda, Polym Mater Sci Eng 90, 525 (2004)

    Google Scholar 

  10. M. Roner, C. Carraher, A. Zhao, J. Roehr, K. Bassett, D. Seigmann-Louda, Polym. Mater. Sci. Eng. 90, 515 (2004)

    CAS  Google Scholar 

  11. M. Roner, C. Carraher, J. Roehr, K. Bassett, D. Seigmann-Louda, J. Polym. Mater. Sci. Eng. 91, 744 (2004)

    CAS  Google Scholar 

  12. C. Carraher, R. Bleicher, Macromolecules Containing Metal and Metal Like Elements, vol. 3 (Wiley, Hoboken, 2005)

    Google Scholar 

  13. C. Carraher, K. Morie, Polym. Mater. Sci. Eng. 91, 556 (2004)

    CAS  Google Scholar 

  14. C. Carraher, D. Seigmann-Louda, Macromolecules Containing Metal and Metal Like Elements, vol. 3 (Wiley, Hoboken, 2004)

    Google Scholar 

  15. G. Barot, K. Shahi, M. Roner, C. Carraher, Polym. Mater. Sci. Eng. 94, 466 (2006)

    Google Scholar 

  16. C. Carraher, K. Morie, Polym. Mater. Sci. Eng. 91, 556 (2004)

    CAS  Google Scholar 

  17. M. Roner, C. Carraher, J. Roche, K. Bassett, J. Polym. Mater. 23, 153 (2006)

    CAS  Google Scholar 

  18. D. Seigmann-Louda, C. Carraher, D. Chamely, A. Cardoso, D. Snedden, Polym. Mater. Sci. Eng. 86, 293 (2002)

    Google Scholar 

  19. D. Seigmann-Louda, C. Carraher, M. Graham, R. Doucette, L. Lanz, Polym. Mater. Sci. Eng. 87, 247 (2002)

    Google Scholar 

  20. D. Seigmann-Louda, C. Carraher, D. Snedden, A. Komulainen, Polym. Mater. Sci. Eng. 90, 512 (2004)

    Google Scholar 

  21. C. Carraher, D. Leahy, S. Ailts, Org. Coat. Plast. Chem. 37, 201 (1977)

    Google Scholar 

  22. C. Carraher, H. Blaxall, J. Schroeder, W. Wenable, Org. Coat. Plast. Chem. 39, 549 (1978)

    CAS  Google Scholar 

  23. C. Carraher, J. Schroeder, W. Venable, C.M.C. Neely, Org Coat. Plast. Chem. 38, 544 (1978)

    Google Scholar 

  24. C. Carraher, J. Schroeder, W. Venable, C.M.C. Neely, D. Giron, W. Wolk, M. Feddersen, Additives for Plastics, Chapter 8 (Academic Press, New York, 1978)

    Google Scholar 

  25. C. Carraher, T. Manek, R. Linville, J.R. Tayler, L. Torre, W. Venable, Org. Coat. Plast. Chem. 43, 753 (1980)

    CAS  Google Scholar 

  26. C. Carraher, R. Linville, T. Manek, H. Blaxell, J.R. Tayler, L. Torre, Electrical Properties of Polymer Chapter 8 (Plenum, New York, 1981)

    Google Scholar 

  27. C. Carraher, V. Nwufoh, J.R. Tayler, Polym. Mater. 60, 685 (1989)

    CAS  Google Scholar 

  28. A. Battin, C. Carraher, Polym. Mater. Sci. Eng. 95, 541 (2006)

    CAS  Google Scholar 

  29. A.I. Aigbodion, C.K.S. Pillai, J.O. Bakare, L.E. Yahaya, Indian J. Chem. Technol. 8, 378 (2001)

    CAS  Google Scholar 

  30. A. Guo, I. Javni, Z. Petrovic, J. Appl. Polym. Sci. 77, 467 (2000)

    Article  CAS  Google Scholar 

  31. C. Wang, F.N. Jones, J. Appl. Polym. Sci. 78, 1698 (2000)

    Article  CAS  Google Scholar 

  32. A.M. Motawie, E.A. Hassan, A. Manich, M.E. Aboul-Fetonch, A. Fakheel-Uddin, J. Appl. Polym. Sci. 55, 1725 (1995)

    Article  CAS  Google Scholar 

  33. J. Chen, M.D. Soucek, W.J. Simon Sick, R.W. Celikay, Polymer 43, 5379 (2002)

    Article  CAS  Google Scholar 

  34. S.K. Das, S. Lenka, J. Appl. Polym. Sci. 75, 1487 (2000)

    Article  CAS  Google Scholar 

  35. A.M. Motawie, E.M. Sadek, M.M.B. Awad, A. Fkheel-Uddin, J. Appl. Polym. Sci. 67, 577 (1998)

    Article  Google Scholar 

  36. M. Alam, S.M. Ashraf, S. Ahmed, J. Polym. Res. 15, 343–350 (2008)

    Article  CAS  Google Scholar 

  37. S. Ahmed, S.M. Ashraf, E. Shamim, M. Nazir, M. Alam, Prog. Org. Coat. 52, 85–91 (2005)

    Article  CAS  Google Scholar 

  38. W.W. Davis, T.R. Stout, Appl. Microbiol. 22, 60 (1971)

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Jamia Millia Islamia, New Delhi, 110025, India

    N. P. Bharathi & Athar Adil Hashmi

  2. Centre for Biomedical Engg, Indian Institute of Technology, New Delhi, 110016, India

    Manawwer Alam

  3. Department of Biosciences, Jamia Millia Islamia, New Delhi, 110025, India

    Arif TasleemJan

Authors
  1. N. P. Bharathi
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  2. Manawwer Alam
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  3. Arif TasleemJan
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  4. Athar Adil Hashmi
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Correspondence to Athar Adil Hashmi.

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Bharathi, N.P., Alam, M., TasleemJan, A. et al. Bioactive Organotin Materials: Synthesis, Characterization and Antimicrobial Investigation. J Inorg Organomet Polym 19, 187–195 (2009). https://doi.org/10.1007/s10904-009-9254-z

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  • DOI: https://doi.org/10.1007/s10904-009-9254-z

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