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Metal Complexes of π-Conjugated Polymers

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Abstract

π-Conjugated chelating polymers such as poly(2,2′-bipyridine-5,5′-diyl), poly(1,10-phenanthroline-3,8-diyl), and salophen polymers have been prepared by organometallic polycondensations. The obtained polymers form metal complexes with various metal species such as [Ru(bpy)2]2+ and CuCl2. Metal complexes of π-conjugated ligands are also polymerized by dehalogenative organometallic polycondensations. Some of the metal complexes of π-conjugated polymers exhibit electrical conducting nature and show catalytic activity for redox reactions.

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  1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

    Takakazu Yamamoto, Hiroki Fukumoto & Take-aki Koizumi

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  1. Takakazu Yamamoto
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  2. Hiroki Fukumoto
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  3. Take-aki Koizumi
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Correspondence to Takakazu Yamamoto.

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Yamamoto, T., Fukumoto, H. & Koizumi, Ta. Metal Complexes of π-Conjugated Polymers. J Inorg Organomet Polym 19, 3–11 (2009). https://doi.org/10.1007/s10904-008-9246-4

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  • DOI: https://doi.org/10.1007/s10904-008-9246-4

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