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Metal-containing Polymers Synthesized via Acyclic Diene Metathesis (ADMET) Polymerization Using Electrochemically-Reduced Tungsten-based Catalyst: Polycarbosilanes

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Abstract

Acyclic diene metathesis (ADMET) polymerization of dienes containing silicon using electrochemically produced active catalyst species (WCl6-e−-Al-CH2Cl2) was investigated. Silicon-containing unsaturated polymers were characterized by 1H- and 13C-NMR spectroscopy, gel permeation chromatography (GPC) and elemental analysis. The thermal behavior of the polymers was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

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Acknowledgments

Hacettepe University Research Fund (04A601014) and Scientific and Technological Research Council of Turkey (TBAG 104T344) are gratefully acknowledged for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hacettepe University, Beytepe, Ankara, 06800, Turkey

    Solmaz Karabulut, Cemil Aydogdu, Bülent Düz & Yavuz İmamoglu

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  1. Solmaz Karabulut
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  2. Cemil Aydogdu
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  3. Bülent Düz
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  4. Yavuz İmamoglu
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Correspondence to Solmaz Karabulut or Yavuz İmamoglu.

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Karabulut, S., Aydogdu, C., Düz, B. et al. Metal-containing Polymers Synthesized via Acyclic Diene Metathesis (ADMET) Polymerization Using Electrochemically-Reduced Tungsten-based Catalyst: Polycarbosilanes. J Inorg Organomet Polym 17, 517–523 (2007). https://doi.org/10.1007/s10904-007-9141-4

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  • DOI: https://doi.org/10.1007/s10904-007-9141-4

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