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A Novel Boat-Shaped Rare Earth Complex with a 3-D Interlinked Structure of Pr(III) and 1,2,4,5-Benzenetetracarboxylic Acid

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Abstract

A novel boat-shaped praseodymium (III)-carboxylate polymeric complex [Pr(Hbtec)]n (H4btec = 1,2,4,5-benzenetetracarboxylic acid) with 3-D interlinked structure, which contains nine-coordinate rare earth metal centers, simplified as PRCPC, has been synthesized under hydrothermal conditions. The frames interlinked with each other and formed a unique boat-like alignment. PRCPC that was obtained was characterized by differential thermal analysis/thermogravimetry (DTA/TG), single crystal X-ray diffraction, elemental analysis and FTIR spectral analysis. Analysis of the single-crystal X-ray diffraction confirms that PRCPC crystallizes in triclinic symmetry with space group (P − 1), where a = 7.325(3), b = 8.162(3), c = 8.791(3) Å, α = 65.345(4), β = 86.015(4), γ = 84.203(5)°, V = 475.0(3) Å3, Z = 2, R1 = 0.0201, wR2 = 0.0505. PRCPC exhibits high thermal stability and its supramolecular frame remains stable without any change under heat treatment to 510°C.

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Acknowledgement

This work was supported by Doctoral Foundation of Jinan University.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Engineering, Jinan University, No.106, Jiwei Road, 250022, Jinan, Shandong, P.R. China

    Q. B. Bo, Z. X. Sun, Y. L. Sheng, Z. W. Zhang, G. X. Sun, C. L. Chen & Y. X. Li

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  1. Q. B. Bo
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  2. Z. X. Sun
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  3. Y. L. Sheng
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Correspondence to Q. B. Bo.

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Bo, Q.B., Sun, Z.X., Sheng, Y.L. et al. A Novel Boat-Shaped Rare Earth Complex with a 3-D Interlinked Structure of Pr(III) and 1,2,4,5-Benzenetetracarboxylic Acid. J Inorg Organomet Polym 16, 241–248 (2006). https://doi.org/10.1007/s10904-006-9046-7

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