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Synthesis and Characterization of Bismuth Complexes [BiI2(4,4′-bpy)(S2CNR2)]∞ and [BiI(S2CNR2)2]∞ and Crystal Structure of [BiI2(4,4′-bpy)(S2CNC4H8O)]∞ and [BiI(S2CNC5H10)2]∞

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An Erratum to this article was published on 06 February 2007

Summary

The six new bismuth(III) complexes [BiI2(4,4′-bpy)(S2CNR2)]∞ (NR2=NC4H8O 1, NC4H8 2, N(C2H4OH)2 3) and [BiI(S2CNR2)2]∞ (NR2= NC5H10 4, NC4H8 5, NEt2 6) have been synthesized by the reactions of BiI3 with 4,4′-bipyridine and dithiocarbamate, and their structures have been characterized by elemental analysis and IR spectroscopy. The crystal structures of complexes 1 and 4 have been determined by X-ray diffraction. In the complex 1, the structure shows a distorted pentagonal bipyramid geometry with seven-coordination for the central Bi atom and the bridging 4,4′-bipyridines links the Bi atoms to form one-dimensional chain polymer. The structure of complex 4 shows a distorted octahedral configuration with six-coordination for the central Bi atom and the bridging iodine atom link the Bi atoms to form one-dimensional chain polymer.

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Acknowledgments

We acknowledged the National Natural Foundation of the Peoples Republic of China (Grant #20271025), Shangdong Province Science Foundation (Grant #L2003B01), and State Key Laboratory of Crystal Materials of Shangdong University, Peoples Republic of China.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China

    Handong Yin, Feng Li, Fahui Li & Daqi Wang

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  1. Handong Yin
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  2. Feng Li
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Correspondence to Handong Yin.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9109-4

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Yin, H., Li, F., Li, F. et al. Synthesis and Characterization of Bismuth Complexes [BiI2(4,4′-bpy)(S2CNR2)]∞ and [BiI(S2CNR2)2]∞ and Crystal Structure of [BiI2(4,4′-bpy)(S2CNC4H8O)]∞ and [BiI(S2CNC5H10)2]∞ . J Inorg Organomet Polym 16, 161–168 (2006). https://doi.org/10.1007/s10904-006-9045-8

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