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Syntheses and Structural Characterization of Triorganotin Derivatives of 3-Mercapto-4-methyl-4H-1,2,4-triazol: X-ray Crystal Structures of One-dimensional Zigzag Polymeric chain of Me3Sn[SC3H4N3] and Ph3Sn[SC3H4N3]

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An Erratum to this article was published on 06 February 2007

The triorganotin derivatives of 3-mercapto-4-methyl-4H-1,2,4-triazol, R3Sn[SC3H4N3] (R = Me 2, n-Bu 3, Ph 4, PhCH2 5), have been synthesized and characterized by IR and NMR spectroscopy. Among them, complexes 2 and 4 were also characterized by X-ray crystallography diffraction analyses, which revealed that both 2 and 4 show one-dimensional zigzag polymeric chain structure in which the geometries of tin atoms are both trigonal bipyramid with the axial positions occupied by sulfur and nitrogen atoms.

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Acknowledgments

We thank the National Natural Science Foundation of China (20271025) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China

    Chunlin Ma, Guangru Tian & Rufen Zhang

  2. Department of Chemistry, Taishan University, Taian, 271021, P.R. China

    Chunlin Ma

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  1. Chunlin Ma
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Correspondence to Chunlin Ma.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9117-4

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Ma, C., Tian, G. & Zhang, R. Syntheses and Structural Characterization of Triorganotin Derivatives of 3-Mercapto-4-methyl-4H-1,2,4-triazol: X-ray Crystal Structures of One-dimensional Zigzag Polymeric chain of Me3Sn[SC3H4N3] and Ph3Sn[SC3H4N3]. J Inorg Organomet Polym 16, 139–145 (2006). https://doi.org/10.1007/s10904-006-9041-z

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