Highly Selective Detection of Cr3 + Ion with Colorimetric & Fluorescent Response Via Chemodosimetric Approach in Aqueous Medium

  • Ganesan Punithakumari
  • Shu Pao Wu
  • Sivan Velmathi
ORIGINAL ARTICLE
  • 18 Downloads

Abstract

So far, very few numbers of chemosensors for Cr3+ ion have been reported. However, the main drawback of reported receptors are the lack of selectivity and other trivalent cations such as Fe3+, Al3+ and anions like F and OAc frequently interfere with such assays. This paper present the synthesis, characterization & sensor studies of Schiff base containing naphthalene moiety which selectively detect Cr3+ ion by chemodosimetric approach. Using FT-IR, 1H NMR, 13C NMR and ESI mass spectroscopic techniques the probe was characterized. This receptor exhibit more selectivity and sensitivity towards Cr3+ than other divalent and trivalent cations like Mn2+, Zn2+, Co2+, Ni2+, Cd2+, Cu2+, Hg2+, Fe3+, and Al3+ ions. After the addition of chromium ion the receptor get change from yellow to colorless in aqueous medium. But no color change was observed on the addition of other metal ions. Using UV-Vis and PL studies, it was confirmed that the selective hydrolysis of imine group of receptor by Cr3+ ions takes place with high fluorescence enhancement that is corresponding to 1-naphthylamine. Receptor acts as selective chemodosimeter for Cr3+ ions with 2:1 stoichiometry and micro molar detection limit. This chemodosimetric approach was applied successfully for bio-imaging of HeLa cells.

Keywords

Naphthalene Schiff base Cr(III) Turn-on fluorescence Bio-imaging Chemodosimeter 

Notes

Acknowledgements

Authors thank the MHRD, GOI for providing infra structure facilities.

Supplementary material

10895_2018_2228_MOESM1_ESM.docx (815 kb)
ESM 1 (DOCX 814 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Organic and Polymer Synthesis LaboratoryNational Institute of TechnologyTiruchirapalliIndia
  2. 2.Department of Applied ChemistryNational Chiao Tung UniversityHsinchuTaiwan

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