Skip to main content

Advertisement

Log in

Modeling of the Process of Hydrolysis of Sodium Borohydride in a Circulating Reactor

  • Published:
Journal of Engineering Physics and Thermophysics Aims and scope

The authors have presented a mathematical model of heat- and mass-transfer processes in a circulating-type reactor implementing the hydrolysis of sodium borohydride in the hydrogen generator. The model was used to analyze two methods of control of the generator output and can be applied to scaling and optimization of structures of generators of this type.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Zuttel, Materials for hydrogen storage, Mater. Today, 6, Issue 9, 24–33 (2003).

    Article  Google Scholar 

  2. U. B. Demirci, O. Akdim, J. Andrieux, et al., Sodium borohydride hydrolysis as hydrogen generator: issues, state of the art and applicability upstream from a fuel cell, Fuel Cells, 10, Issue 3, 335–350 (2010).

    Article  Google Scholar 

  3. P. Brack, S. Dann, and K. G. U. Wijayantha, Heterogeneous and homogenous catalysts for hydrogen generation by hydrolysis of aqueous sodium borohydride (NaBH4) solutions. Review, Energy Sci. Eng., 3, Issue 3, 174–188 (2015).

  4. U. B. Demirci, The hydrogen cycle with the hydrolysis of sodium borohydride: A statistical approach for highlighting the scientifi c/technical issues to prioritize in the fi eld. Review, Int. J. Hydrogen Energy, 40, Issue 6, 2673–2691 (2015).

    Article  Google Scholar 

  5. Y. Kojima, K. Suzuki, K. Fukumoto, et al., Development of 10 kW-scale hydrogen generator using chemical hydride, J. Power Sources, 125, Issue 1, 22–26 (2004).

    Article  Google Scholar 

  6. Y. Wu, Q. Zhang, K. McNamara, et al., Catalytic reactor performance of a borohydride hydrogen generator, Am. Chem. Soc., Div. Fuel Chem., 49, Issue 1, 148–149 (2004).

    Google Scholar 

  7. S. Galli, M. De Francesco, G. Monteleone, et al., Development of a compact hydrogen generator from sodium borohydride, Int. J. Hydrogen Energy, 35, Issue 14, 7344–7349 (2010).

    Article  Google Scholar 

  8. C.-L. Hsueh, C.-H. Liu, B.-H. Chen, et al., A novel design of solid-state NaBH4 composite as a hydrogen source for 2 W PEMFC applications, J. Power Sources, 196, Issue 7, 3530–3538 (2011).

    Article  Google Scholar 

  9. J. Zhang, Y. Zheng, J. P. Gore, et al., 1 kWe sodium borohydride hydrogen generation system. Part I: Experimental study, J. Power Sources, 165, Issue 2, 844–853 (2007).

    Article  Google Scholar 

  10. V. G. Minkina, V. I. Kalinin, and S. I. Shabunya, Development of a sodium–borohydride hydrogen generator, Khim. Tekhnol., No. 11, 698–704 (2013).

  11. V. G. Minkina, V. I. Kalinin, and S. I. Shabunya, Hydrogen generator operating on sodium borohydride for stationary hydrogen generator, Int. J. Hydrogen Energy, 41, No. 22, 9227–9233 (2016).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 91, No. 6, pp. 1700–1705, November–December, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shabunya, S.I., Kalinin, V.I., Minkina, V.G. et al. Modeling of the Process of Hydrolysis of Sodium Borohydride in a Circulating Reactor. J Eng Phys Thermophy 91, 1617–1622 (2018). https://doi.org/10.1007/s10891-018-1900-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10891-018-1900-2

Keywords

Navigation